Monobenzoate useful as a plasticizer in plastisol compositions
View Patent ↗A unique monobenzoate useful as a plasticizer in polymeric dispersions, such as plastisols and melt compounds. The monobenzoate comprises 3-phenyl propyl benzoate, a benzoate ester heretofore known as a flavoring and fragrance agent, but not previously utilized as a plasticizer in polymeric applications. Depending on the application, the advantages rendered by the use of the inventive monobenzoate include, among other things, excellent solvating properties, low viscosity, viscosity stability, and improved rheology, as well as health, safety and environmental advantages over traditional plasticizers. The monobenzoate may be used alone or in combination with a variety of plasticizers, including but not limited to phthalates, terephthalates, dibenzoates, other monobenzoates, or 1,2-cyclohexane dicarboxylate esters, and mixtures thereof.
1. A plastisol composition comprising:
a. a polyvinyl chloride (PVC)-based or an acrylic-based polymer dispersion wherein the acrylic-based polymer is a homopolymer or copolymer of polymethacrylate, aromatic methacrylates, alkylacrylates, or acrylic acid; and
b. a plasticizer consisting of 3-phenylpropyl benzoate, wherein the plasticizer provides improved solvation and rheology characteristics and improved gel/fusion temperatures over that achieved with other known high solvating plasticizers used in plastisols.
2. A plasticizer blend for use in plastisol compositions consisting of:
3-phenyl propyl benzoate,
diisononyl-1,2-cyclohexane dicarboxylate, and
a dibenzoate triblend comprising 20 wt. % of 1,2-propylene glycol dibenzoate and 80 wt % of a 4:1 diethylene glycol dibenzoate:dipropylene glycol dibenzoate.
3. The plasticizer blend of claim 2 , wherein the plastisol composition comprises a polyvinyl chloride polymer dispersed in the plasticizer blend.
4. A plasticizer blend for use in plastisol compositions consisting of:
3-phenyl propyl benzoate,
di-2-ethylhexyl terephthalate, and
a dibenzoate triblend comprising 20 wt % of 1,2-propylene glycol dibenzoate and 80 wt. % of a 4:1 diethylene glycol dibenzoate:dipropylene glycol dibenzoate.
5. The plasticizer blend of claim 4 , wherein the plastisol composition comprises a polyvinyl chloride polymer dispersed in the plasticizer blend.
6. A method of plasticizing a polyvinyl chloride (PVC) based-plastisol or an acrylic based-plastisol, comprising the step of:
adding 3-phenylpropyl benzoate to a primary plasticizer selected from the group consisting of di-2-ethylhexyl terephthalate, diisononyl-1,2-cyclohexane dicarboxylate, a dibenzoate triblend comprising 20 wt. % of 1,2-propylene glycol dibenzoate and 80 wt. % of a 4:1 diethylene glycol dibenzoate:dipropylene glycol dibenzoate, and mixtures thereof, wherein the PVC-based plastisol comprises a homopolymer or copolymer of polyvinyl chloride, and wherein the acrylic-based plastisol comprises a homopolymer or copolymer of polymethacrylates, aromatic methacrylates, alkylacrylates, or acrylic acid.