Separator and electrochemical device having the same
The present invention refers to a separator and an electrochemical device having the same. The separator of the present invention comprises a non-woven fabric substrate obtained from fibers and having multiple pores formed between the fibers; and a polymer coating layer formed on a part or the whole of the surface of the fibers, wherein the polymer coating layer comprises a polymer having a tensile strength of 80 MPa or more, a tensile modulus of 3,000 MPa or more and a flexural modulus of 3,000 MPa or more. The separator of the present invention can reduce costs for manufacturing electrochemical devices, and it can control the size of pores present in the non-woven fabric substrate to prevent the generation of a leak current and provide improved mechanical strength.
1. A separator, comprising:
a non-woven fabric substrate comprising fibers and having multiple pores between the fibers; and
a polymer coating layer disposed on a part or the whole of the surface of strands of the fibers,
wherein the polymer coating layer comprises a polymer having a tensile strength ranging from 80 MPa to 133 MPa, a tensile modulus ranging from 3,000 MPa to 7,800 MPa, and a flexural modulus ranging from 3,000 MPa to 7,300 MPa,
wherein the polymer is selected from the group consisting of polyamide ether ketones (PAEK), polyimides (PI), polyphenylene sulfones (PPSU), polyphenylene ethers (PPE), polyether sulfones (PES), polyether ether ketones (PEEK), polybenzo imidazoles (PBI), polyether imides (PEI), polyamideimides (PAI), poly(p-phenylene-2,6-benzobisoxazoles), epoxy resins and a mixture thereof.
2. The separator according to claim 1 , wherein the fibers have a thickness of 0.01 to 10 μm.
3. The separator according to claim 1 , wherein the non-woven fabric substrate comprises pores having a large diameter of 0.05 to 70 μm by 50% or more based on the total number of pores.
4. The separator according to claim 1 , wherein the non-woven fabric substrate has a porosity of 30 to 80%, and a thickness of 10 to 30 μm.
5. The separator according to claim 1 , which further comprises multiple inorganic particles adhered on the polymer coating layer.
6. The separator according to claim 5 , wherein the inorganic particles have an average diameter of 0.001 to 10 μm, and are selected from the group consisting of BaTiO 3 , Pb(Zr,Ti)O 3 (PZT), Pb 1-x La x Zr 1-y TiO 3 (PLZT, 0<x<1, 0<y<1), Pb(Mg 1/3 Nb 2/3 )O 3 —PbTiO 3 (PMN-PT), hafnia (HfO 2 ), SrTiO 3 , SnO 2 , CeO 2 , MgO, NiO, CaO, ZnO, ZrO 2 , Y 2 O 3 , Al 2 O 3 , SiC, TiO 2 and a mixture thereof.
7. The separator according to claim 5 , wherein the inorganic particles are present in an amount of 100 to 10,000 parts by weight based on 100 parts by weight of the polymer.
8. The separator according to claim 1 , which has a porosity of 5 to 50%.
9. The separator according to claim 1 , which satisfies the following equation (1):
0.5<( W 2 /D 2 )/( W 1 /D 1 )<3.5 (I)
wherein, W 1 is a weight per 1 m 2 of the non-woven fabric substrate, D 1 is a density of the non-woven fabric substrate, W 2 is a weight of the polymer present in 1 m 2 of the polymer-coating layer, and D 2 is a density of the polymer.
10. An electrochemical device, comprising a cathode, an anode and a separator interposed between the cathode and the anode, wherein the separator is defined in claim 1 .
11. The electrochemical device according to claim 10 , which is a lithium secondary battery.
12. A separator, comprising:
a non-woven fabric substrate comprising fibers and having multiple pores between the fibers; and
a polymer coating layer disposed on a part or the whole of the surface of strands of the fibers,
wherein the polymer coating layer comprises a polymer having a tensile strength ranging from 80 MPa to 133 MPa, a tensile modulus ranging from 3,000 MPa to 7,800 MPa, and a flexural modulus ranging from 3,000 MPa to 7,300 MPa,
wherein the separator which satisfies the following equation (1):
0.5<( W 2 /D 2 )/( W 1 /D 1 )<3.5 (I)
wherein, W 1 is a weight per 1 m 2 of the non-woven fabric substrate, D 1 is a density of the non-woven fabric substrate, W 2 is a weight of the polymer present in 1 m 2 of the polymer-coating layer, and D 2 is a density of the polymer.