Anode for lithium secondary battery and lithium secondary battery including the same
Provided is an anode for a lithium secondary battery composed of a multi-layered structure including an electrode current collector, a first anode active material layer including a first anode active material formed on the electrode current collector, and a second anode active material layer including a second anode active material having relatively lower press density and relatively larger average particle diameter than the first anode active material. Since an anode according to an embodiment of the present invention may include a multi-layered active material layer including two kinds of anode active materials having different press densities and average particle diameters on an electrode current collector, porosity of the surface of the electrode may be improved even after a press process to improve ion mobility into the electrode. Thus, charge characteristics and cycle life of a lithium secondary battery may be improved.
1. An anode comprising:
an electrode current collector; and
a multi-layered active material layer formed on the electrode current collector,
wherein the multi-layered active material layer comprises:
a first anode active material layer including a first anode active material; and
a second anode active material layer including a second anode active material, wherein the second anode active material layer is prepared by including the second anode active material having a lower press density and a larger average particle diameter than the first anode active material,
wherein the first anode active material and the second anode active material each comprises crystalline carbon, amorphous carbon, or a mixture thereof.
2. The anode of claim 1 , wherein the crystalline carbon of the first anode active material and the second anode active material is natural graphite, artificial graphite, or a mixture thereof, and has a spherical or spherical-like shape.
3. The anode of claim 1 , wherein a ratio of the average particle diameter of the first anode active material to the average particle diameter of the second anode active material is in a range of 1:9 to 5:5.1.
4. The anode of claim 3 , wherein the ratio of the average particle diameter of the first anode active material to the average particle diameter of the second anode active material is in a range of 1:1.3 to 1:4.
5. The anode of claim 1 , wherein a ratio of the press density of the first anode active material to the press density of the second anode active material is in a range of 1.1:1 to 3:1 under a pressure of 12 MPa to 16 MPa.
6. The anode of claim 1 , wherein a ratio of compressive strength of the first anode active material to compressive strength of the second anode active material is in a range of 2:8 to 5:5.1 under a pressure of 12 MPa to 16 MPa.
7. The anode of claim 1 , wherein porosity of the second anode active material layer is higher than porosity of the first anode active material layer.
8. The anode of claim 1 , wherein the first anode active material and the second anode active material each further comprise a conductive agent and a binder.
9. A lithium secondary battery comprising the anode of claim 1 .