Method for manufacturing a solid electrolyte
View Patent ↗A method for manufacturing a solid electrolyte includes dissolving first polymers and second polymers in a cosolvent including a first cosolvent and a second cosolvent to provide a preparation solution; adding a lithium solution to the preparation solution to provide a mixture solution; removing the second cosolvent from the mixture solution to prepare an electrolyte paste that exhibits thixotropy; and coating the electrolyte paste onto a substrate to form an electrolyte film, wherein the electrolyte paste in a gel state is characterized by the first polymers being aligned in parallel to one another in one direction; the second polymers randomly surrounding the first polymers and having an average molecular weight that is greater than that of the first polymers; and a lithium solution provided between the first polymers and the second polymers.
1. A method for manufacturing a solid electrolyte, comprising:
preparing a preparation solution by dissolving first polymers and second polymers in a cosolvent system, the cosolvent system including a first cosolvent and a second cosolvent;
preparing a mixture solution by adding a lithium solution to the preparation solution;
preparing an electrolyte paste that exhibits thixotropy by removing the second cosolvent from the mixture solution, wherein the electrolyte paste is in a sol state; and
forming an electrolyte film by coating the electrolyte paste onto a substrate and subsequently gelling the electrolyte paste from the sol state to a gel state on the substrate,
wherein the electrolyte film is comprised of:
the first polymers, the first polymers being aligned in parallel to one another in one direction;
the second polymers, the second polymers randomly surrounding the first polymers and having an average molecular weight that is greater than that of the first polymers; and
the lithium solution, the lithium solution being provided between the first polymer and the second polymers.
2. The method of manufacturing a solid electrolyte of claim 1 , wherein gelling the electrolyte paste is performed at a temperature ranging from about 5° C. to about 50° C.
3. The method of manufacturing a solid electrolyte of claim 2 , wherein, in the sol state, each of the first polymers of the electrolyte paste is arranged in random directions with respect to each other.
4. The method for manufacturing a solid electrolyte of claim 1 , wherein the second cosolvent has a lower boiling point that is lower than that of each of the first polymers, the second polymers, the lithium solution and the first cosolvent.
5. The method for manufacturing a solid electrolyte of claim 1 , wherein the second cosolvent is removed by stirring.
6. The method of manufacturing a solid electrolyte of claim 1 , wherein the first polymers have an average molecular weight ranging from about 1 to about 100,000 and the second polymers have an average molecular weight ranging about 200,000 to about 1,000,000.
7. The method for manufacturing a solid electrolyte of claim 1 , wherein coating the electrolyte paste is performed by a screen printing method.
8. The method of manufacturing a solid electrolyte of claim 1 , wherein the mixture is in a sol state.