Electrophoretic particles, electrophoretic dispersion liquid, display sheet, display device, and electronic equipment
View Patent ↗Electrophoretic particle include a core particle (mother particle); a siloxane-based compound that is bonded to a surface of the core particle and contains a connection structure in which a plurality of siloxane bonds are serially connected to each other; and a charging group that is an organic group bonded to the surface of the core particle, contains a main skeleton, and has a positive or negative electric charge. It is preferable that the occupancy rate of an area to which the siloxane-based compound is bonded on the surface of the core particle be in the range of 0.05% to 20%.
1. An electrophoretic particle, comprising:
a mother particle;
a siloxane-based compound that is derived from silicone oil and is bonded to a surface of the mother particle and contains a connection structure in which a plurality of siloxane bonds are serially connected to each other; and
a charging group that is an organic group bonded to the surface of the mother particle, contains a main skeleton, and has a positive or negative electric charge, wherein
an occupancy rate of an area to which the charging group is bonded on the surface of the mother particle is lower than an occupancy rate of an area to which the siloxane-based compound is bonded on the surface of the mother particle,
the siloxane-based compound has a structure derived from a coupling agent which is bonded to the surface of the mother particle,
the connection structure is connected to the surface of the mother particle through the structure derived from the coupling agent,
the charging group contains an ion pair bonded to the main skeleton, and
the charging group further has a structure derived from the coupling agent and is connected to the surface of the mother particle through the structure derived from the coupling agent.
2. The electrophoretic particle according to claim 1 , wherein a content of the charging group is in a range of 0.1% by mass to 40% by mass based on a total mass of the mother particle and the charging group.
3. An electrophoretic dispersion liquid, comprising:
a plurality of the electrophoretic particles according to claim 2 ; and
a dispersion medium that allows the plurality of electrophoretic particles to be dispersed.
4. The electrophoretic particle according to claim 1 , wherein the occupancy rate of an area to which the siloxane-based compound is bonded on the surface of the mother particle is in a range of 0.1% to 10%.
5. An electrophoretic dispersion liquid, comprising:
a plurality of the electrophoretic particles according to claim 4 ; and
a dispersion medium that allows the plurality of electrophoretic particles to be dispersed.
6. The electrophoretic particle according to claim 1 , wherein the siloxane-based compound has a linear molecular structure that is formed of a main chain containing the connection structure and a side chain bonded to the main chain.
7. The electrophoretic particle according to claim 1 ,
wherein the siloxane-based compound has a hydrocarbon structure bonded to the surface of the mother particle, and
the connection structure is connected to the surface of the mother particle through the hydrocarbon structure.
8. The electrophoretic particle according to claim 1 , wherein a weight average molecular weight of the siloxane-based compound is in a range of 1000 to 100000.
9. The electrophoretic particle according to claim 1 , wherein a molecular weight of the charging group is smaller than a molecular weight of the siloxane-based compound.
10. The electrophoretic particle according to claim 1 , wherein the ion pair contains at least one of an ammonium-based cation, a carboxylic acid anion, a phosphoric acid anion, a sulfonic acid anion, and a boron anion.
11. An electrophoretic dispersion liquid, comprising:
a plurality of the electrophoretic particles according to claim 1 ; and
a dispersion medium that allows the plurality of electrophoretic particles to be dispersed.
12. The electrophoretic dispersion liquid according to claim 11 , wherein the relative dielectric constant of the dispersion medium is in the range of 1.5 to 3.
13. A display sheet, comprising:
a first substrate on which a first electrode is provided;
a second substrate that is arranged to face the first substrate and on which a second electrode is provided; and
a display layer that is provided between the first substrate and the second substrate and contains the electrophoretic dispersion liquid according to claim 11 .
14. A display device, comprising the display sheet according to claim 13 .
15. Electronic equipment, comprising the display device according to claim 14 .