Electrophoretic particles, electrophoretic dispersion liquid, display sheet, display device, and electronic equipment
View Patent ↗Electrophoretic particle include a core particle; a siloxane-based compound that is bonded to a surface of the core particle and contains a connection structure in which a plurality of siloxane bonds are serially connected to each other; and a polarizing group that is an organic group bonded to the surface of the core particle, contains a main skeleton and a substituent bonded to the main skeleton, and has unevenly distributed electrons on the particle side of the main skeleton or the opposing side thereof.
1. An electrophoretic particle, comprising:
a mother particle;
a siloxane-based compound that is derived from silicone oil and is bonded to a surface of the mother particle and contains a connection structure in which a plurality of siloxane bonds are serially connected to each other; and
a polarizing group that is an organic group bonded to the surface of the mother particle, contains a main skeleton and a substituent bonded to the main skeleton, and has unevenly distributed electrons on the mother particle side of the main skeleton or the opposing side thereof,
wherein the main skeleton included in the polarizing group has a portion in which π electrons are delocalized.
2. The electrophoretic particle according to claim 1 , wherein an occupancy rate of an area to which the siloxane-based compound is bonded on the surface of the mother particle is in a range of 0.05% to 20%.
3. The electrophoretic particle according to claim 1 , wherein the total content of the siloxane-based compound and the polarizing group is in a range of 0.5 parts by mass to 10 parts by mass based on 100 parts by mass of the mother particle.
4. The electrophoretic particle according to claim 1 , wherein an occupancy rate of the area to which the polarizing group is bonded on the surface of the mother particle is lower than that of an area to which the siloxane-based compound is bonded on the surface of the mother particle.
5. The electrophoretic particle according to claim 1 , wherein the siloxane-based compound has a linear molecular structure that is formed of a main chain containing the connection structure and a side chain bonded to the main chain.
6. The electrophoretic particle according to claim 1 ,
wherein the siloxane-based compound has a structure derived from a coupling agent which is bonded to the surface of the mother particle, and
the connection structure is connected to the surface of the mother particle through the structure derived from the coupling agent.
7. The electrophoretic particle according to claim 1 ,
wherein the siloxane-based compound has a hydrocarbon structure bonded to the surface of the mother particle, and
the connection structure is connected to the surface of the mother particle through the hydrocarbon structure.
8. The electrophoretic particle according to claim 1 , wherein a weight average molecular weight of the siloxane-based compound is in the range of 1000 to 100000.
9. The electrophoretic particle according to claim 1 , wherein a molecular weight of the polarizing group is smaller than the molecular weight of the siloxane-based compound.
10. The electrophoretic particle according to claim 1 , wherein the portion in which π electrons are delocalized includes a cyclic structure having a cyclic shape in at least a portion thereof.
11. The electrophoretic particle according to claim 10 ,
wherein the cyclic structure is positioned on an end portion of the main skeleton, which is the opposite side to the mother particle, and
the substituent is bonded to the cyclic structure.
12. The electrophoretic particle according to claim 11 , wherein the substituent is an electron attracting group or an electron donating group.
13. The electrophoretic particle according to claim 10 , wherein the main skeleton has a portion functioning as a spacer which is positioned between the mother particle and the cyclic structure.
14. The electrophoretic particle according to claim 10 ,
wherein the polarizing group includes a structure derived from the coupling agent which is bonded to the surface of the mother particle, and
the cyclic structure is connected to the surface of the mother particle through the structure derived from the coupling agent.
15. An electrophoretic dispersion liquid, comprising:
a plurality of the electrophoretic particles according to claim 1 ; and
a dispersion medium that allows the plurality of electrophoretic particles to be dispersed.
16. The electrophoretic dispersion liquid according to claim 15 , wherein the relative dielectric constant of the dispersion medium is in the range of 1.5 to 3.
17. A display sheet, comprising:
a first substrate on which a first electrode is provided;
a second substrate that is arranged to face the first substrate and on which a second electrode is provided; and
a display layer that is provided between the first substrate and the second substrate and contains the electrophoretic dispersion liquid according to claim 15 .
18. A display device, comprising the display sheet according to claim 17 .
19. Electronic equipment, comprising the display device according to claim 18 .