LED package with red-emitting phosphors
View Patent ↗A process for fabricating a LED lighting apparatus includes disposing a composite coating on a surface of a LED chip. The composite coating comprises a first composite layer having a manganese doped phosphor of formula I and a first binder, and a second composite layer comprising a second phosphor composition and a second binder. The first binder, the second binder or both include a poly(meth)acrylate. A x [MF y ]:Mn 4+ (I) wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MF y ] ion; y is 5, 6 or 7.
1. A process for fabricating a LED lighting apparatus, comprising:
forming a first composite layer comprising a first phosphor composition of formula I and a first binder,
A x [MF y ]:Mn 4+ (I)
wherein,
A is Li, Na, K, Rb, Cs, or combinations thereof;
M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or combinations thereof;
x is the absolute value of the charge of the [MF y ] ion;
y is 5, 6 or 7;
forming a second composite layer comprising a second phosphor composition and a second binder, wherein the first binder, the second binder or both comprise a poly(meth)acrylate, and wherein forming the first composite layer, the second composite layer or both comprises:
selecting a particle size distribution of particulates for one or both the first binder and the second binder, wherein the particle size distribution has a D50 value from about 150 microns to about 300 microns; and
mixing the first phosphor composition with the particulates of the first binder and pressing a mixture of the first phosphor composition and the first binder at approximately melting temperature of the first binder to form the first composite layer, and mixing the second phosphor composition with the particulates of the second binder and pressing a mixture of the second phosphor composition and the second binder at approximately melting temperature of the second binder to form the second composite layer, thereby controlling a distribution of the first phosphor composition in the first composite layer and the second phosphor composition in the second composite layer,
forming a composite coating by disposing the first composite layer on the second composite layer, and
disposing the composite coating on a LED.
2. The process according to claim 1 , wherein forming the composite coating further comprises bonding the first composite layer to the second composite layer.
3. The process according to claim 2 , wherein the first composite layer and the second composite layer are bonded by an adhesive.
4. The process according to claim 2 , wherein bonding comprises curing the first composite layer and the second composite layer.
5. The process according to claim 1 , wherein the first phosphor composition of formula I comprises a population of particles having a particle size distribution with a D50 value in a range from about 20 microns to about 50 microns.
6. The process according to claim 1 , wherein the first phosphor composition of formula I comprises a population of particles having a particle size distribution with a D50 value in a range from about 10 microns to about 30 microns.
7. The process according to claim 1 , wherein the poly(meth)acrylate is poly(methyl methacrylate).
8. The process according to claim 1 , wherein the first phosphor composition is K 2 SiF 6 :Mn 4+ .