Method of forming metallic pattern on polymer substrate
A method of forming a metallic pattern on a polymer substrate is provided. A mixture layer is formed on a polymer substrate surface. The mixture layer includes an active carrier medium and nanoparticles dispersed in the active carrier medium. A laser process is performed to treat a portion of the mixture layer to form active seed residues on the surface of the polymer substrate. A cleaning process is performed to remove an untreated portion of the mixture layer to expose the surface of the polymer substrate, while the active seed residues are remained on the surface of the polymer substrate. Then, the active seed residues on the polymer substrate are subjected to an electroless plating process to form the metallic pattern over the active seed residues on the polymer substrate.
1. A method of forming a metallic pattern on a polymer substrate, comprising:
providing a polymer substrate;
forming a mixture layer on a surface of the polymer substrate, wherein the mixture layer includes an active carrier medium and nanoparticles dispersed in the active carrier medium, and a material of the nanoparticles includes copper oxide;
performing a laser process to treat a portion of the mixture layer to form active seed residues on the surface of the polymer substrate, wherein the laser process is performed by using a UV laser at 355 nm with a power of 0.2˜0.4 W and 80% overlapping and the laser process is a laser ablation and activation process;
performing a cleaning process to remove an untreated portion of the mixture layer to expose the surface of the polymer substrate, while the active seed residues are remained on the surface of the polymer substrate; and
subjecting the active seed residues on the polymer substrate to an electroless plating process to form the metallic pattern over the active seed residues.
2. The method according to claim 1 , wherein a material of the polymer substrate includes nylons, polycarbonates (PC), acrylonitrile butadiene styrene (ABS), PC/ABS, polyethylene terephthalate (PET), polyether ether ketone (PEEK) or liquid crystal polymers (LCP).
3. The method according to claim 1 , wherein the active seed residues are copper residues.
4. The method according to claim 1 , wherein the electroless plating process includes an electroless copper plating process and the metallic pattern includes a copper pattern.
5. The method according to claim 1 , wherein the nanoparticles have an average size below 100 nm.
6. The method according to claim 1 , wherein a content of the nanoparticles in the mixture layer ranges from 10 wt % to 20 wt %, relative to a total weight of the mixture layer.
7. The method according to claim 1 , wherein a material of the active carrier medium includes polyvinylpyrrolidone (PVP) or polyethylene oxide (PEO).
8. The method according to claim 1 , wherein forming the mixture layer includes forming the mixture layer by spraying, spin coating, dip coating, screen printing, pad printing or smearing.
9. The method according to claim 1 , wherein a position of a distribution range of the active seed residues corresponds to a position of the metallic pattern.