Golf ball having a thermoplastic positive hardness gradient inner core layer and a thermostat shallow positive hardness gradient outer core layer
View Patent ↗A golf ball has an inner core layer including a thermoplastic highly-neutralized ionomer and having a geometric center hardness less than a surface hardness to define a first positive hardness gradient. An outer core layer is formed about the inner core and includes a homogenous thermoset composition. The outer core has an interior hardness less than an outer surface hardness to define a second positive hardness gradient. An inner and outer cover layers are disposed about outer core layer. The first and second hardness gradients each have a slope and the slope of the second hardness gradient is less than the slope of the first hardness gradient such that a ratio of the first and second slopes is 0.8 to 0.85.
1. A golf ball comprising:
an inner core layer comprising a thermoplastic highly-neutralized ionomer comprising a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 70% or greater, and having a geometric center hardness less than a surface hardness to define a first positive hardness gradient;
an outer core layer disposed about the inner core, the outer core being formed from a homogenous thermoset composition and having an interior hardness less than an outer surface hardness to define a second positive hardness gradient;
an inner cover layer disposed about outer core layer; and
an outer cover layer disposed about the inner cover layer,
wherein the second hardness gradient is greater than or equal to the first hardness gradient.
2. The golf ball of claim 1 , wherein the acid groups of the copolymer are neutralized by 80% or greater.
3. The golf ball of claim 2 , wherein the acid groups of the copolymer are neutralized by 90% or greater.
4. The golf ball of claim 3 , wherein the acid groups of the copolymer are neutralized by about 100%.
5. The golf ball of claim 1 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.
6. The golf ball of claim 5 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.
7. The golf ball of claim 5 , wherein the organic acid or salt thereof comprises a magnesium salt of oleic acid.
8. A golf ball comprising:
an inner core layer comprising a thermoplastic highly-neutralized ionomer comprising a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 70% or greater, and having a geometric center hardness less than a surface hardness to define a first positive hardness gradient;
an outer core layer disposed about the inner core, the outer core being formed from a homogenous thermoset composition and having an interior hardness less than an outer surface hardness to define a second positive hardness gradient;
an inner cover layer disposed about outer core layer; and
an outer cover layer disposed about the inner cover layer,
wherein the first and second hardness gradients each have a slope and the slope of the first hardness gradient is greater than about 1.0 and the slope of the second hardness gradient is less than about 1.0.
9. The golf ball of claim 8 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.
10. The golf ball of claim 9 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.
11. The golf ball of claim 9 , wherein the organic acid or salt thereof comprises a magnesium salt of oleic acid.
12. The golf ball of claim 8 , wherein the acid groups of the copolymer are neutralized by 80% or greater.
13. The golf ball of claim 12 , wherein the acid groups of the copolymer are neutralized by about 100%.