Process for the manufacture of polycarbonate compositions
View Patent ↗A continuous process for the manufacture of a polycarbonate comprises: combining an aromatic dihydroxy compound stream and a diaryl carbonate stream to form a mixture; controlling a weight or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound by: measuring a sound velocity, Vs, in the mixture at an operating temperature of the controlling step; and determining the weight or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound in the mixture; and adjusting a flow rate of at least one of the aromatic dihydroxy compound stream and the diaryl carbonate stream, if needed, to achieve a desired weight or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound; and polymerizing the aromatic dihydroxy compound and the diaryl carbonate in the presence of a catalyst to produce the polycarbonate.
1. A process for monitoring a relative level of an aromatic dihydroxy compound or a diaryl carbonate in a mixture comprising the aromatic dihydroxy compound and the diaryl carbonate, the process comprising:
measuring a sound velocity, Vs, in the mixture at an operating temperature of the process; and
determining the relative level of the aromatic dihydroxy compound or the diaryl carbonate in the mixture based on Equation 1, 2, 3 or 4:
WP1 =a+b×Vs (Equation 1)
WP2=100−( a+b×Vs ) (Equation 2)
WR=[100−( a+b×Vs )]/( a+b×Vs ) (Equation 3)
MR=(Mw1/Mw2)×[100−( a+b×Vs )]/( a+b×Vs ) (Equation 4)
wherein
WP1 is the weight percent of the aromatic dihydroxy compound in the mixture,
WP2 is the weight percent of the diaryl carbonate in the mixture,
Mw1 is the molecular weight of the aromatic dihydroxy compound,
Mw2 is the molecular weight of the diaryl carbonate,
WR is the weight ratio of the diaryl carbonate to the aromatic dihydroxy compound,
MR is the molar ratio of the diaryl carbonate to the aromatic dihydroxy compound, and a and b are constants.
2. The process of claim 1 , further comprising:
calculating the weight ratio WR or molar ratio MR of the diaryl carbonate to the aromatic dihydroxy compound;
comparing the calculated weight ratio WR or molar ratio MR to a desired weight ratio or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound; and
if needed, adjusting the amount of the aromatic dihydroxy compound or the amount of the diaryl carbonate added to the mixture to achieve the desired weight ratio WR or molar ratio MR.
3. The process of claim 1 , further comprising mixing the mixture before determining the sound velocity.
4. The process of claim 1 , wherein the mixture is a binary mixture of the aromatic dihydroxy compound and the diaryl carbonate.
5. The process of claim 1 , wherein the sound velocity in the mixture is measured through an ultrasound meter.
6. The process of claim 1 , wherein a and b are temperature-dependent constants; and wherein a and b are determined by measuring the sound velocity in diaryl carbonate and dihydroxy aromatic compound mixtures having known diaryl carbonate and dihydroxy aromatic molar or weight ratio at the operating temperature and regressing a linear model.
7. The process of claim 1 , wherein the sound velocity is measured before any substantial reaction between the aromatic dihydroxy compound and the diaryl carbonate takes place.
8. The process of claim 1 , wherein the aromatic dihydroxy compound is bisphenol A, and the diaryl carbonate is diphenyl carbonate.
9. The process of claim 1 , wherein the operating operation temperature is fixed within ±1° C. of a constant value.
10. A continuous process for the manufacture of a polycarbonate comprising:
combining an aromatic dihydroxy compound stream and a diaryl carbonate stream to form a mixture;
controlling a weight or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound by:
measuring a sound velocity, Vs, in the mixture at an operating temperature of the controlling step; and
determining the weight or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound in the mixture based on Equation 3 or Equation 4:
WR=[100−( a+b×Vs )]/( a+b×Vs ) (Equation 3)
MR=(Mw1/Mw2)×[100−( a+b×Vs )]/( a+b×Vs ) (Equation 4)
wherein Mw1 is the molecular weight of the aromatic dihydroxy compound, Mw2 is the molecular weight of the diaryl carbonate, WR is the weight ratio of the diaryl carbonate to the aromatic dihydroxy compound, MR is the molar ratio of the diaryl carbonate to the aromatic dihydroxy compound, and a and b are constants; and
adjusting a flow rate of at least one of the aromatic dihydroxy compound stream and the diaryl carbonate stream, if needed, to achieve a desired weight or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound; and
polymerizing the aromatic dihydroxy compound and the diaryl carbonate in the presence of a catalyst to produce the polycarbonate.
11. The process of claim 10 , further comprising adding a catalyst stream to the mixture, and adding the mixture to a monomer pre-mixer.
12. The process of claim 10 , wherein adjusting the flow rate comprises adjusting opening of a valve controlling the flow of at least one of the diaryl carbonate and the aromatic dihydroxy compound.
13. A polycarbonate manufactured by the process of claim 10 .
14. The polycarbonate of claim 13 , wherein the standard deviation of a determined weight ratio WR or molar ratio MR to a desired weight ratio or molar ratio is less than 0.02; and
an article made from the polycarbonate has a delta yellowness index of less than 5 units after the article is exposed to a temperature of 130° C. for 800 hours.
15. The polycarbonate of claim 14 , wherein an article made from the polycarbonate has a delta yellowness index of less than 2 units after the article is exposed to a temperature of 130° C. for 200 hours.
16. The process of claim 10 , wherein the standard deviation of a determined weight ratio WR or molar ratio MR to a desired weight ratio or molar ratio is less than 0.005.
17. A process for monitoring a relative level of an aromatic dihydroxy compound or a diaryl carbonate in a mixture comprising the aromatic dihydroxy compound and the diaryl carbonate, the process comprising:
measuring a sound velocity, Vs, in the mixture at an operating temperature of the process; and
determining the relative level of the aromatic dihydroxy compound or the diaryl carbonate in the mixture based on Equation 1, 2, 3 or 4:
WP1 =a+b×Vs (Equation 1)
WP2=100−( a+b×Vs ) (Equation 2)
WR=[100−( a+b×Vs )]/( a+b×Vs ) (Equation 3)
MR=(Mw1/Mw2)×[100−( a+b×Vs )]/( a+b×Vs ) (Equation 4)
wherein
WP1 is the weight percent of the aromatic dihydroxy compound in the mixture,
WP2 is the weight percent of the diaryl carbonate in the mixture,
Mw1 is the molecular weight of the aromatic dihydroxy compound,
Mw2 is the molecular weight of the diaryl carbonate,
WR is the weight ratio of the diaryl carbonate to the aromatic dihydroxy compound,
MR is the molar ratio of the diaryl carbonate to the aromatic dihydroxy compound, and
a and b are constants, further comprising:
calculating the weight ratio WR or molar ratio MR of the diaryl carbonate to the aromatic dihydroxy compound;
comparing the calculated weight ratio WR or molar ratio MR to a desired weight ratio or molar ratio of the diaryl carbonate to the aromatic dihydroxy compound; and
if needed, adjusting the amount of the aromatic dihydroxy compound or the amount of the diaryl carbonate added to the mixture to achieve the desired weight ratio WR or molar ratio MR, wherein the standard deviation of a calculated weight ratio WR or molar ratio MR to a desired weight ratio or molar ratio is less than 0.02.
18. The process of claim 17 , wherein the standard deviation of a calculated weight ratio WR or molar ratio MR to a desired weight ratio or molar ratio is less than 0.005.
19. The polycarbonate of claim 13 , wherein the standard deviation of a determined weight ratio WR or molar ratio MR to a desired weight ratio or molar ratio is less than 0.005.