Cathode active material for lithium secondary battery
View Patent ↗Provided is a lithium transition metal oxide having an α-NaFeO 2 layered crystal structure, as a cathode active material for lithium secondary battery, wherein the transition metal includes a blend of Ni and Mn, an average oxidation number of the transition metals except lithium is +3 or higher, and the lithium transition metal oxide satisfies Equations 1 and 2: 1.0< m (Ni)/ m (Mn) (1) m (Ni 2+ )/ m (Mn 4+ )<1 (2) wherein m(Ni)/m(Mn) represents a molar ratio of nickel to manganese and m (Ni 2+ )/m (Mn 4+ ) represents a molar ratio of Ni 2+ to Mn 4+ . The cathode active material of the present invention has a uniform and stable layered structure through control of oxidation number of transition metals to a level higher than +3, in contrast to conventional cathode active materials, thus advantageously exerting improved overall electrochemical properties including electric capacity, in particular, superior high-rate charge/discharge characteristics.
1. A lithium transition metal oxide having an α-NaFeO 2 layered crystal structure, as a cathode active material for lithium secondary battery, wherein the transition metal includes a blend of Ni and Mn, an average oxidation number of the transition metals except lithium is +3 or higher, and the lithium transition metal oxide satisfies Equation 1 below:
1.0 <m (Ni)/ m (Mn) (1)
wherein the content of nickel intercalated into the lithium site is lower than 5 mol % but greater than zero, and m (Ni)/m (Mn) represents a molar ratio of nickel to manganese.
2. The cathode active material according to claim 1 , wherein the average oxidation number of transition metals is higher than 3.0 and not higher than 3.5.
3. The cathode active material according to claim 2 , wherein the average oxidation number of the transition metals except lithium is 3.01 to 3.3.
4. The cathode active material according to claim 2 , wherein the average oxidation number of the transition metals except lithium is 3.1 to 3.3.
5. The cathode active material according to claim 1 , wherein the nickel is composed of nickel (a) present in an excessive amount, as compared to the manganese content and nickel (b) present in an amount corresponding to the manganese content.
6. The cathode active material according to claim 5 , wherein the nickel (b) present in an amount corresponding to the manganese content contains Ni 2+ and Ni 3+ .
7. The cathode active material according to claim 5 , wherein the nickel (a) is present in an excessive amount as compared to the manganese content is Ni 3+ .
8. A cathode comprising the cathode active material according to claim 1 .
9. A lithium secondary battery comprising the cathode according to claim 8 .
10. The cathode active material according to claim 1 , the α-NaFeO 2 layered crystal structure comprises a lithium containing Li-oxide layer and a transition metal-containing transition metal oxide layer, wherein the content of nickel intercalated into lithium sites is lower than 5 mol % but greater than zero.
11. The cathode active material according to claim 1 , wherein the nickel is composed of nickel (a) present in an excessive amount, as compared to the manganese content and nickel (b) present in an amount corresponding to the manganese content, wherein the nickel (b) present in an amount corresponding to the manganese content comprises Ni 2+ and Ni 3+ , and wherein the nickel (a) is present in an excessive amount as compared to the manganese content is Ni 3+ .