Latex primer composition and latex primed substrates
View Patent ↗A first polymer latex and second polymer latex can be mixed to form a dried primer layer on a substrate to adhere patterned materials having fine lines. The first polymer latex comprises a first polymer and a first surfactant such that a dried coating of the first polymer latex has a surface polarity of at least 50%. The second polymer latex comprises a second polymer and a second surfactant such that a dried coating of the second polymer latex has a surface polarity of less than or equal to 27%. Moreover, a dried coating of the mixture has a surface polarity of at least 15% and up to and including 50%. Primed substrates are useful for preparing electrically-conductive articles having electrically-conductive fine lines directly on a dried primer layer by applying a patterned material to a substrate. Such articles can be used as touch screen displays in various electronic devices.
1. A composition comprising a mixture of a first polymer latex and a second polymer latex,
wherein the first polymer latex comprises a first polymer and a first surfactant such that a dried coating of the first polymer latex has a surface polarity of at least 50%, and
wherein the second polymer latex comprises a second polymer and a second surfactant such that a dried coating of the second polymer latex has a surface polarity of less than or equal to 27%, and
wherein a dried coating of the composition has a surface polarity of at least 15% and up to and including 50%,
wherein the weight ratio of the first polymer latex to the second polymer latex in the composition is from 1:3 and to and including 3:1,
wherein:
the first polymer comprises at least 75 weight % and up to and including 90 weight % of recurring units derived from glycidyl (meth)acrylate and at least 10 weight % and up to and including 25 weight % of recurring units derived from n-butyl (meth)acrylate, based on the total first polymer weight, which first polymer has a glass transition temperature of at least 25° C. and up to and including 75° C., and the first surfactant is a sodium α-olefin (C 14 -C 16 ) sulfonate:
the second polymer comprises at least 75 weight % and up to and including 90 weight % of recurring units derived from glycidyl (meth)acrylate and at least 10 weight % and up to and including 25 weight % of recurring units derived from n-butyl (meth)acrylate, based on the total second polymer weight, which second polymer has a glass transition temperature of at least 25° C. and up to and including 75° C., and the second surfactant is an ammonium salt of a sulfated polyethoxy nonylphenol;
the first surfactant is present in a dried coating of the mixture in an amount of at least 1 weight % and up to and including 3 weight %, based on total dry coating weight;
the second surfactant is present in a dried coating of the mixture in an amount of at least 0.35 weight % and up to and including 1.1 weight %, based on the total dry coating weight; and
the total amount of the first and second surfactants in a dry coating of the mixture is less than 3.35 weight %, based on the total dry coating weight.
2. The composition of claim 1 , wherein a dried coating of the composition has a surface polarity of at least 28% and up to and including 50%.
3. A substrate comprising a support and a dried primer layer disposed on at least one supporting surface of the support, the dried primer layer comprising a mixture of:
a first polymer latex comprising a first polymer and a first surfactant such that a dried coating the first polymer latex has a surface polarity of at least 50%, and
a second polymer latex comprising a second polymer and a second surfactant that is different from the first surfactant such that a dried coating of the second polymer latex has a surface polarity of less than or equal to 27%,
wherein the dried primer layer has a surface polarity of at least 15% and up to and including 50%,
wherein the weight ratio of the first polymer latex to the second polymer latex in the dried primer layer is from 1:3 and to and including 3:1, and the first surfactant comprises a sodium α-olefin (C 14 -C 16 ) sulfonate, and the second surfactant comprises an ammonium salt of a sulfated polyethoxy nonylphenol.
4. The substrate of claim 3 that has an integrated transmittance of at least 88%.
5. The substrate of claim 3 comprising a transparent polymeric support and having the dried primer layer disposed directly thereon.
6. The substrate of claim 3 , wherein at least one of the first polymer and the second polymer comprises a vinyl polymer comprising recurring units derived at least from glycidyl (meth)acrylate.
7. The substrate of claim 6 , wherein each of the first polymer latex and the second polymer latex comprises a vinyl polymer independently comprising at least 75 weight % and up to and including 90 weight % of recurring units derived from glycidyl (meth)acrylate, based on the total weight of the vinyl polymer.
8. The substrate of claim 7 , wherein at least one of the first polymer latex and the second polymer latex comprises a vinyl polymer further comprising recurring units derived from an alkyl (meth)acrylate having an ester alkyl group having at least 2 carbon atoms.
9. The substrate of claim 3 , wherein at least one of the first polymer and the second polymer is crosslinked.
10. The substrate of claim 3 , wherein the first polymer and the second polymer independently have glass transition temperatures of at least 25° C.
11. The substrate of claim 3 , wherein the first surfactant is a compound represented by R—CH 2 —CH═CH—CH 2 —S(═O) 2 O.Na + wherein R is a C 10 , C 11 , or C 12 hydrocarbon group, or mixtures of such compounds with different R groups that are any of C 10 to C 12 hydrocarbons groups; and the second surfactant is represented by R′-phenyl-(O—CH 2 CH 2 ) n —S(═O)O 2 − NH 4 + wherein R′ is a C 8 to C 12 hydrocarbon group, and n is 3 to 10.
12. The substrate of claim 3 , wherein the first surfactant is present in the dried primer layer in an amount of at least 1 weight % and up to and including 3 weight %, and the second surfactant is present in the dried primer layer in an amount of at least 0.35 weight % and up to and including 1.1 weight %, both based on the total dried primer layer weight.
13. The substrate of claim 3 , wherein the total amount of the first and second surfactants in the dried primer layer is up to and including 3.35 weight %, based on the total dried primer layer weight.
14. The substrate of claim 3 , wherein the dried primer layer has an average thickness of at least 0.05 μm and up to and including 0.4 μm.
15. The substrate of claim 3 , comprising a poly(ethylene terephthalate) or poly(ethylene naphthalate) support.
16. A transparent polymeric substrate comprising a transparent polyester support and a dried primer layer disposed directly on at least one supporting surface of the transparent polyester support,
wherein:
(i) the transparent polymeric substrate has an integrated transmittance of at least 88%;
(ii) the dried primer layer has an average thickness of at least 0.05 μm and up to and including 0.4 μm, and comprises a mixture of:
a first polymer latex comprising a first polymer and a first surfactant, wherein the first polymer comprises at least 75 weight % and up to and including 90 weight % of recurring units derived from glycidyl (meth)acrylate and at least 10 weight % and up to and including 25 weight % of recurring units derived from n-butyl (meth)acrylate, based on the total first polymer weight, which first polymer has a glass transition temperature of at least 25° C. and up to and including 75° C., and the first surfactant is a sodium α-olefin (C 14 -C 16 ) sulfonate; and
a second polymer latex comprising a second polymer and a second surfactant that is different from the first surfactant, wherein the second polymer comprises at least 75 weight % and up to and including 90 weight % of recurring units derived from glycidyl (meth)acrylate and at least 10 weight % and up to and including 25 weight % of recurring units derived from n-butyl (meth)acrylate, based on the total second polymer weight, which second polymer has a glass transition temperature of at least 25° C. and up to and including 75° C., and the second surfactant is an ammonium salt of a sulfated polyethoxy nonylphenol;
(iii) the dried primer layer has a surface polarity of at least 28% and up to and including 50%;
(iv) the weight ratio of the first polymer latex to the second polymer latex in the dried primer layer is from 1:3 and to and including 3:1;
(v) the first surfactant is present in the dried primer layer in an amount of at least 1 weight % and up to and including 3 weight %, based on total dried primer weight;
(vi) the second surfactant is present in the dried primer layer in an amount of at least 0.35 weight % and up to and including 1.1 weight %, based on the total dried primer layer; and
(vii) the total amount of the first and second surfactants in the dried primer layer is less than 3.35 weight %, based on the total dried primer layer weight.