Glass substrate for display cover glass and its production process
View Patent ↗To provide a glass substrate for a display cover glass not only having excellent strength and antibacterial properties but also having a high transparency and a high visible transmittance suitable as a cover glass for a display device. A glass substrate for a display cover glass, which comprises a surface compressive stress layer and an antibacterial substance-containing layer formed on the glass substrate surface, characterized by having a ratio (T 1 /T 2 ) of the transmittance T 1 at a wavelength of 428 nm to the transmittance T 2 at a wavelength of 650 nm of the glass substrate of at least 0.95, and a transmittance at a wavelength of 428 nm of at least 86% when the thickness of the glass substrate is from 0.1 to 3.0 mm.
1. A glass substrate for a display cover glass, which comprises a surface compressive stress layer and an antibacterial substance-containing layer on the glass substrate surface, wherein the glass substrate has a ratio (T 1 /T 2 ) of the transmittance T 1 at a wavelength of 428 nm to the transmittance T 2 at a wavelength of 650 nm of the glass substrate of at least 0.95, and a transmittance at a wavelength of 428 nm of at least 86% when the thickness of the glass substrate is from 0.1 to 3.0 mm, and
wherein the antibacterial substance-containing layer is a silver ion diffusion layer having silver ions diffused in the glass substrate surface and the silver is present in an amount of from 0.2 to 100 μg/cm 2 at a depth of 40 μm from the glass substrate surface.
2. The glass substrate for a display cover glass according to claim 1 , wherein the glass substrate has a glass composition comprising, as represented by mol % as calculated as oxides, from 55 to 80% of SiO 2 , from 0.1 to 15% of Al 2 O 3 , from 0 to 15% of B 2 O 3 , from 0 to 10% of ZnO, from 0.1 to 15% of Na 2 O, from 0 to 10% of K 2 O, and from 0 to 16% of MgO+CaO.
3. The glass substrate for a display cover glass according to claim 1 , wherein the surface compressive stress layer on the glass substrate surface is formed by chemical tempering, and the surface compressive stress layer has a depth of at least 3 μm and a surface compressive stress of a least 250 MPa.
4. The glass substrate for a display cover glass according to claim 1 , wherein the silver ion diffusion layer has a silver amount of from 0.4 to 80 μg/cm 2 at a depth of 40 μm from the glass substrate surface.
5. The glass substrate for a display cover glass according to claim 1 , wherein the glass substrate is plate-formed by a float process.
6. The glass substrate for a display cover glass according to claim 1 , wherein the silver ion diffusion layer has a silver amount of from 0.6 to 60 μg/cm 2 at a depth of 40 μm from the glass substrate surface.
7. The glass substrate for a display cover glass according to claim 1 , wherein the silver ion diffusion layer has a silver amount of from 0.8 to 20 μg/cm 2 at a depth of 40 μm from the glass substrate surface.
8. The glass substrate for a display cover glass according to claim 1 , wherein the silver ion diffusion layer has a silver amount of from 1 to 15 μg/cm 2 at a depth of 40 μm from the glass substrate surface.
9. The glass substrate for a display cover glass according to claim 2 , wherein the amount of SiO 2 in said glass substrate, as represented by mol % as calculated as oxides, is from 60 to 75%.
10. The glass substrate for a display cover glass according to claim 2 , wherein the amount of Al 2 O 3 in said glass substrate, as represented by mol % as calculated as oxides, is from 1 to 11%.
11. The glass substrate for a display cover glass according to claim 2 , wherein the amount of B 2 O 3 in said glass substrate, as represented by mol % as calculated as oxides, is from 0 to 10%.
12. The glass substrate for a display cover glass according to claim 2 , wherein the amount of ZnO in said glass substrate, as represented by mol % as calculated as oxides, is from 0 to 8%.
13. The glass substrate for a display cover glass according to claim 2 , wherein the amount of Na 2 O in said glass substrate, as represented by mol % as calculated as oxides, is from 3 to 14%.
14. The glass substrate for a display cover glass according to claim 2 , wherein the amount of K 2 O in said glass substrate, as represented by mol % as calculated as oxides, is from 0.1 to 8%.
15. The glass substrate for a display cover glass according to claim 2 , wherein the amount of MgO+CaO in said glass substrate, as represented by mol % as calculated as oxides, is from 0 to 15%.
16. A display device having a glass substrate for a display cover glass as a front glass of a display, which comprises a surface compressive stress layer and an antibacterial layer on the glass substrate surface, wherein the glass substrate has a ratio (T 1 /T 2 ) of the transmittance T 1 at a wavelength of 428 nm to the transmittance T 2 at a wavelength of 650 nm of the glass substrate of at least 0.95, and a transmittance at a wavelength of 428 nm of at least 86% when the thickness of the glass substrate is from 0.1 to 3.0 mm, and wherein the antibacterial substance-containing layer is a silver ion diffusion layer having silver ions diffused in the glass substrate surface and the silver ions present in an amount of from 0.2 to 100 μg/cm 2 at a depth of 40 μm from the glass substrate surface.