IP Library Granted Patent US 8,987,537
Granted Patent B1
US 8,987,537 · App. 14/313,216 · Granted Mar 24, 2015

Fuel compositions

Inventors: Danny F. Droubi (Houston, TX); Michael Allen Branch (Spring, TX); Cynthia Delaney-Kinsella (Houston, TX); Dana Tatum Lipinsky (Houston, TX); Lawrence Stephen Kraus (Dickinson, TX); Tommy Louis Brumfield (Spring, TX); Ariel Bru (Ryswijk, NL); Koen Steernberg (Amsterdam, NL); Pierre Tardif (Houston, TX); Shannon Boudreaux (Houston, TX)
Assignee: Shell Oil Company
C10L1/04
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Quick Facts
Patent No.
US 8,987,537
App. No.
14/313,216
Granted
Mar 24, 2015
Kind
B1
Abstract

Low sulphur marine fuel compositions are provided. Embodiments comprise greater than 50 to 90 wt % of a residual hydrocarbon component, with the remaining 10 and up to 50 wt % selected from a non-hydroprocessed hydrocarbon component, a hydroprocessed hydrocarbon component, and a combination thereof. Embodiments of the marine fuel composition can have a sulphur content of about 0.1 wt % or less.

Claims (24)

1. A marine fuel composition comprising:

60 to 90 wt % of an atmospheric tower bottoms (ATB) residual hydrocarbon component; and

the remaining 10 to 40 wt % of comprising a hydroprocessed hydrocarbon component selected from a group consisting of low-sulfur diesel (LSD) having a sulphur content of less than 500 wppm, ultra low-sulfur diesel (ULSD) having a sulphur content of less than 15 wppm; hydrotreated LCO; hydrotreated HCO; hydrotreated pyrolysis gas oil, hydrotreated thermally cracked heavy distillate, hydrotreated thermally cracked gas oil, hydrocracker diesel, and any combination thereof.

2. The marine fuel composition of claim 1 wherein the sulphur content of the marine fuel composition is in a range of 400 to 1000 wppm.

3. The marine fuel composition of claim 1 which exhibits at least one of the following:

a hydrogen sulfide content of at most 2.0 mg/kg; an acid number of at most 2.5 mg KOH per gram; a sediment content of at most 0.1 wt %; a water content of at most 0.5 vol %; and an ash content of at most 0.15 wt %.

4. The marine fuel composition of claim 1 which has at least one of the following: a density at 15 degrees C. in a range of 0.870 to 1.010 g/cm 3 , a kinematic viscosity at 50 degrees C. in a range of 1 to 700 cSt, a pour point of −30 to 35 degrees C., and a flash point of at least 60 degrees C.

5. The marine fuel composition of claim 1 wherein the ATB residual hydrocarbon component has a sulfur content of at most 0.4 wt %.

6. The marine fuel composition of claim 1 wherein the ATB residual hydrocarbon component has a sulfur content of at most 0.2 wt %.

7. The marine fuel composition of claim 1 wherein the ATB residual hydrocarbon component exhibits at least one of the following: a pour point in a range of −19.0 to 64 degrees C., a flash point in a range of 80 to 213 degrees C.; an acid number of up to 8.00 mgKOH/g; a density at ˜15 degrees C. of at most about 1.0 g/cc; and a kinematic viscosity at ˜50 degrees C. in a range of 1.75 to 15000 cSt.

8. The marine fuel composition of claim 1 wherein the ATB residual hydrocarbon component comprises a first type of ATB residual hydrocarbon component which exhibits at least one of the following: a pour point of about 45 degrees C., a flash point of about 124 degrees C.; a density at ˜15 degrees C. of about 0.91 g/cm 3 , and a kinematic viscosity at ˜50 degrees C. of about 165 cSt.

9. The marine fuel composition of claim 8 comprising at least 60% of the first type of ATB residual hydrocarbon component.

10. The marine fuel composition of claim 8 wherein the ATB residual hydrocarbon component comprises a second type of ATB residual hydrocarbon component (ATB) which exhibits at least one of the following: a pour point of about −2 degrees C., a flash point of about 207 degrees C.; a density at ˜15 degrees C. of about 0.94 g/cm 3 , and a kinematic viscosity at ˜50 degrees C. of about 880 cSt.

11. The marine fuel composition of claim 10 comprising at least 20 wt % of the first type of ATB residual hydrocarbon component and at least 30wt % of the second type of ATB residual hydrocarbon component.

12. The marine fuel composition of claim 10 comprising at least 32 wt % of the second type of ATB residual hydrocarbon component.

13. The marine fuel composition of claim 10 comprising at least 32 wt % of the first type of ATB residual hydrocarbon component.

14. The marine fuel composition of claim 1 comprising at least 70 wt % of the ATB residual hydrocarbon component.

15. The marine fuel composition of claim 1 comprising at least 80 wt % of the ATB residual hydrocarbon component.

16. The marine fuel composition of claim 1 comprising 90 wt % of the ATB residual hydrocarbon component.

17. The marine fuel composition of claim 1 wherein the remaining 10 to 40 wt % further comprises a non-hydroprocessed hydrocarbon component selected from a group consisting of light cycle oil (LCO), heavy cycle oil (HCO), fluid catalytic cracking (FCC) cycle oil, FCC slurry oil, pyrolysis gas oil, cracked light gas oil (CLGO), cracked heavy gas oil (CHGO), pyrolysis light gas oil (PLGO), pyrolysis heavy gas oil (PHGO), thermally cracked residue, thermally cracked heavy distillate, coker heavy distillates, and any combination thereof.

18. The marine fuel composition of claim 1 wherein the remaining 10 to 40 wt % further comprises a non-hydroprocessed hydrocarbon component selected from a group consisting of vacuum gas oil (VGO), coker diesel, coker gas oil, coker VGO, thermally cracked VGO, thermally cracked diesel, thermally cracked gas oil, Group I slack waxes, lube oil aromatic extracts, deasphalted oil (DAO), and any combination thereof.

19. The marine fuel composition of claim 1 wherein the remaining 10 to 40 wt % further comprises a non-hydroprocessed hydrocarbon component is from a group consisting of coker kerosene, thermally cracked kerosene, gas-to-liquids (GTL) wax, GTL hydrocarbons, straight-run diesel, straight-run kerosene, straight run gas oil (SRGO), and any combination thereof.

20. The marine fuel composition of claim 1 wherein the remaining 10 to 40 wt % further comprising a hydroprocessed hydrocarbon component is selected from a group consisting of hydrotreated coker diesel, hydrotreated coker gas oil, hydrotreated thermally cracked diesel, hydrotreated VGO, hydrotreated coker VGO, hydrotreated residues, hydrocracker bottoms, hydrotreated thermally cracked VGO, and hydrotreated DAO, and any combination thereof.

21. The marine fuel composition of claim 1 wherein the remaining 10 to 40 wt % further comprising a hydroprocessed hydrocarbon component is selected from a group consisting of ultra low sulfur kerosene (ULSK), hydrotreated jet fuel, hydrotreated kerosene, hydrotreated coker kerosene, hydrocracker kerosene, hydrotreated thermally cracked kerosene, and any combination thereof.

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 11, 2015
From: DROUBI, DANNY F.; BRANCH, MICHAEL ALLEN; DELANEY-KINSELLA, CYNTHIA; LIPINSKY, DANA TATUM; KRAUS, LAWRENCE STEPHEN; BRUMFIELD, TOMMY LOUIS; BRU, ARIEL; STEERNBERG, KOEN; BOUDREAUX, SHANNON; TARDIF, PIERRE
To: SHELL OIL COMPANY
Reel/Frame 034940/0487 →
Continuity (1)
Provisional Application 62002005 · May 22, 2014