IP Library Granted Patent US 12,497,737
Granted Patent B2
US 12,497,737 · App. 14/316,262 · Granted Dec 16, 2025

Filter media

Inventors: Jiayi Pan (Le Mans, FR); Christophe Le Moigne (Le Mans, FR); Nathalie Durot (Le Mans, FR); Michel Barale (Le Mans, FR); Stephane Derrien (Le Mans, FR)
Assignee: SWM Holdings US, LLC
D21H27/08A24D3/08A24D3/14B01D39/18B65D85/808D21H17/53B01D2239/04
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,497,737
App. No.
14/316,262
Granted
Dec 16, 2025
Kind
B2
Abstract

A filter element is disclosed made from a gathered paper web that may be crimped, embossed, and/or corrugated. In accordance with the present disclosure, the paper web is treated with at least two different additives. The first additive comprises amphiphilic molecules, having hydrophilic and hydrophobic ends such as a ketene dimer that has one or more branching groups. The second additive, on the other hand, may comprise a polymer component such as a polyalkylene glycol. The filter element may also be treated with a polyamine or an amino acid or salt thereof. In one embodiment, the filter element may be incorporated into the filter of a smoking article. The two additives together may improve smoke taste, reduce some smoke phenols, and reduce some smoke carbonyls.

Claims (38)

1 . A filter element comprising:

a base web containing wood pulp fibers, other plant fibers, or mixtures thereof, the base web being combined with at least a first additive and a second additive, the first additive being combined with the base web as a size,

the first additive comprising a compound having one of the following structures:

wherein R1 and R2 of the first additive comprise alkyl or alkenyl groups; and

the second additive comprising a polyether, monopropylene glycol, sorbitol, glycerin, or mixtures thereof, the second additive having been applied to a surface of the base web, wherein the second additive is present on the surface of the base web in a pattern that covers from about 10% to about 90% of the surface area of the surface of the base web;

wherein the first additive is present in the base web in an amount of from 18% to about 30% by weight of the base web and wherein the second additive is present in the base web in an amount of from about 15% by weight to about 25% by weight of the base web;

wherein the base web is gathered, crimped, embossed, corrugated, or combinations thereof, into a rod form;

wherein the base web is free of synthetic fibers, wherein the base web of the filter element is continuous.

2 . A filter element as defined in claim 1 , wherein the first additive comprises an alkyl ketene dimer or alkenyl ketene dimer and wherein the second additive comprises a polyalkylene glycol.

3 . A filter element as defined in claim 2 , wherein the polyalkylene glycol has an average molecular weight of greater than about 500 g/mol.

4 . A filter element as defined in claim 2 , wherein the polyalkylene glycol comprises a polyethylene oxide, a methoxypolyethylene glycol, a polyethylene glycol derivative, or mixtures thereof.

5 . A filter element as defined in claim 2 , wherein the first additive is added to the base web, and wherein the first additive is present in the base web in an amount from about 20% to about 30% by weight of the base web.

6 . A filter element as defined in claim 1 , wherein the base web has a basis weight of from about 10 gsm to about 200 gsm.

7 . A filter element as defined in claim 1 , wherein the base web contains wood fibers or flax fibers.

8 . A filter element as defined in claim 1 , wherein the base web comprises reconstituted tobacco base sheet or reconstituted tobacco.

9 . A filter element as defined in claim 1 , wherein the base web further contains an amino acid, a peptide, or a salt of an amino acid.

10 . A filter element as defined in claim 1 , wherein the base web further contains a glycinate.

11 . A smoking article comprising:

a column of tobacco;

a wrapping paper surrounding the column of tobacco;

a filter located adjacent to one end of the column of tobacco, the filter comprising a first segment and a second segment, wherein the first segment comprises the filter element of claim 1 ; and

a tipping paper attaching the filter to the column of tobacco.

12 . A smoking article as defined in claim 11 , wherein the filter removes at least 10% of phenol from mainstream smoke passing through the filter.

13 . A smoking article as defined in claim 11 , wherein the filter removes at least 10% of cresols from mainstream smoke passing through the filter.

14 . A smoking article as defined in claim 11 , wherein the filter removes at least 10% of crotonaldehyde from mainstream smoke passing through the filter.

15 . An air filter comprising the filter element as defined in claim 1 .

16 . A tea product comprising tea leaves and a filter, the filter comprising a filter element as defined in claim 1 .

17 . A coffee filter comprising the filter element as defined in claim 1 .

18 . A filter element as defined in claim 1 , wherein the first additive comprises a compound having one of the following structures:

wherein R1 and R2 of the first additive comprise alkyl groups having a carbon chain length of from about 12 carbon atoms to about 28 carbon atoms.

19 . A filter element comprising:

a base web containing wood pulp fibers, other plant fibers, or mixtures thereof, the base web being combined with at least a first additive and a second additive, the first additive being combined with the base web as a size, the first additive comprising a compound having one of the following structures:

wherein R1 and R2 of the first additive comprise alkyl groups having a carbon chain length of from about 12 carbon atoms to about 28 carbon atoms; and

the second additive comprising a polyether, monopropylene glycol, sorbitol, glycerin, or mixtures thereof, the second additive having been applied to a surface of the base web, wherein the second additive is present on the surface of the base web in a pattern that covers from about 10% to about 90% of the surface area of the surface of the base web;

wherein the first additive is present in the base web in an amount of from 18% to about 30% by weight of the base web and wherein the second additive is present in the base web in an amount of from about 15% by weight to about 25% by weight of the base web;

wherein the base web is gathered, crimped, embossed, corrugated, or combinations thereof, into a rod form;

wherein the base web is free of synthetic fibers, wherein the base web of the filter element is continuous.

20 . A filter element as defined in claim 19 , wherein the first additive comprises an alkyl ketene dimer and wherein the second additive comprises a polyalkylene glycol.

Assignments (13)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 21, 2025
From: MATIV HOLDINGS, INC.
To: SWM HOLDINGS US, LLC
Reel/Frame 073143/0724 →
RELEASE OF SECURITY INTEREST Recorded Nov 30, 2023
From: JPMORGAN CHASE BANK, N.A.
To: MATIV HOLDINGS, INC. FKA SCHWEITZER-MAUDUIT INTERNATIONAL, INC.
Reel/Frame 065709/0802 →
CHANGE OF NAME Recorded Feb 9, 2023
From: SCHWEITZER-MAUDUIT INTERNATIONAL, INC.
To: MATIV HOLDINGS, INC.
Reel/Frame 062693/0467 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2021
From: DERRIEN, STEPHANE
To: PMD INDUSTRIES
Reel/Frame 055498/0124 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2021
From: LTR INDUSTRIES
To: SWM LUXEMBOURG
Reel/Frame 055498/0167 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2021
From: SWM SERVICES
To: SCHWEITZER-MAUDUIT INTERNATIONAL, INC.
Reel/Frame 055498/0292 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2021
From: LTR INDUSTRIES
To: SCHWEITZER-MAUDUIT INTERNATIONAL, INC.
Reel/Frame 055498/0359 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2021
From: PMD INDUSTRIES
To: SCHWEITZER-MAUDUIT INTERNATIONAL, INC.
Reel/Frame 055498/0208 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2021
From: BARALE, MICHEL; PAN, JIAYI
To: SWM SERVICES
Reel/Frame 055497/0200 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2021
From: DUROT, NATHALIE; LE MOIGNE, CHRISTOPHE
To: LTR INDUSTRIES
Reel/Frame 055497/0901 →
SECURITY INTEREST Recorded Sep 26, 2018
From: SCHWEITZERMAUDUIT INTERNATIONAL, INC.; DELSTAR TECHNOLOGIES, INC.; ARGOTEC LLC; CONWED PLASTICS LLC
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 047156/0569 →
RELEASE OF SECURITY INTEREST Recorded Sep 25, 2018
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: ARGOTEC LLC; SCHWEITZER-MAUDUIT INTERNATIONAL, INC.; DELSTAR TECHNOLOGIES, INC.
Reel/Frame 047151/0287 →
SECURITY INTEREST Recorded Oct 28, 2015
From: ARGOTEC LLC; SCHWEITZER-MAUDUIT INTERNATIONAL, INC.; DELSTAR TECHNOLOGIES, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 036989/0487 →
Continuity (2)
Provisional Application 61839608 · Jun 26, 2013
Related Publication 20150001148A1 · Jan 1, 2015
References Cited (59)
US 2968306A · Touey · 1961 [cited by examiner]
US 3019794A · Whitmore · 1962 [cited by examiner]
US 3227164A · Mcconnell · 1966 [cited by examiner]
US 3353541A · Hind et al. · 1967 [cited by applicant]
US 3386449A · Hind · 1968 [cited by applicant]
US 3400723A · Muller · 1968 [cited by applicant]
US 3415253A · Michels et al. · 1968 [cited by applicant]
US 3420241A · Hind et al. · 1969 [cited by applicant]
US 3428053A · Schoenbaum et al. · 1969 [cited by applicant]
US 3467109A · Block et al. · 1969 [cited by applicant]
US 3483874A · Hind · 1969 [cited by applicant]
US 3561451A · Jacin · 1971 [cited by applicant]
US 3608564A · Takahashi · 1971 [cited by examiner]
US 3760815A · Deszyck · 1973 [cited by applicant]
US 3847164A · Mattina et al. · 1974 [cited by applicant]
US 3860012A · Selke · 1975 [cited by applicant]
US 4182349A · Selke · 1980 [cited by applicant]
US 4355995A · Berger · 1982 [cited by applicant]
US 4614546A · Schroer · 1986 [cited by examiner]
US 4674519A · Keritsis et al. · 1987 [cited by applicant]
US 5025814A · Raker · 1991 [cited by examiner]
US 5360023A · Blakley et al. · 1994 [cited by applicant]
US 5439010A · Ross · 1995 [cited by examiner]
US 5678577A · Matsumura · 1997 [cited by examiner]
US 5698627A · Obuni et al. · 1997 [cited by applicant]
US 5715844A · Young et al. · 1998 [cited by applicant]
US 5724998A · Gellatly et al. · 1998 [cited by applicant]
US 5765570A · Litzinger et al. · 1998 [cited by applicant]
US 5856006A · Asai · 1999 [cited by examiner]
US 5947126A · Wilson · 1999 [cited by examiner]
US 6310132B1 · Sackmann et al. · 2001 [cited by applicant]
US 6344239B1 · Asai · 2002 [cited by examiner]
US 6457475B1 · Tani · 2002 [cited by examiner]
US 6503604B1 · Kasahara et al. · 2003 [cited by applicant]
US 6666952B2 · Dilts et al. · 2003 [cited by applicant]
US 6676806B1 · Butt, Sr. · 2004 [cited by examiner]
US 6749721B2 · Shannon et al. · 2004 [cited by applicant]
US 7900639B2 · Perfetti et al. · 2011 [cited by applicant]
US 8333872B2 · Propst, Jr. et al. · 2012 [cited by applicant]
US 8425726B2 · Buwono et al. · 2013 [cited by applicant]
US 8434498B2 · Sebastian · 2013 [cited by applicant]
US 8597667B2 · Mou et al. · 2013 [cited by applicant]
US 20030183239A1 · Lesser · 2003 [cited by examiner]
US 20050000526A1 · Tarora et al. · 2005 [cited by applicant]
US 20060289023A1 · Von Borstel · 2006 [cited by examiner]
US 20070107865A1 · Tammi et al. · 2007 [cited by applicant]
US 20110023900A1 · Clarke · 2011 [cited by examiner]
US 20120067359A1 · Clarke · 2012 [cited by examiner]
US 20120120229A1 · Brantley · 2012 [cited by examiner]
US 20130025611A1 · Rushforth et al. · 2013 [cited by applicant]
US 20130137561A1 · Sampson · 2013 [cited by applicant]
EP 0304759A2 · 1989 [cited by examiner]
EP 606005A1 · 1994 [cited by examiner]
GB 2046572A · 1980 [cited by examiner]
GB 2075328 · 1981 [cited by applicant]
WO WO2004022850A1 · 2004 [cited by examiner]
Abstract of Chinese Publication CN 101167601 dated Apr. 30, 2008, 1, page. [cited by applicant]
Abstract of Chinese Publication CN103120364, dated May 29, 2013, 2 pages. [cited by applicant]
International Search Report PCT/IB2014/062640, dated Mar. 31, 2015, 16 pages. [cited by applicant]