Flooding operations employing chlorine dioxide
View Patent ↗A method includes introducing a treatment fluid including a first polymer gel into a subterranean formation to generate a production fluid having an aqueous portion and a hydrocarbon portion, treating the aqueous portion of the production fluid with chlorine dioxide to separate additional hydrocarbons from the aqueous portion, and adjusting the viscosity of the treated aqueous portion prior to introducing the treated aqueous portion back into the subterranean formation.
1. A method comprising:
introducing a polymer gel-containing treatment fluid into a subterranean formation under conditions of a polymer flooding operation, the polymer gel-containing treatment fluid comprising:
a water-soluble polymer;
an amount of chlorine dioxide sufficient to increase the viscosity of the treatment fluid; and
an aqueous base fluid.
2. The method of claim 1 , further comprising generating a production fluid comprising an aqueous portion and a hydrocarbon portion.
3. The method of claim 2 , further comprising treating the production fluid with chlorine dioxide thereby separating of an aqueous portion and a hydrocarbon portion, wherein after the treating step, at least 5 ppm residual chlorine dioxide remains.
4. The method of claim 3 , further comprising adding a second water-soluble polymer to the aqueous portion to form a recycled flooding fluid.
5. The method of claim 4 , further comprising introducing the recycled flooding fluid into the subterranean formation under conditions of a polymer flooding operation.
6. The method of claim 1 , wherein the amount of chlorine dioxide is at least about 5 ppm residual chlorine dioxide.
7. The method of claim 1 , wherein the amount of chlorine dioxide comprises at least about 6 ppm residual chlorine dioxide.
8. The method of claim 1 , wherein the amount of chlorine dioxide is in a range from about 5 ppm to about 20 ppm residual chlorine dioxide.
9. The method of claim 1 , wherein an upper limit of the amount chlorine dioxide is an amount less than would substantially break the polymer gel, as determined by viscosity measurement.
10. The method of claim 1 , wherein the amount of chlorine dioxide is substantially greater than needed for biocidal activity.
11. A method comprising:
introducing a treatment fluid into a subterranean formation under conditions of a polymer flooding operation, the treatment fluid comprising:
a polymer gel comprising a water-soluble polymer; and
an amount of chlorine dioxide substantially greater than needed for biocidal activity and also allowing an amount of water-soluble polymer to be used to form the polymer gel to be reduced by about 25% to about 75%, relative to a treatment fluid lacking chlorine dioxide; and
an aqueous base fluid.
12. The method of claim 11 , further comprising generating a production fluid comprising an aqueous portion and a hydrocarbon portion.
13. The method of claim 12 , further comprising treating the production fluid with chlorine dioxide thereby separating of an aqueous portion and a hydrocarbon portion, wherein after the treating step, at least 5 ppm residual chlorine dioxide remains.
14. The method of claim 13 , further comprising adding a second water-soluble polymer to the aqueous portion to form a recycled flooding fluid.
15. The method of claim 14 , further comprising introducing the recycled flooding fluid into the subterranean formation under conditions of a polymer flooding operation.
16. The method of claim 11 , wherein the amount of chlorine dioxide comprises at least about 5 ppm residual chlorine dioxide.
17. The method of claim 11 , wherein the amount of chlorine dioxide comprises at least about 6 ppm residual chlorine dioxide.
18. The method of claim 11 , wherein the amount of chlorine dioxides comprises from about 5 ppm to about 20 ppm residual chlorine dioxide.
19. The method of claim 11 , wherein an upper limit of the amount of chlorine dioxide is an amount less than substantially breaks the polymer gel, as determined by measurement of viscosity.