Granted Patent B2

US 9,606,048 · App. 14/319,626 · Granted Mar 28, 2017

Abstract

Claims (33)

1. A method for measuring the passivation coating composition weight per unit area on a metal substrate comprising the steps of:

(i) applying a passivation coating composition to a metal substrate to obtain a passivation coating composition on the metal substrate;

(ii) measuring a Fourier Transform Infrared energy spectrum of the passivation coating composition on the metal substrate of step (i) by obtaining the FTIR spectrum and integrating the spectrum associated with at least one functional group to yield an integral of the absorbances;

(iii) obtaining a calibration standard using a Fourier Transform Infrared energy spectrum for a series of calibration samples having different predetermined weights of the passivation coating composition on the metal substrates by

(a) coating a series of metal substrates with different amounts of passivation coating composition to form calibration samples;

(b) determining the amount of passivation coating composition on the surface of each calibration sample and the area that is coated on each calibration sample, the amount of passivation coating composition being determined gravimetrically;

(c) calculating the passivation coating composition weight per unit area for each calibration sample of step (b);

(d) acquiring an FTIR spectrum for each calibration sample of known passivation composition weight per unit area of step (c) and integrating the peaks associated with at least one functional group to yield an integral of the absorbances; and

(e) plotting the passivation coating composition weight per unit area for each calibration sample of step (c) versus the integral of the absorbances for each calibration sample of step (d) to obtain calibration standard; and

(iv) calculating the passivation coating composition weight per unit area on the metal substrate using the calibration standard of step (iii) and integral of absorbances from step (ii).

2. The method of claim 1 wherein the FTIR energy spectrum is measured by a grazing angle head.

3. The method of claim 2 wherein the grazing angle is in the range of from 5 to 89 degrees.

4. The method of claim 2 wherein the distance between the grazing angle head and the substrate is in the range of from 0 to 5 cm.

5. The method of claim 1 wherein the FTIR energy spectrum is measured by an attenuated total reflection head.

6. The method of claim 1 wherein the FTIR energy spectrum is measured by a hand-held spectrometer.

7. The method of claim 1 wherein the passivation coating composition is a silane-containing coating composition.

8. The method of claim 7 wherein the silane-containing coating composition comprises:

(a) 0.01 to 80 weight percent ureido silane, and/or hydrolyzate forms thereof;

(b) 0.001 to 36 weight percent colloidal metal oxide and/or silica sol particles; and

(c) remainder being water,

wherein the weight percents are based on the total weight of the silane-containing coating composition.

9. The method of claim 7 wherein the silane-containing coating composition further comprises a fluorescence dye.

10. The method of claim 1 wherein the passivation coating composition is a metal alkoxide coating containing a metal selected from the group consisting of zirconium and titanium.

11. The method of claim 10 wherein the metal alkoxide is titanium tetraethoxide or zirconium tetraethoxide.

12. The method of claim 1 wherein the passivation coating composition is a fluorozirconic acid coating or fluorotitanic acid coating.

13. The method of claim 1 wherein the weight of the passivation coating composition is in the range of from about 5.4 to 5,400 milligrams per square meter.

14. The method of claim 1 wherein the substrate is selected from the group consisting of cold rolled steel, hot dip galvanized steel, electrogalvanized steel, aluminum, magnesium, zinc alloy and zinc coated steel.

15. The method of claim 1 wherein the substrate having the passivation coating composition is substantially dried before the FTIR measurement.

16. The method of claim 1 wherein the substrate having the passivation coating composition is a moving coil line.

17. The method of claim 16 wherein the moving coil line is stopped for a predetermined amount of an acquisition time during the FTIR measurement.

18. The method of claim 17 wherein the acquisition time is one second.

19. The method of claim 17 wherein the acquisition time is less than one second.

20. The method of claim 1 wherein the measuring the passivation coating composition weight per unit area on the substrate is done on a moving metal substrate without significantly interrupting the movement of the metal substrate.

Assignments (18)