Dual core golf ball having a shallow “positive hardness gradient” thermoplastic inner core and a steep “positive hardness gradient” thermoset outer core layer
View Patent ↗A golf ball includes an inner core layer including a thermoplastic highly-neutralized ionomer formed from a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater. The inner core has a geometric center hardness and a surface hardness to define a first hardness gradient. An outer core layer is disposed about the inner core and is formed from a homogenous thermoset composition. The outer core layer has an interior hardness and an outer surface hardness to define a second hardness gradient. An inner cover layer is disposed about outer core layer and an outer cover layer is disposed about the inner cover layer. A slope of the second hardness gradient is greater than a slope of the first hardness gradient.
1. A golf ball comprising:
an inner core layer comprising a thermoplastic highly-neutralized ionomer comprising a copolymer of ethylene and an α,β-unsaturated carboxylic acid, an organic acid or salt thereof, and sufficient cation source to neutralize the acid groups of the copolymer by 80% or greater, and having a geometric center hardness and a surface hardness to define a first hardness gradient;
an outer core layer disposed about the inner core, the outer core being formed from a homogenous thermoset composition and having an interior hardness and an outer surface hardness to define a second hardness gradient;
an inner cover layer disposed about outer core layer; and
an outer cover layer disposed about the inner cover layer,
wherein a slope of the second hardness gradient is greater than a slope of the first hardness gradient.
2. The golf ball of claim 1 , wherein a ratio of the slope of the second hardness gradient to the slope of the first hardness gradient is greater than 1.
3. The golf ball of claim 2 , wherein a ratio of the slope of the second hardness gradient to the slope of the first hardness gradient is greater than 1.5.
4. The golf ball of claim 3 , wherein a ratio of the slope of the second hardness gradient to the slope of the first hardness gradient is greater than 2.
5. The golf ball of claim 1 , wherein the inner core layer has an outer diameter of about 0.5 inches to about 1.13 inches.
6. The golf ball of claim 1 , wherein the acid groups of the copolymer are neutralized by 90% or greater.
7. The golf ball of claim 6 wherein the acid groups of the copolymer are neutralized by about 100%.
8. The golf ball of claim 1 , wherein the organic acid or salt thereof comprises barium, lithium, sodium, zinc, bismuth, chromium, cobalt, copper, potassium, strontium, titanium, tungsten, magnesium, cesium, iron, nickel, silver, aluminum, tin, or calcium salts, or salts of fatty acids.
9. The golf ball of claim 8 , wherein the fatty acid salt comprises stearic acid, behenic acid, erucic acid, oleic acid, linoelic acid or dimerized derivatives thereof.
10. The golf ball of claim 8 , wherein the organic acid or salt thereof comprises a magnesium salt of oleic acid.
11. The golf ball of claim 1 , wherein the outer core layer comprises a soft and fast agent.
12. The golf ball of claim 11 , wherein the soft and fast agent comprises a halogenated thiophenol.