High temperature electrochemical cell structures, and methods for making
View Patent ↗An electrochemical cell is described, including an anodic chamber and a cathodic chamber separated by an electrolyte separator tube, all contained within a cell case. The cell also includes an electrically insulating ceramic collar positioned at an opening of the cathodic chamber, and defining an aperture in communication with the opening; along with a cathode current collector assembly; and at least one metallic ring that has a coefficient of thermal expansion (CTE) in the range of about 3 to about 7.5 ppm/° C., contacting at least a portion of a metallic component within the cell, and an adjacent ceramic component. An active braze alloy composition attaches and hermetically seals the ring to the metallic component and the collar. Sodium metal halide batteries that contain this type of cell are also described, along with methods for sealing structures within the cell.
1. An electrochemical cell for a sodium metal halide-based battery, comprising:
(a) an anodic chamber for containing an anodic material; and a cathodic chamber for containing a cathodic material, separated from each other by an electrolyte separator tube, all contained within a case for the cell;
(b) an electrically insulating ceramic collar positioned at an opening of the cathodic chamber, and defining an aperture in communication with the opening;
(c) a cathode current collector assembly disposed within the cathode chamber;
(d) at least one ring comprising a metal or metal alloy that has a coefficient of thermal expansion (CTE) in the range of about 3 to about 7.5 ppm/° C. over a temperature range of about 30° C. to about 450° C., contacting at least a portion of a metallic component within the cell, and an adjacent portion of the ceramic collar; and
(e) a braze alloy composition attaching and hermetically sealing the ring to the metallic component and the collar, wherein the braze alloy composition comprises
(I) nickel; an active metal element; and at least one of (i) germanium; (ii) niobium and chromium; and (iii) silicon and boron; or
(II) copper, nickel, and an active metal element.
2. The electrochemical cell of claim 1 , wherein the metallic alloy forming the ring is selected from the group consisting of
(A) molybdenum, tungsten, niobium; and alloys thereof; and
(B) iron-nickel alloys or nickel-cobalt ferrous alloys.
3. The electrochemical cell of claim 2 , wherein the metallic alloy forming the ring has a CTE in the range of about 5.1 to about 5.5 ppm/° C. over a temperature range of about 30° C. to about 450° C.
4. The electrochemical cell of claim 2 , wherein the metallic alloy forming the ring comprises iron, at least about 25% by weight nickel; and at least about 15% cobalt.
5. The electrochemical cell of claim 4 , wherein the metallic alloy forming the ring further comprises less than about 3% by weight (each) of at least one of carbon, silicon, and manganese.
6. The electrochemical cell of claim 1 , wherein the ring contacts at least a portion of the cathode current collector assembly and an adjacent portion of the ceramic collar.
7. The electrochemical cell of claim 1 , wherein the ring contacts at least a portion of the ceramic collar and an adjacent portion of the cell case.
8. The electrochemical cell of claim 7 , wherein the ring attaches and hermetically seals the cell case to the ceramic collar, by way of another portion of the braze alloy composition.
9. The electrochemical cell of claim 1 , wherein the separator tube is formed of a beta″-alumina (beta double prime alumina) material; and the ceramic collar comprises alpha-alumina.
10. The electrochemical cell of claim 1 , wherein the braze alloy composition further comprises at least one alloying element selected from cobalt, iron, chromium, or niobium.
11. The electrochemical cell of claim 1 , wherein the active braze further comprises at least one of silicon or boron.
12. The electrochemical cell of claim 1 , wherein the active metal of the braze alloy composition comprises titanium, zirconium, hafnium, vanadium, or a combination thereof.
13. A sodium metal halide thermal battery, comprising a plurality of electrochemical cells that are in electrical communication with each other, wherein each electrochemical cell comprises:
(a) an anodic chamber for containing an anodic material; and a cathodic chamber for containing a cathodic material, separated from each other by an electrolyte separator tube, all contained within a case for the cell;
(b) an electrically insulating ceramic collar positioned at an opening of the cathodic chamber, and defining an aperture in communication with the opening;
(c) a cathode current collector assembly disposed within the cathode chamber;
(d) at least one ring comprising a metal or metal alloy that has a coefficient of thermal expansion (CTE) in the range of about 3 to about 7.5 ppm/° C. over a temperature range of about 30° C. to about 450° C., contacting at least a portion of a metallic component within the cell, and an adjacent portion of the ceramic collar; and
(e) a braze alloy composition attaching and hermetically sealing the ring to the metallic component and the collar, wherein the braze alloy composition comprises
(I) nickel; an active metal element; and at least one of (i) germanium; (ii) niobium and chromium; and (iii) silicon and boron; or
(II) copper, nickel, and an active metal element.
14. The sodium metal halide thermal battery of claim 13 , comprising at least two of the rings.
15. An electrochemical cell for a sodium-based thermal battery that comprises an anodic chamber for containing an anodic material; a cathodic chamber for containing a cathodic material, and an intervening electrolyte separator tube, all contained within a case for the cell; wherein the electrochemical cell further includes at least one sealing ring formed of a metal or metal alloy that has a CTE in the range of about 3 to about 7.5 ppm/° C. over a temperature range of about 30° C. to about 450° C., contacting at least one ceramic structure within the cell.