Stable insecticide compositions and methods for producing same
View Patent ↗Insect controlling compositions including an N-substituted (6-haloalkylpyridin-3-yl)alkyl sulfoximine compound exhibiting increased stability, along with methods for preparing same, are disclosed.
1. A composition, comprising a stereoisomeric mixture of {1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}(methyl)oxido-λ 4 -sulfanylidenecyanamide defined by a first pair of diastereomers and a second pair of diastereomers, wherein the first and second pairs of diastereomers are present at a ratio of at least about 3:1.
2. The composition of claim 1 , wherein the first and second pairs of diastereomers are present at a ratio from about 3:1 to about 100:1.
3. The composition of claim 1 , wherein the first and second pairs of diastereomers are present at a ratio from about 3:1 to about 40:1.
4. The composition of claim 1 , wherein the first pair of diastereomers is defined by {(R)-1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-(R)-(methyl)oxido-λ 4 -sulfanylidenecyanamide and {(S)-1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-(S)-(methyl)oxido-λ 4 -sulfanylidenecyanamide and the second pair of diastereomers is defined by {(R)-1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-(S)-(methyl)oxido-λ 4 -sulfanylidenecyanamide and {(S)-1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-(R)-(methyl)oxido-λ 4 -sulfanylidenecyanamide.
5. The composition of claim 1 , further comprising one or more other insecticides.
6. The composition of claim 5 , wherein said insecticide is a spinosyn selected from the group consisting of spinetoram, spinosad and mixtures thereof.
7. The composition of claim 6 , wherein the ratio, by weight, between {1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}(methyl)oxido-λ 4 -sulfanylidenecyanamide and the spinosyn is from about 3:1 to about 1:3.
8. The composition of claim 7 , wherein the ratio, by weight, between {1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}(methyl)oxido-λ 4 -sulfanylidenecyanamide and the spinosyn is about 2:1.
9. A method of controlling insects which comprises applying to a locus where control is desired an insect-inactivating amount of a composition according to claim 1 .