Electrophoretic dispersion
View Patent ↗The present invention is directed to an electrophoretic dispersion comprising charged pigment particles dispersed in a solvent or solvent mixture, wherein at least one type of the charged pigment particles has an aggregation size about 2 to about 10 times their primary size and/or has a PDI in the range of 0.1 to 0.3. The electrophoretic dispersion of the present invention is capable of improving both image bistability and contrast ratio through adjusting the size distribution of the charged pigment particles.
1. An electrophoretic display comprising a pair of spaced-apart electrodes and an electrophoretic dispersion disposed between the pair of electrodes, the electrophoretic dispersion comprising charged pigment particles dispersed in a solvent or solvent mixture, wherein at least one type of the charged pigment particles has a polydispersity index (PDI) in the range of about 0.1 to about 0.3, and at least 60% of at least one type of the charged pigment particles has an average aggregation size in the range of about 2 to about 10 times their primary size.
2. The display of claim 1 , wherein the at least one type of the charged pigment particles has a polydispersity index (PDI) in the range of about 0.15 to about 0.25.
3. The display of claim 1 , wherein said pigment particles are formed from core particles coated with a copolymer formed from a first type of monomer and a second type of monomer, the first type of monomer having a homopolymer which is incompatible with the solvent or solvent mixture in which the pigment particles are dispersed and the second type of monomer having a homopolymer which is compatible with the solvent or solvent mixture in which the pigment particles are dispersed.
4. The display of claim 3 , wherein the copolymer is a random copolymer or a block copolymer.
5. The display of claim 3 , wherein said first type of monomer is styrene, benzyl 2-methylacrylate, methyl acrylate, butyl acrylate, vinyl pyridine, 2-hydoxyethyl acrylate, dimethylaminoethyl methacrylate, acrylic acid or vinyl phosphoric acid.
6. The display of claim 3 , wherein said second type of monomer has long alkyl or branched side chains.
7. The display of claim 3 , wherein said second type of monomer is lauryl acrylate, lauryl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, hexyl acrylate, hexyl methacrylate, n-octyl acrylate, n-octyl methacrylate, n-octadecyl acrylate, or n-octadecyl methacrylate.
8. The display of claim 3 , wherein the molar ratio of the first type of monomer to the second type of monomer is between 5:1 to 1:10.
9. The display of claim 3 , wherein said core particles are inorganic particles or organic particles.
10. The display of claim 1 , wherein the solvent or solvent mixture is aliphatic hydrocarbon based.