Low-temperature phase-stable acyl glycinate compositions
View Patent ↗Low-temperature stable concentrate compositions comprising an acyl glycinate present in an amount greater than 70 wt % by weight of the composition; and b) at least one of a zwitterionic surfactant or an amphoteric surfactant present in an amount greater than 0.1 wt % by weight of the composition, wherein the concentrate is low temperature stable.
1. A low-temperature phase-stable concentrate composition consisting of:
a) an acyl glycinate present in an amount greater than 15 wt %;
b) at least one of a zwitterionic surfactant or an amphoteric surfactant present in an amount greater than about 0.1 wt %; and
(c) water; and, optionally,
(d) glycerine in an amount from about 0.01 wt % to about 2 wt %; and, optionally,
(e) at least one electrolyte,
wherein the amounts are by total weight of the composition and
wherein the concentrate is phase-stable at a temperature less than or equal to 17° C.
2. The concentrate composition of claim 1 wherein the acyl glycinate is of formula (1):
RC(O)NHCH 2 CO 2 X (I),
wherein R is a C 8 -C 22 alkyl group, and X is a cation or H.
3. The concentrate composition of claim 2 wherein the cation is selected from sodium, potassium, or ammonium.
4. The concentrate of claim 2 wherein R is a C 8 -C 18 group.
5. The concentrate of claim 1 wherein the at least one zwitterionic surfactant or amphoteric surfactant is selected from an alkyl betaine surfactant or salt thereof, an alkyl hydroxyl sulfobetaine surfactant or salt thereof, or an alkyl sulfobetaine surfactant or salt thereof.
6. The concentrate of claim 1 wherein the at least one zwitterionic surfactant or amphoteric surfactant is an alkyl sulfobetaine surfactant or salt thereof.
7. The concentrate of claim 1 wherein the at least one zwitterionic surfactant or amphoteric surfactant is present in an amount greater than 0.5 wt % by weight of the composition.
8. The concentrate of claim 1 wherein the at least one zwitterionic surfactant or amphoteric surfactant is present in an amount greater than 1 wt % by weight of the composition.
9. The concentrate of claim 1 wherein the at least one zwitterionic surfactant or amphoteric surfactant is selected from alkyl betaines or salts thereof, amidopropyl betaines or salts thereof, alkyl sulfobetaines or salts thereof, alkyl amphocarboxy glycinates or salts thereof, alkyl amphocarboxypropionates or salts thereof, alkyl amphodipropionates or salts thereof, alkyl amphoglycinates or salts thereof, alkyl amphopropionates or salts thereof, alkyl iminopropionates or salts thereof, alkyl iminodipropionates or salts thereof, alkyl amphopropylsulfonates or salts thereof, or mixtures thereof.
10. The concentrate of claim 1 wherein the concentrate is phase-stable at a temperature less than or equal to 6° C.
11. The concentrate of claim 1 wherein the concentrate is phase-stable at a temperature less than or equal to 4° C.
12. A method for storing a concentrated acyl glycinate composition by:
a) obtaining a concentrated acyl glycinate composition consisting of water and greater than 15 wt %, by total weight of composition, of acyl glycinate; and
b) contacting at least one of a zwitterionic surfactant or amphoteric surfactant component with the concentrated acyl glycinate composition, whereby the concentrated acyl glycinate composition is phase-stable at a temperature less than or equal to 17° C.
13. The method of claim 12 wherein the surfactant component is present in the concentrated acyl glycinate composition in an amount greater than 0.5 wt % by weight of composition.
14. The method of claim 12 wherein the surfactant component is present in the concentrated acyl glycinate composition in an amount greater than 1 wt % by weight of composition.
15. The method of claim 12 wherein the surfactant component is present in the concentrated acyl glycinate composition in an amount greater than 25 wt % by weight of composition.
16. The method of claim 12 wherein the surfactant component is selected from an alkyl betaine surfactant, an alkyl sulfobetaine surfactant or a mixture thereof.
17. The method of claim 12 wherein the acyl glycinate is of formula (I):
RC(O)NHCH 2 CO 2 X (I),
wherein R is a C 8 -C 22 alkyl group, and X is a cation or H.
18. The method of claim 12 whereby the concentrated acyl glycinate composition is phase-stable at a temperature less than or equal to 10° C.
19. The method of claim 12 whereby the concentrated acyl glycinate composition is phase-stable at a temperature less than or equal to 4° C.