Anode active material for lithium secondary battery and lithium secondary battery comprising the same
The anode active material of the present invention comprises silicon-based particles obtained from at least one of silicon, a silicon oxide and a silicon alloy, and the silicon-based particles have a faceted shape, thereby providing high capacity and good life characteristics without causing any deterioration which has been generated in the use of conventional silicon-based particles, and eventually providing a lithium secondary battery having such characteristics.
1. An anode active material, comprising silicon-based particles obtained from at least one of silicon, a silicon oxide and a silicon alloy, the silicon-based particles being solid and having a faceted shape,
wherein the silicon-based particles having a faceted shape comprise a silicon alloy which comprises silicon and at least one element selected from the group consisting of Mn and Ce, and
wherein the silicon-based particles having a faceted shape have a surface area greater than that of spherical silicon-based particles by 1.5 to 4 times when their volume is in the same level as volume of the spherical silicon-based particles.
2. The anode active material of claim 1 , wherein the silicon-based particles are a faceted anode active material and the faceted silicon-based particles come into contact with each other by at least one of line contact whereby edges of particles are in contact with one another and area contact whereby surface areas of particles are in contact with one another.
3. The anode active material of claim 1 , wherein the faceted silicon-based particles have a polyhedral shape consisting of a plurality of polygons.
4. The anode active material of claim 1 , wherein the silicon-based particles having a faceted shape have an average diameter of 0.1 to 30 μm.
5. The anode active material of claim 1 , which is a single phase consisting of only silicon-based particles obtained from at least one of silicon, a silicon oxide and a silicon alloy.
6. An anode for a lithium secondary battery, comprising a current collector; and an anode active material layer formed on at least one surface of the current collector,
wherein the anode active material layer comprises the anode active material of claim 1 .
7. A lithium secondary battery, comprising a cathode, an anode, and a separator interposed between the cathode and the anode,
wherein the anode is defined in claim 6 .
8. An anode for a lithium secondary battery, comprising a current collector and an anode active material layer formed on at least one surface of the current collector, the anode active material layer comprising an anode active material including silicon-based particles obtained from at least one of a silicon oxide and a silicon alloy, the silicon-based particles being solid and having a faceted shape, characterized in that the silicon-based particles having a faceted shape have an average diameter of 0.1 to 30 μm,
wherein the silicon-based particles having a faceted shape are obtained by heating one or both of 1) a compound consisting of a silicon oxide and 2) a combination of elements consisting of a silicon mixed with at least one element selected from the group consisting of Mn, Fe, Ca, Ce, La, Cr, Co, Bi, Pb, Cd, and Mo to obtain a molten product, spraying the molten product on a rotary copper wheel using argon gas under vacuum to produce a thin plate, and then milling the thin plate, an output of the milling being the silicon-based particles having a faceted shape, and
wherein the silicon-based particles come into contact with each other by at least one of line contact whereby edges of particles are in contact with one another and area contact whereby surface areas of particles are in contact with one another.
9. A method for preparing an anode for a lithium secondary battery comprising:
obtaining silicon-based particles having a faceted shape as defined in claim 8 through the performance of steps comprising:
mixing and heating a combination of elements consisting of a silicon and at least one element selected from the group consisting of Mn, Fe, Ca, Ce, La, Cr, Co, Bi, Pb, Cd and Mo to obtain a Si alloy;
spraying the Si alloy on a rotary copper wheel using argon gas under vacuum to produce the Si alloy in the form of a thin plate; and
milling the Si alloy in the form of the thin plate,
wherein subsequent to milling, silicon-based particles are obtained having a solid faceted shape with an average diameter of 0.1 to 30 μm;
applying the silicon-based particles on a current collector; and
compressing the silicon-based particles on the current collector to form the anode for the lithium secondary battery.
10. The method for preparing an anode for a lithium secondary battery of claim 9 , wherein the combination of elements consists of a silicon and at least one element selected from the group consisting of Mn, Ce and Pb.
11. An anode for a lithium secondary battery, comprising a current collector and an anode active material layer formed on at least one surface of the current collector, the anode active material layer comprising an anode active material including silicon-based particles obtained from a silicon alloy, the silicon-based particles having a faceted shape, characterized in that the silicon-based particles having a faceted shape have an average diameter of 0.1 to 30 μm,
wherein the silicon-based particles having a faceted shape are obtained by mixing and heating a combination of elements consisting of silicon and at least one element selected from the group consisting of Mn, Fe, Ca, Ce, La, Cr, Co, Bi, Pb, Cd, and Mo to obtain a molten alloy, spraying the molten alloy on a rotary copper wheel using argon gas under vacuum to produce the silicon alloy in the form of a thin plate, and then milling the thin plate, an output of the milling being the silicon-based particles having a faceted shape,
wherein the silicon alloy is free of oxygen, and
wherein the silicon-based particles come into contact with each other by at least one of line contact whereby edges of particles are in contact with one another and area contact whereby surface areas of particles are in contact with one another.
12. The anode for a lithium secondary battery of claim 11 , wherein the silicon-based particles having a faceted shape comprises a silicon alloy which comprises silicon and at least one element selected from the group consisting of Mn, Ce and Pb.
13. An anode active material, comprising silicon-based particles obtained from an Si/Al/Fe alloy, the silicon-based particles having a faceted shape, characterized in that the silicon-based particles having a faceted shape have an average diameter of 0.1 to 30 μm,
wherein the silicon-based particles having a faceted shape are obtained by mixing and heating Si, Al and Fe to obtain a molten alloy, spraying the molten alloy on a rotary copper wheel using argon gas under vacuum to produce the Si/Al/Fe alloy in the form of a thin plate, and then milling the thin plate, an output of the milling being the silicon-based particles having a faceted shape, and
wherein the Si/Al/Fe alloy is free of oxygen.
14. The anode active material of claim 13 , wherein the atomic ratio of Si, Al and Fe is 75/15/10(%).
15. An anode for a lithium secondary battery, comprising a current collector and an anode active material layer formed on at least one surface of the current collector,
wherein the anode active material layer comprises the anode active material of claim 13 .