The disclosure relates to a multiple pane which includes a pair of glass panels spaced by the spacers and sealed at peripheries thereof. The objective is to provide a multiple pane in which the spacers are formed easily, and a method of preparing the multiple pane. The multiple pane includes: a pair of glass panels; a plurality of spacers interposed between the pair of glass panels; and a hermetic bond to hermetically bond peripheries of the pair of glass panels to each other. The multiple pane contains a space formed between the pair of glass panels, the space being to be sealed so as to be in a reduced pressure state. Each of the plurality of spacers being a porous member formed on one glass panel of the pair of glass panels.
1. A multiple pane comprising:
a pair of glass panels;
a plurality of spacers interposed between the pair of glass panels; and
a hermetic bond that hermetically bonds peripheries of the pair of glass panels to each other,
the multiple pane comprising a space provided between the pair of glass panels, the space being sealed so as to be in a reduced pressure state,
each of the plurality of spacers being a porous member provided on one glass panel of the pair of glass panels, and
the porous member containing a plurality of hollow silica particles each of which includes a hollow space therewithin.
2. The multiple pane according to claim 1 , wherein
the plurality of spacers comprise a mixture of
material to compose the plurality of spacers that contain the plurality of hollow silica particles, and
a binder, and
each of the plurality of spacers has
pores provided by removing the binder, and
pores that the plurality of hollow silica particles have therewithin.
3. The multiple pane according to claim 1 , wherein
each of the plurality of spacers comprises porous glass.
4. The multiple pane according to claim 1 , wherein
each of the plurality of spacers comprises the porous member containing a filler of a heat-resistant ceramic.
5. The multiple pane according to claim 1 , wherein
the porous member further contains crystalized glass.
6. The multiple pane according to claim 1 , wherein
each of the plurality of spacers comprises the porous member containing a metal oxide material with electrical conductivity.
7. The multiple pane according to claim 1 , wherein
each of the plurality of spacers has a porosity ranging from 1% to 20%.
8. The multiple pane according to claim 1 , wherein
each of the plurality of spacers comprises the porous member that includes at least two layers,
the at least two layers include a layer in contact with one of the pair of glass panels on which the spacers are not provided, and
the layer has the highest adhesiveness to glass of the at least two layers.
9. The multiple pane according to of claim 1 , wherein
each of the plurality of spacers comprises the porous member that includes at least two layers,
the at least two layers include a layer in contact with one of the pair of glass panels on which the spacers are not provided, and
the layer has the highest heat-barrier properties of the at least two layers.
10. The multiple pane according to claim 1 , wherein
each of the plurality of hollow silica particles has a particle diameter of 10 to 300 nm and a shell thickness of 1 to 15 nm.