Drainage of an aqueous composition
View Patent ↗In a process for separating a solid material from a suspension of the solid material in water, an organopolysiloxane polyalkylene oxide copolymer comprising a branched organopolysiloxane structure is added to the suspension of solid material in water and the suspension is drained. The organopolysiloxane polyalkylene oxide copolymer comprising a branched organopolysiloxane structure increases the rate of drainage of the suspension.
1. A process for separating a solid material from a suspension of the solid material in water, said process comprising:
adding to the suspension of solid material in water an organopolysiloxane polyalkylene oxide copolymer having the general formula
R 2 R*SiO(RR′SiO) x (R 2 SiO) y (RR″SiO) z SiR 2 R* (I)
wherein each R represents a hydrocarbon group having 1 to 25 carbon atoms;
each R′ represents a polyoxyalkylene group of the formula
-A-O-(A′-O) w —(C 2 H 4 O) a (C 3 H 6 O) b (C 4 H 8 O) c —R 2
wherein A represents a divalent hydrocarbon group having 1 to 20 carbon atoms, an acylalkyl group of the formula -A″C(O)— where A″ is an alkylene group having 2 to 4 carbon atoms, or a direct bond to Si, A′ represents an alkylene group having 2 to 5 carbon atoms, R 2 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or an acyl group having 1 to 20 carbon atoms, w=0 or 1, a=0-50, b=0-50 and c=0-20, provided that a+b+c is at least 1; each R″ represents an organopolysiloxane moiety or an organic group substituted by an organopolysiloxane moiety and is bonded to Si by a Si—C bond or a siloxane linkage; each R* is a R, R′ or R″ group; x=1-40; y=0-300; and z=1-5;
mixing the organopolysiloxane polyalkylene oxide copolymer and the suspension of solid material in water to form a mixture; and
draining the solid material from the mixture;
wherein the organopolysiloxane polyalkylene oxide copolymer comprising a branched organopolysiloxane structure increases the rate of drainage of the suspension.
2. The process according to claim 1 , wherein the solid material is fibrous cellulosic material.
3. The process according to claim 2 , further defined as a process for producing dry washed wood pulp, wherein the solid material is washed wood pulp and the suspension is the washed wood pulp and an aqueous slurry.
4. The process according to claim 1 , wherein b=5-40, c=0 and b is greater than a.
5. The process according to claim 1 , wherein the organopolysiloxane moiety comprising R″ is substituted by at least one polyoxyalkylene group.
6. The process according to claim 1 , wherein the organopolysiloxane polyalkylene oxide copolymer has the general formula
wherein R, R′, R*, x, y and z are as defined above; each R 3 represents hydrogen or an alkyl group having 1 to 3 carbon atoms and Y represents an organic or organosiloxane linkage which contains no hydrolysable bonds.
7. The process according to claim 1 , wherein the organopolysiloxane polyalkylene oxide copolymer has the general formula
wherein R, R′, R*, x, y and z are as defined above and each R 4 represents a hydrocarbon group having 1 to 25 carbon atoms or a polyorganosiloxane group of the formula
R 2 R*SiO(RR′SiO) x′ (R 2 SiO) y (RR″SiO) z′ —
wherein R, R′, R″, R* and y are as defined above, x′=0-10 and z′=0-5.
8. The process according to claim 1 , wherein the organopolysiloxane polyalkylene oxide copolymer has the general formula
wherein R is defined above; each R 5 represents a hydrocarbon group having 1 to 25 carbon atoms, a polyoxyalkylene group of the formula
-A-O-(A′-O) w —(C 2 H 4 O) a (C 3 H 6 O) b (C 4 H 8 O) c —R 2
wherein A represents a divalent hydrocarbon group having 1 to 20 carbon atoms or an acylalkyl group of the formula -A″C(O)— where A″ is an alkylene group having 2 to 4 carbon atoms, A′ represents an alkylene group having 2 to 5 carbon atoms, R 2 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or an acyl group having 1 to 20 carbon atoms, w=0 or 1, a=0-50, b=0-50 and c=0-20, provided that a+b+c is at least 1, or an organopolysiloxane moiety or organic group substituted by an organopolysiloxane moiety which is bonded to Si by a Si—C bond, provided that at least one group R 5 represents a polyoxyalkylene group and at least one group R 5 represents an organopolysiloxane moiety or organic group substituted by an organopolysiloxane moiety; n=1-400; and each q=1 or 2.
9. The process according to claim 1 , wherein the branched organopolysiloxane polyalkylene oxide copolymer is present as part of a composition also containing organopolysiloxane polyalkylene oxide copolymer having the general formula
R 2 R*SiO(RR′SiO) x (R 2 SiO) y (RR″SiO) z SiR 2 R* (I)
wherein each R represents a hydrocarbon group having 1 to 25 carbon atoms; each R′ represents a polyoxyalkylene group of the formula
-A-O-(A′-O) w —(C 2 H 4 O) a (C 3 H 6 O) b (C 4 H 8 O) c —R 2
wherein A represents a divalent hydrocarbon group having 1 to 20 carbon atoms, an acylalkyl group of the formula -A″C(O)— where A″ is an alkylene group having 2 to 4 carbon atoms, or a direct bond to Si, A′ represents an alkylene group having 2 to 5 carbon atoms, R 2 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or an acyl group having 1 to 20 carbon atoms, w=0 or 1, a=0-50, b=0-50 and c=0-20, provided that a+b+c is at least 1; each R″ represents an organopolysiloxane moiety or an organic group substituted by an organopolysiloxane moiety and is bonded to Si by a Si—C bond or a siloxane linkage; each R* is a R, R′ or R″ group; x=1-40; y=0-300; and z=0, the average value of z in the total organopolysiloxane polyalkylene oxide copolymer in the composition being in the range 0.1 to 2.
10. The process according to claim 9 , wherein the composition has a viscosity of less than 30000 cSt at 25° C.
11. The process according to claim 1 , wherein the solid material is coal.
12. The process according to claim 1 , wherein the solid material is sewage sludge.
13. A process for improving the drainage of a suspended solid material from an aqueous medium, said process comprising adding an organopolysiloxane polyalkylene oxide copolymer comprising a branched organopolysiloxane structure to the aqueous medium, said branched organopolysiloxane polyalkylene oxide copolymer having the general formula
R 2 R*SiO(RR′SiO) x (R 2 SiO) y (RR″SiO) z SiR 2 R* (I)
wherein each R represents a hydrocarbon group having 1 to 25 carbon atoms; each R′ represents a polyoxyalkylene group of the formula
-A-O-(A′-O) w —(C 2 H 4 O) a (C 3 H 6 O) b (C 4 H 8 O)—R 2
wherein A represents a divalent hydrocarbon group having 1 to 20 carbon atoms, an acylalkyl group of the formula -A″C(O)— where A″ is an alkylene group having 2 to 4 carbon atoms, or a direct bond to Si, A′ represents an alkylene group having 2 to 5 carbon atoms, R 2 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or an acyl group having 1 to 20 carbon atoms, w=0 or 1, a=0-50, b=0-50 and c=0-20, provided that a+b+c is at least 1; each R″ represents an organopolysiloxane moiety or an organic group substituted by an organopolysiloxane moiety and is bonded to Si by a Si—C bond or a siloxane linkage; each R* is a R, R′ or R″ group; x=1-40; y=0-300; and z=1-5.
14. A laundry process comprising washing textile material in an aqueous detergent solution and rinsing the washed textile material with water, wherein the aqueous detergent solution or the water comprises an organopolysiloxane polyalkylene oxide copolymer having the general formula
R 2 R*SiO(RR′SiO) x (R 2 SiO) y (RR″SiO) z SiR 2 R* (I)
wherein each R represents a hydrocarbon group having 1 to 25 carbon atoms; each R′ represents a polyoxyalkylene group of the formula
-A-O-(A′-O) w —(C 2 H 4 O) a (C 3 H 6 O) b (C 4 H 8 O) c —R 2
wherein A represents a divalent hydrocarbon group having 1 to 20 carbon atoms, an acylalkyl group of the formula -A″C(O)— where A″ is an alkylene group having 2 to 4 carbon atoms, or a direct bond to Si, A′ represents an alkylene group having 2 to 5 carbon atoms, R 2 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms or an acyl group having 1 to 20 carbon atoms, w=0 or 1, a=0-50, b=0-50 and c=0-20, provided that a+b+c is at least 1; each R″ represents an organopolysiloxane moiety or an organic group substituted by an organopolysiloxane moiety and is bonded to Si by a Si—C bond or a siloxane linkage; each R* is a R, R′ or R″ group; x=1-40; y=0-300; and z=1-5.
15. The process according to claim 3 , further comprising washing wood pulp in the aqueous slurry to form the suspension and drying the washed wood pulp after draining the washed wood pulp from the mixture.
16. The process according to claim 15 , wherein the organopolysiloxane polyalkylene oxide copolymer is added to the aqueous slurry before draining the washed wood pulp from the mixture, thereby increasing the rate of drainage and reducing the total energy used in draining and drying of the washed wood pulp.