Bifunctional anti-deposit and anti-corrosion additives
View Patent ↗The invention concerns bifunctional compositions usable in the field of extraction of hydrocarbons, oil and/or gas, said compositions being homogeneous, clear and stable and comprising at least one anti-mineral-deposit additive, at least one corrosion inhibitor, and at least one agent for compatibilizing between the anti-mineral-deposit additive and the corrosion inhibitor.
1. A composition comprising
from 15% to 60% by weight of at least one corrosion inhibitor,
from 10% to 40% by weight of at least one mineral scale inhibitor,
at least one sulfur-comprising additive chosen from mercapto acids and mercapto alcohols, and
from 1 to 20% by weight of at least one compatibility agent, and,
optionally at least one solvent in a quantity sufficient for (q.s. for) reaching 100%,
wherein the compatibility agent is a water-soluble nonionic, cationic or amphoteric surfactant,
wherein the corrosion inhibitor is a fatty amine derivative chosen from amino acids, aminoalcohols, amidoamines, and pyridine derivatives, and
wherein the composition does not comprise an acidic or neutral aminophosphonate.
2. The composition as claimed in claim 1 , wherein the mineral scale inhibitor is chosen from poly(acrylic acids, poly(alkyl acrylate)s, copolymers based on phosphinocarboxylic acids, tannins, lignosulfonates, polyacrylamides, and naphthalenesulfonates.
3. The composition as claimed in claim 1 , wherein the compatibility agent is chosen from ethoxylated fatty-chain amines, quaternized fatty-chain amines, fatty-chain amino acids, oxyethylated and/or oxypropylated condensates, alkylarylsulfonates, oxyethylated and/or oxypropylated fatty-chain alcohols, and mixtures of two or more of them in all proportions.
4. The composition as claimed in claim 1 , additionally comprising at least one solvent chosen from water, water-soluble organic solvents and water/water-soluble organic solvent(s) mixtures.
5. The composition as claimed in claim 1 , wherein the at least one sulfur-comprising additive is chosen from mercaptoethanol mercaptopropanol, thioglycolic acid and mercaptopropionic add.
6. The composition as claimed in claim 1 , comprising:
from 1% to 10% by weight of the at least one sulfur-comprising additive.
7. The composition as claimed # claim 1 , comprising:
from 15% to 40% by weight of the at least one mineral scale inhibitor,
from 20% to 55% by weight of the at least one corrosion inhibitor,
from 4% to 20% by weight of the at least one compatibility agent, and
optionally at least one solvent in a quantity sufficient for (q.s. for) reaching 100%.
8. The composition as claimed in claim 1 , comprising:
from 15% to 40% by weight of the at e one mineral scale inhibitor,
from 20% to 55% by weight of the at least one corrosion inhibitor,
from 4% to 20% by weight of the at least one compatibility agent, and
from 3% to 10% by weight of the at least one sulfur-comprising additive, and
optionally at least one solvent in a quantity sufficient for (q.s. for) reaching 100%.
9. A method of extracting hydrocarbons, oil or gas, continuously, batchwise or by the squeeze method from lines, comprising injecting the composition as claimed in claim 1 in the lines for the extraction of the hydrocarbons.
10. The method as claimed in claim 8 , wherein the amount of the composition injected is between 1 ppm and 1000 ppm (weight/volume).
11. The method as claimed in claim 9 , wherein the amount of the composition injected is between 50 ppm and 800 ppm (weight/volume).