Polycarbonate comprising glass fibres
View Patent ↗The present invention relates to a thermoplastic molding composition composed of polycarbonate and inorganic fillers which comprises from 0.01 to 0.5 part by weight of at least one anhydride-modified alpha-olefin terpolymer and which has a high degree of rigidity and nevertheless exhibits good strength, as well as stress-strain characteristics corresponding to those of an unreinforced polycarbonate. Surprisingly, the molding composition additionally exhibits an improvement in flame retardancy. The invention relates in particular to flame-retardant, thermoplastic molding compositions filled with glass fibers, and to the production and use thereof. The property profile is, surprisingly, independent of the degree of interaction of the filler with the polycarbonate matrix.
1. A flame-retardant, thermoplastic moulding composition comprising
A) from 47.500 to 97.939 parts by weight of at least one aromatic polycarbonate,
B) from 0.001 to 1.000 part by weight of at least one flame retardant,
C) from 0.01 to 0.50 part by weight of at least one rubber-free anhydride-modified alpha-olefin terpolymer,
D) from 2.0 to 40.0 parts by weight of at least one inorganic filler,
E) from 0.05 to 1.00 part by weight of at least one demoulding agent,
F) from 0.0 to 10.0 parts by weight of a further additive,
wherein the sum of the parts by weight of components A) to F) is 100 parts by weight.
2. The moulding composition according to claim 1 , wherein component D) is present in an amount of from 7.0 to 14.0 parts by weight.
3. The moulding composition according to claim 1 , wherein component F) is present in an amount of from 1.0 to 6.0 parts by weight.
4. The moulding composition according to claim 1 , wherein component C) is present in an amount of from 0.20 to 0.30 part by weight.
5. The moulding composition according to claim 1 , wherein the anhydride is selected from the group consisting of maleic anhydride, phthalic anhydride, fumaric anhydride, itaconic anhydride, and mixtures thereof.
6. The moulding composition according to claim 5 , wherein the anhydride is maleic anhydride.
7. The moulding composition according to claim 5 , wherein the alpha-olefin terpolymer comprises structural units selected from the group consisting of ethylene, 1-propene, 1-butene, 1-isobutene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene, 1-tridecene, 1-tetradecene, 1-octadecene, 1-nonadecene, and mixtures thereof.
8. The moulding composition according to claim 5 , wherein the rubber-free anhydride-modified terpolymer comprises
C1) from 90.0 to 98.0 wt. % terpolymer and
C2) from 2.0 to 10.0 wt. % anhydride.
9. The moulding composition according to claim 1 , wherein the terpolymer comprises ethylene, 1-propene and 1-octene structural units.
10. The moulding composition according to claim 8 , wherein the olefinic portion E1) of the anhydride-modified terpolymer is characterised in that
the ethylene content is from 96.0 to 80.0 wt. %;
the propylene content is from 2.0 to 10.0 wt. %; and
the octene content is from 2.0 to 10.0 wt. %.
11. The moulding composition according to claim 1 , wherein the rubber-free anhydride-modified terpolymer has a molecular weight Mw of from 2000 to 10,000 g/mol.
12. A method of preparing the polycarbonate composition of claim 1 comprising adding rubber-free anhydride-modified alpha-olefin terpolymers according to component C) for increasing the flowability of polycarbonate compositions.
13. The method according to claim 12 , wherein the amount of component C for the compositions with improved flowability is from 0.5 to 10.0 parts by weight.
14. The method according to claim 12 , wherein the rubber-free anhydride-modified alpha-olefin terpolymer is characterized in terms of its components and the amounts thereof by claim 5 .