Polyisobutylene prepared with low diluent content reaction medium
View Patent ↗A method of making a polyisobutylene polymer in a recirculating loop reactor with one or more reaction tubes in contact with a heat transfer medium includes: (a) providing a feed mixture consisting essentially of polymerizable monomer and catalyst to a residual reactor stream at a feed rate to form a reaction mixture, the reaction mixture containing less than 5% by weight diluent components; (b) recirculating the reaction mixture in the one or more reaction tubes of the loop reactor at a recirculation rate greater than the feed rate utilizing a recirculating pump operating at a pressure differential, delta P, corresponding to a recirculating flow; (c) polymerizing the reaction mixture in the one or more tubes of the loop reactor to convert the feed mixture to polyisobutylene polymer while cooling the one or more tubes of the loop reactor with the heat transfer medium; and (e) withdrawing polyisobutylene polymer from the loop reactor.
1. A method of making a polyisobutylene polymer in a recirculating loop reactor with one or more reaction tubes in contact with a heat transfer medium comprising:
(a) providing a feed mixture consisting essentially of polymerizable monomer and catalyst to a residual reactor stream at a feed rate to form a reaction mixture, the reaction mixture containing less than 5% by weight diluent components;
(b) recirculating the reaction mixture in the one or more reaction tubes of the loop reactor at a recirculation rate greater than the feed rate utilizing a recirculating pump operating at a pressure differential, delta P, corresponding to a recirculating flow;
(c) polymerizing the reaction mixture in the one or more tubes of the loop reactor to convert the feed mixture to polyisobutylene polymer while cooling the one or more tubes of the loop reactor with the heat transfer medium; and
(e) withdrawing polyisobutylene polymer from the loop reactor.
2. The method according to claim 1 , wherein the feed mixture and the reaction mixture contain 1.5% by weight or less diluent components.
3. The method according to claim 1 , wherein the feed mixture and the reaction mixture contain 1% by weight or less diluent components.
4. The method according to claim 1 , wherein the delta P and polymerization reaction are controlled to provide a linear velocity of the reaction mixture of at least 10 ft/sec in the one or more reaction tubes of the loop reactor.
5. The method according to claim 4 , wherein the delta P and polymerization reaction are controlled to provide a linear velocity of the reaction mixture of at least 12 ft/sec in the one or more reaction tubes of the loop reactor.
6. The method according to claim 1 , wherein the delta P and polymerization reaction are controlled to provide a linear velocity of the reaction mixture of from 10 ft/sec to 20 ft/sec in the one or more reaction tubes of the loop reactor.
7. The method according to claim 1 , wherein the polyisobutylene withdrawn from the loop reactor is a highly reactive polyisobutylene with a number average molecular weight of from 500 to 4000 Daltons.
8. The method according to claim 7 , wherein the loop reactor is operated with a catalyst turnover number of from 650 to 1350 lbs. polymer/lbs. catalyst and the polyisobutylene withdrawn from the loop reactor is a highly reactive polyisobutylene with a number average molecular weight of from 1500 to 4000 Daltons.
9. The method according to claim 1 , wherein the polymer withdrawn from the loop reactor is a mid-range vinylidene polyisobutylene polymer with a number average molecular weight of from 500 Daltons to 4000 Daltons and wherein the loop reactor is operated with a catalyst turnover number of from 1600 lbs. polymer/lbs. catalyst to 3000 lbs. polymer/lbs. catalyst.
10. A method of making a polyisobutylene polymer in a recirculating loop reactor with one or more reaction tubes in contact with a heat transfer medium comprising:
(a) providing a feed mixture consisting essentially of polymerizable monomer and catalyst to a residual reactor stream at a feed rate to form a reaction mixture, the reaction mixture containing less than 5% by weight diluent components;
(b) recirculating the reaction mixture in the one or more reaction tubes of the loop reactor at a recirculation rate utilizing a recirculating pump operating at a pressure differential, delta P, of from 35 psi to 80 psi;
(c) polymerizing the reaction mixture in the one or more tubes of the loop reactor to convert the feed mixture to polyisobutylene polymer while cooling the one or more tubes of the loop reactor with the heat transfer medium;
(d) controlling the pressure delta and polymerization reaction of steps (b) and (c) to provide a recirculation ratio of the recirculation rate to the feed rate of at least 30:1; and
(e) withdrawing polyisobutylene polymer from the loop reactor.
11. The method according to claim 10 , wherein the feed mixture and the reaction mixture contain 1.5% by weight or less diluent components.
12. The method according to claim 10 , wherein the feed mixture and the reaction mixture contain 1% by weight or less diluent components.
13. The method according to claim 10 , wherein the conversion of isobutylene monomer to polymer is at least 55%.
14. The method according to claim 10 , wherein the delta P of the recirculating pump is at least 50 psi.
15. The method according to claim 14 , operated at a recirculation ratio of from 30:1 to 50:1.
16. The method according to claim 15 , operated at a recirculation ratio of at least 35:1.
17. The method according to claim 15 , operated at a recirculation ratio of at least 37.5:1.
18. The method according to claim 1 , operated continuously at a residence time of from 3 to 6 minutes.