Alpha-alkoxysilane-terminated prepolymer for fast-curing spray foams with improved propellant gas solubility
View Patent ↗The present invention relates to an alpha-alkoxysilane-terminated prepolymer preparable by reaction of at least one polyether polyol, of a polyisocyanate and of an alpha-alkoxysilane having at least one isocyanate-reactive group, said polyether polyol having a weight average of 500 to 7000 g/mol and having ethylene oxide and propylene oxide units, the proportion of ethylene oxide units being up to 50% by weight based on the polyether polyol. The invention further provides a process for preparing an inventive alpha-alkoxysilane-terminated prepolymer, a composition, a multicomponent system and a spray can comprising an inventive alpha-alkoxysilane-terminated prepolymer, and also a moulding obtainable by polymerization from an inventive alpha-alkoxysilane-terminated prepolymer.
1. An α-alkoxysilane-terminated prepolymer obtained by reacting at least a polyether polyol, a polyisocyanate and an α-alkoxysilane, wherein the α-alkoxysilane is [(cyclohexylamino) methyl]triethoxysilane, wherein the polyisocyanate is hexamethylene 1,6-diisocyanate or a polyisocyanate mixture comprising hexamethylene 1,6-diisocyanate, and wherein the polyether polyol has a weight average of 500 to 7000 g/mol, comprises propylene oxide units and has a 0 to 50 wt % fraction, based on the polyether polyol, of ethylene oxide units.
2. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the fraction of ethylene oxide units is not more than 30 wt % based on the polyether polyol.
3. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the fraction of ethylene oxide units is not more than 20 wt %, based on the polyether polyol.
4. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the weight average of the polyether polyol is in the range from 800 to 6000 g/mol.
5. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the weight average of the polyether polyol is in the range from 1000 to 4500 g/mol.
6. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the α-alkoxysilane-terminated prepolymer contains triethoxy-α-silane groups.
7. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the polyisocyanate is an aliphatic polyisocyanate.
8. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the polymer is obtained by reacting the α-alkoxysilane with an NCO-terminated polyurethane prepolymer, wherein the NCO-terminated polyurethane prepolymer is obtainable by reacting the polyisocyanate with the polyether polyol and the average NCO functionality of the NCO-terminated polyurethane prepolymer is 4 or less.
9. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the polymer is obtained by reacting the α-alkoxysilane with an NCO-terminated polyurethane prepolymer, wherein the NCO-terminated polyurethane prepolymer is obtainable by reacting the polyisocyanate with the polyether polyol and the average NCO functionality of the NCO-terminated polyurethane prepolymer is in the range from 2 to 4.
10. A process for preparing an α-alkoxysilane-terminated prepolymer as claimed in claim 1 , comprising the steps of:
reacting the polyether polyol with the polyisocyanate to form an NCO-terminated polyurethane prepolymer, and
reacting the NCO-terminated polyurethane prepolymer with [(cyclohexylamino) methyl]triethoxysilane to form the α-alkoxysilane-terminated prepolymer.
11. An isocyanate-free, foamable composition wherein the composition contains an α-alkoxysilane-terminated prepolymer as claimed in claim 1 .
12. The composition as claimed in claim 11 , wherein the composition contains at least an active medical ingredient selected from substances that release nitrogen monoxide under in vivo conditions, or vitamins, provitamins, carotenoids, analgesics, antiseptics, hemostyptics, antihistamines, antimicrobial metals or salts thereof, plant-based wound healing promoter substances or substance mixtures, plant extracts, enzymes, growth factors, enzyme inhibitors and also combinations thereof.
13. The composition as claimed in claim 11 , wherein the composition contains a pressure-liquefied propellant gas.
14. The composition as claimed in claim 13 , wherein the content level of dissolved propellant gas in the composition is from 10 to 30 wt %.
15. An isocyanate-free multicomponent system which comprises at least two separate components, wherein the first component comprises a composition as claimed in claim 11 and the second component comprises a protic compound.
16. The multicomponent system as claimed in claim 15 , wherein the protic compound is an aqueous component and the aqueous component has a pH of 4.0 to 9.5.
17. The multicomponent system as claimed in claim 16 , wherein the aqueous component has a pH of 5.0 to 6.5.
18. The multicomponent system as claimed in claim 16 , wherein the aqueous component comprises or consists of a polyurethane dispersion.
19. The α-alkoxysilane-terminated prepolymer as claimed in claim 1 , wherein the polyisocyanate is hexamethylene 1,6 diisocyanate.