IP Library Granted Patent US 9,458,277
Granted Patent B2
US 9,458,277 · App. 14/348,310 · Granted Oct 4, 2016

Homogeneous extruded articles made from thermoplastically processable polyurethanes based on polyester diols formed from succinic acid and 1,3-propanediol

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Quick Facts
Patent No.
US 9,458,277
App. No.
14/348,310
Granted
Oct 4, 2016
Kind
B2
Abstract

The present invention relates to homogeneous extruded articles made from thermoplastically processable polyurethanes based on polyester diols formed from succinic acid and 1,3-propanediol.

Claims (24)

1. A method comprising preparing a thermoplastically processable polyurethane elastomer with hardness from 65 to 95 Shore A, determined in accordance with ISO 868, obtained from the components consisting of:

a) one or more substantially linear polyesterdiol with functionality from 1.8 to 2.2,

b) one or more organic diisocyanate,

c) one or more diol with a molar mass from 60 to 350 g/mol,

where the molar NCO:OH ratio is set at from 0.9:1 to 1.1:1,

and wherein the substantially linear polyesterdiol a) consists of succinic acid and of 1,3-propanediol and has an average molar mass of from 750 to 3500 g/mol.

2. An extruded item essentially consisting of a thermoplastically processable polyurethane elastomer with hardness from 65 to 95 Shore A, determined in accordance with ISO 868, obtained from the components consisting of:

a) one or more substantially linear polyesterdiol with functionality from 1.8 to 2.2,

b) one or more organic diisocyanate,

c) one or more diol with a molar mass from 60 to 350 g/mol,

where the molar NCO:OH ratio is set at from 0.9:1 to 1.1:1,

and wherein the substantially linear polyesterdiol a) consists of succinic acid and of 1,3-propanediol and has an average molar mass of from 750 to 3500 g/mol.

3. The extruded item as claimed in claim 2 , wherein at least one of components a) and c) has been produced entirely or to some extent biologically.

4. The extruded item as claimed in claim 2 , wherein the organic diisocyanate b) is selected from one or more isocyanates from the group consisting of diphenylmethane 4,4′-diisocyanate, isophorone diisocyanate, dicyclohexylmethane 4,4-diisocyanate, hexamethylene 1,6-diisocyanate, and naphthylene 1,5-diisocyanate.

5. The extruded item as claimed in claim 2 , wherein the diol c) is selected from the group consisting of 1,4-butanediol, 1,3-propanediol, ethylene 1,2-glycol, and 1,6-hexanediol.

6. The extruded item as claimed in claim 2 , wherein the succinic acid in the polyesterdiol is produced biologically by fermentation of carbohydrates.

7. The extruded item as claimed in claim 2 , wherein the 1,3-propanediol used in the polyesterdiol has been produced biologically via fermentation of carbohydrates.

8. The extruded item as claimed in claim 2 , wherein the diol comprises a biologically produced 1,3-propanediol.

9. A process for the production of an extruded item as claimed in claim 2 comprising extruding the thermoplastically processable polyurethane elastomers with hardness from 65 to 95 Shore A, determined in accordance with ISO 868, obtained from the components consisting of:

a) one or more substantially linear polyesterdiols with functionality from 1.8 to 2.2,

b) one or more organic diisocyanates,

c) one or more diols with molar masses from 60 to 350 g/mol,

where the molar NCO:OH ratio is set at from 0.9:1 to 1.1:1,

and wherein the substantially linear polyesterdiols a) consists of succinic acid and of 1,3-propanediol and have an average molar mass of from 750 to 3500 g/mol.

Assignments (4)
CHANGE OF NAME Recorded Apr 7, 2016
From: BAYER MATERIALSCIENCE AG
To: COVESTRO DEUTSCHLAND AG
Reel/Frame 038376/0427 →
CHANGE OF NAME Recorded Mar 21, 2016
From: BAYER MATERIALSCIENCE AG
To: COVESTRO DEUTSCHLAND AG
Reel/Frame 038188/0408 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2016
From: BAYER INTELLECTUAL PROPERTY GMBH
To: BAYER MATERIALSCIENCE AG
Reel/Frame 038056/0732 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 28, 2014
From: BRAEUER, WOLFGANG; SHEN, YI; KAUFHOLD, WOLFGANG; NEFZGER, HARTMUT
To: BAYER INTELLECTUAL PROPERTY GMBH
Reel/Frame 033627/0776 →