IP Library Granted Patent US 8,937,286
Granted Patent B2
US 8,937,286 · App. 14/350,196 · Granted Jan 20, 2015

Solid scintillator and electron beam detector using the same

Inventors: Kazumitsu Morimoto (Kamakura, JP); Yoshitaka Adachi (Yokohama, JP); Akihisa Saito (Yokohama, JP); Eiji Oyaizu (Yokohama, JP); Masaki Toyoshima (Fujisawa, JP)
Assignees: Kabushiki Kaisha Toshiba; Toshiba Materials Co., Ltd.
C09K11/7774H01J37/244
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Quick Facts
Patent No.
US 8,937,286
App. No.
14/350,196
Granted
Jan 20, 2015
Kind
B2
Abstract

The present invention provides a solid scintillator comprising a rare earth oxide sintered body, wherein: an afterglow time, which is the time required for a light output from the solid scintillator to degrease from a maximum value to 1/e of the maximum value, is 200 ns or shorter. The rare earth oxide sintered body preferably has a composition represented by a general formula (1): Ln a X b O c :Ce  (1), wherein Ln is one or more elements selected from Y, Gd and Lu; X is one or more elements selected from Si, Al and B; and a, b and c satisfy 1≦a≦5, 0.9≦b≦6, and 2.5≦≦c≦13, respectively.

Claims (32)

1. A solid scintillator comprising a rare earth oxide sintered body, wherein:

an afterglow time, which is the time required for a light output from the solid scintillator to degrease from a maximum value to 1/e of the maximum value, is 200 ns or shorter, and

the rare earth oxide sintered body has a composition represented by a following general formula (1):

[Formula 1]

Ln a X b O c :Ce  (1)

wherein Ln is one or more elements selected from Y, Gd and Lu; X is one or more elements selected from Si, Al and B; and a, b and c satisfy 1≦a≦5, 0.9≦b≦6, and 2.5≦c≦13, respectively.

2. The solid scintillator according to claim 1 , wherein the rare earth oxide sintered body has a composition represented by a following general formula (2):

[Formula 2]

Y 2 O 3 .β 1 SiO 2 :Ce  (2)

wherein β 1 satisfies 0.95<β 1 <1.05.

3. The solid scintillator according to claim 1 , wherein the rare earth oxide sintered body has a composition represented by a following general formula (3):

[Formula 3]

α 2 Y 2 O 3 .β 2 Al 2 O 3 :Ce  (3)

wherein α 2 and β 2 satisfy 1.45<α 2 <1.55 and 2.45<β 2 <2.55, respectively.

4. The solid scintillator according to claim 1 , wherein the rare earth oxide sintered body has a composition represented by a following general formula (4):

[Formula 4]

α 3 Y 2 O 3 .β 3 Al 2 O 3 :Ce  (4)

wherein α 3 and β 3 satisfy 0.45<α 3 <0.55 and 0.45<β 3 <0.55, respectively.

5. The solid scintillator according to claim 1 , wherein the rare earth oxide sintered body has a composition represented by a following general formula (5):

[Formula 5]

α 4 Y 2 O 3 .β 4 Al 2 O 3 :Ce,Pr  (5)

wherein α 4 and β 4 satisfy 0.45<α 4 <0.55 and 0.45<β 4 <0.55, respectively.

6. The solid scintillator according to claim 1 , wherein the rare earth oxide sintered body has a composition represented by a following general formula (6):

[Formula 6]

0.8Gd 2 O 3 .0.2Y 2 O 3 .β 5 SiO 2 :Ce  (6)

wherein β 5 satisfies 0.95<β 5 <1.05.

7. The solid scintillator according to claim 1 , wherein the rare earth oxide sintered body has an average crystal particle size of 1 to 20 μm.

8. The solid scintillator according to claim 1 , wherein the rare earth oxide sintered body has a relative density of 99% or more.

9. The solid scintillator according to claim 1 , wherein surface roughness Ra of an output surface outputting light to a photoelectron multiplier tube side is 0.3 to 10 μm.

10. An electron beam detector using a solid scintillator according to claim 1 .

11. The electron beam detector according to claim 10 comprising a photoelectron multiplier tube.

12. The electron beam detector according to claim 10 , wherein the electron beam detector is used in a SEM apparatus.

Assignments (4)
NUNC PRO TUNC ASSIGNMENT Recorded Feb 19, 2026
From: KABUSHIKI KAISHA TOSHIBA
To: TOSHIBA MATERIALS CO. LTD.
Reel/Frame 074940/0511 →
CHANGE OF NAME Recorded Feb 19, 2026
From: TOSHIBA MATERIALS CO. LTD.
To: NITERRA MATERIALS CO., LTD.
Reel/Frame 074941/0803 →
CHANGE OF ADDRESS Recorded Feb 19, 2026
From: KABUSHIKI KAISHA TOSHIBA
To: KABUSHIKI KAISHA TOSHIBA
Reel/Frame 074941/0846 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 7, 2014
From: MORIMOTO, KAZUMITSU; ADACHI, YOSHITAKA; SAITO, AKIHISA; OYAIZU, EIJI; TOYOSHIMA, MASAKI
To: KABUSHIKI KAISHA TOSHIBA; TOSHIBA MATERIALS CO., LTD.
Reel/Frame 032616/0579 →
Priority Claims (1)
JP 2011-241697 · Nov 2, 2011 · national
Continuity (1)
Related Publication 20140246586A1 · Sep 4, 2014