Polyester film
View Patent ↗The present invention provides a polyester film that can be suitably used in the applications requiring excellent transparency and slipping property, for example, such as a film member for a transparent electrode used in touch panels, etc., and a member for molding films. The present invention relates to a polyester film comprising non-heat-resistant particles supported thereon, in which after supporting the non-heat-resistant particles on at least one surface of an unstretched polyester film, the unstretched polyester film is stretched in at least one direction thereof, and a process for producing a polyester film comprising the steps of blowing non-heat-resistant particles onto at least one surface of an unstretched polyester film to support the non-heat-resistant particles thereon, or applying a coating solution comprising the non-heat-resistant particles onto at least one surface of the unstretched polyester film to support the non-heat-resistant particles thereon; and then stretching the unstretched polyester film in at least one direction thereof.
1. A polyester film comprising non-heat-resistant particles supported thereon and having a thickness of 25 to 300 μm, in which after supporting the non-heat-resistant particles on at least one surface of an unstretched polyester film, the unstretched polyester film is stretched in at least one direction thereof,
wherein the non-heat-resistant particles are supported on the polyester film by applying the coating solution comprising the non-heat-resistant particles thereonto, and
wherein after applying the coating solution comprising the non-heat-resistant particles onto at least one surface of the unstretched polyester film and then stretching the unstretched polyester film in at least one direction thereof to form a coating layer thereon, another coating layer prepared from a coating solution comprising a metal oxide and two or more kinds of crosslinking agents, is formed on the coating layer or on a surface of the polyester film opposed to the surface on which the coating layer is formed and the metal oxide is at least one selected from the group consisting of zirconium oxide, titanium oxide, tin oxide, yttrium oxide, antimony oxide, indium oxide, zinc oxide, antimony tin oxide and indium tin oxide.
2. A process for producing a polyester film, comprising the steps of:
blowing non-heat-resistant particles onto at least one surface of an unstretched polyester film to support the non-heat-resistant particles thereon, or applying a coating solution comprising the non-heat-resistant particles onto at least one surface of the unstretched polyester film to support the non-heat-resistant particles thereon; and then
stretching the unstretched polyester film in at least one direction thereof such that the polyester film has a thickness of 25 to 300 μm after stretching.
3. The polyester film according to claim 1 , wherein the non-heat-resistant particles are supported on the polyester film using a polymer in combination therewith.
4. The polyester film according to claim 1 , wherein the haze of the polyester film is 0.0 to 2.0% and after applying the coating solution comprising the non-heat-resistant particles onto at least one surface of the unstretched polyester film and then stretching the unstretched polyester film in at least one direction thereof to form a coating layer thereon, another coating layer having an absolute reflectance having one minimum value in a wavelength range of 400 to 800 nm in which the absolute reflectance at the minimum value is not less than 4.0%, is formed on the coating layer or on a surface of the polyester film opposed to the surface on which the coating layer is formed.
5. The polyester film according to claim 1 , wherein the non-heat-resistant particles are non-heat resistant organic particles.
6. The polyester film according to claim 1 , wherein the non-heat-resistant particles are non-heat resistant polymer particles.
7. The polyester film according to claim 1 , wherein the non-heat-resistant particles are non-heat resistant non-crosslinked polymer particles.
8. The polyester film according to claim 1 , wherein the non-heat-resistant particles are non-heat resistant non-crosslinked acrylic particles or non-heat resistant non-crosslinked styrene/acrylic resin particles.
9. The process for producing a polyester film according to claim 2 comprising
applying the coating solution comprising the non-heat-resistant particles onto at least one surface of the unstretched polyester film to support the non-heat-resistant particles thereon in a coating layer, and
after stretching the unstretched polyester film, applying a coating solution comprising a metal oxide and two or more kinds of crosslinking agents, on the coating layer having the non-heat-resistant particles or on a surface of the polyester film opposed to the surface on which the coating layer having the non-heat-resistant particles is formed,
wherein the metal oxide is at least one selected from the group consisting of zirconium oxide, titanium oxide, tin oxide, yttrium oxide, antimony oxide, indium oxide, zinc oxide, antimony tin oxide and indium tin oxide.
10. A polyester film comprising non-heat-resistant particles supported on both surfaces thereof and having a thickness of 25 to 300 μm, in which after supporting the non-heat-resistant particles on at least one surface of an unstretched polyester film, the unstretched polyester film is stretched in at least one direction thereof.
11. The polyester film according to claim 10 , wherein after applying the coating solution comprising the non-heat-resistant particles onto at least one surface of the unstretched polyester film and then stretching the unstretched polyester film in at least one direction thereof to form a coating layer thereon, another coating layer prepared from a coating solution comprising a metal oxide and two or more kinds of crosslinking agents, is formed on the coating layer or on a surface of the polyester film opposed to the surface on which the coating layer is formed and the metal oxide is at least one selected from the group consisting of zirconium oxide, titanium oxide, tin oxide, yttrium oxide, antimony oxide, indium oxide, zinc oxide, antimony tin oxide and indium tin oxide.
12. A process for producing a polyester film, comprising the steps of:
blowing non-heat-resistant particles onto at least one surface of an unstretched polyester film to support the non-heat-resistant particles on both surfaces thereof, or applying a coating solution comprising the non-heat-resistant particles onto both surfaces of the unstretched polyester film to support the non-heat-resistant particles on both surfaces thereof; and then
stretching the unstretched polyester film in at least one direction thereof such that the polyester film has a thickness of 25 to 300 μm after stretching.
13. The process for producing a polyester film according to claim 12 comprising
applying the coating solution comprising the non-heat-resistant particles onto both surfaces of the unstretched polyester film to support the non-heat-resistant particles thereon in two coating layers, and
after stretching the unstretched polyester film, applying a coating solution comprising a metal oxide and two or more kinds of crosslinking agents, on at least one coating layer having the non-heat-resistant particles,
wherein the metal oxide is at least one selected from the group consisting of zirconium oxide, titanium oxide, tin oxide, yttrium oxide, antimony oxide, indium oxide, zinc oxide, antimony tin oxide and indium tin oxide.