Elastomer composition having a very good dispersion of the charge in the elastomer matrix
View Patent ↗The invention relates to a rubber composition based on at least one diene elastomer, a reinforcing filler including at least carbon black, having a specific surface area CTAB greater than or equal to 130 m 2 /g, a plasticizing hydrocarbon resin, the vitreous transition temperature of which, Tg, is greater than 20° C. and the softening point of which is less than 170° C., and a cross linking system, the dispersion of the filler in the elastomeric matrix having a Z score greater than or equal to 70.
1. A rubber composition comprising the reaction products of:
a first master batch comprising a mixture obtained, in a liquid phase, of at least one diene elastomer and a reinforcing filler comprising at least carbon black having a CTAB specific surface area greater than or equal to 130 m 2 /g, wherein said carbon black is dispersed in said first master batch such that a dispersion of said carbon black in said first master batch has a Z score greater than or equal to 80;
a plasticizing hydrocarbon resin, having a glass transition temperature, Tg, which is greater than 20° C. and a softening point which is less than 170° C.; and
a crosslinking system,
wherein said reinforcing filler is dispersed in said rubber composition such that a dispersion of said reinforcing filler in said rubber composition has a Z score greater than or equal to 70.
2. A rubber composition according to claim 1 , wherein said plasticizing hydrocarbon resin content ranges from greater than 5 parts per hundred parts by weight of elastomer (phr) to less than 25 phr.
3. The composition according to claim 1 , wherein said first masterbatch is obtained from a mixture, in a liquid phase, of at least one diene elastomer latex and an aqueous dispersion of said carbon black.
4. The composition according to claim 3 , wherein said first masterbatch is a dried coagulum of the mixture, in a liquid phase, of at least one diene elastomer latex and an aqueous dispersion of said carbon black.
5. The rubber composition according to claim 1 , wherein said diene elastomer is selected from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and blends of these elastomers.
6. The rubber composition according to claim 5 , wherein said diene elastomer is a natural rubber.
7. The rubber composition according to claim 1 , wherein said reinforcing filler comprises at least one inorganic filler, and further comprising at least a second elastomer.
8. The rubber composition according to claim 7 , wherein said carbon black is present in an amount of from 20 to 80 phr, and said inorganic filler is present in an amount of from 5 to 50 phr.
9. The rubber composition as recited in claim 7 , wherein said inorganic filler and said second elastomer are combined in a second master batch in solid form by thermomechanical kneading prior to addition of said second master batch into said first master batch.
10. The rubber composition according to claim 1 , wherein a total amount of said reinforcing filler ranges from 30 to 150 phr.
11. A finished or semi-finished article comprising a rubber composition according to claim 1 .
12. A tire tread comprising a rubber composition according to claim 1 .