Method for producing hydrogen from ammonia

1. A method of producing hydrogen from ammonia the method comprising:

(i) providing ammonia as a fuel source;

(ii) introducing ammonia into a reactor and reacting at least some of the ammonia with a metal and/or a metal-containing-compound to form at least one intermediate and optionally hydrogen;

(iii) decomposing at least some of the intermediate produced in step (ii) to form hydrogen and to regenerate the metal and/or the metal-containing-compound;

(iv) removing at least some of the hydrogen formed in step (iii); and

(v) reacting the regenerated metal and/or the regenerated metal-containing-compound with further ammonia;

wherein the metal and/or the metal-containing-compound comprises or is selected from the group consisting of Group I metals;

wherein the Group I metal is selected from the group consisting of Na, Li, K, Rb, Cs, alloys and mixtures of two or more thereof;

wherein the reaction of the at least some ammonia with the metal and/or the metal-containing-compound to form the at least one intermediate is carried out at a temperature in the range of from 450 to 800° C. and at a pressure of 0.01 to 20 MPa.

2. The method according to claim 1 wherein the method is carried out in-situ in a vehicle.

3. The method according to claim 1 further comprising introducing the removed hydrogen into a fuel cell or a prime mover.

4. The method according to claim 1 further comprising combusting the removed hydrogen.

5. The method according to claim 1 wherein the at least one intermediate is a stable, isolatable intermediate.

6. The method according to claim 1 wherein the at least one intermediate is a metal amide.

7. The method according to claim 1 further comprising refuelling the ammonia fuel source.

8. The method according to claim 1 wherein the Group I metal is Na.

9. The method according to claim 1 wherein the reaction of the at least some ammonia with a metal and/or metal containing compound to form at least one intermediate is carried out in the presence of a catalyst.

10. The method according to claim 9 wherein the catalyst comprises one or more transition metals, lanthanide metals and mixtures thereof.

11. The method according to claim 10 wherein the catalyst is selected from the group consisting of transition metal calogenides, lanthanide metal calogenides, transition metal halides, lanthanide metal halides, transition metal pnictides, lanthanide metal pnictides, transition metal tetrels, lanthanide metal tetrels and mixtures of two or more thereof.

12. The method according to claim 1 wherein the at least some ammonia is introduced into the reactor such that the molar ratio of ammonia to metal and/or metal-containing-compound is in the range of from 1:1 to 1:2.

13. The method according to claim 1 further comprising removing hydrogen formed by the reaction of ammonia with the metal and/or the metal-containing-compound from the reactor.

14. The method according to claim 1 wherein at least some of the intermediate formed in step (ii) is decomposed to form hydrogen and to regenerate at least some of the metal and/or the metal-containing-compound by electrochemical, thermal, microwave, mechanical, impact, combustion, detonation and/or ultrasound means.

15. The method according to claim 1 wherein hydrogen is provided at the point of use or into a distributed network.

16. A method of producing hydrogen from ammonia the method comprising:

(i) providing ammonia as a fuel source;

(ii) introducing ammonia into a reactor and reacting at least some of the ammonia with a metal and/or a metal-containing-compound to form at least one intermediate and optionally hydrogen;

(iii) decomposing at least some of the intermediate produced in step (ii) to form hydrogen and to regenerate the metal and/or the metal-containing-compound;

(iv) removing at least some of the hydrogen formed in step (iii); and

(v) reacting the regenerated metal and/or the regenerated metal-containing-compound with further ammonia; and

wherein the reaction of the at least some ammonia with a metal and/or metal containing compound to form at least one intermediate is carried out in the presence of a catalyst; and

wherein the catalyst is selected from the group consisting of transition metal calogenides, lanthanide metal calogenides, transition metal halides, lanthanide metal halides, transition metal pnictides, lanthanide metal pnictides, transition metal tetrels, lanthanide metal tetrels and mixtures of two or more thereof.