Super-absorbing polymers with rapid absorption properties and method for producing the same
View Patent ↗The present invention relates to a particulate absorbent polymer material having: i) a maximum APC i×10 sec value ≥1.6) for at least one number i selected from the group of integers from 2 to 12 (=APC max ); or ii) a value ≥12 for the sum total of all APC i×10 sec values for all numbers i from the group of integers from 2 to 12 (=APC sum ); wherein the APC i×10 sec value is: APC i×10 sec =QI i×10 sec value 2 ×PI i×10 sec value where the QI i×10 sec value is the swell index and i×10 seconds after adding the 0.9% by weight NaCl solution, and the PI i×10 sec value is the permeability index and i×10 seconds after adding the 0.9% by weight NaCl solution.
1. A method for preparing a low cellulose content absorbent core by selecting a particulate superabsorbent polymer material for incorporating the particulate absorbent polymer material in an absorbent core containing an upper substrate layer, a lower substrate layer and also an absorption layer arranged between the upper and the lower substrate layers, wherein the absorption layer comprises the particulate absorbent polymer material and less than 0.1 g of cellulose fibres per gram of particulate absorbent polymer material, containing the steps of
A) identifying a particulate absorbent polymer material having at least one of the following properties:
i) a maximum APC i×10 sec value ≥1.6 for at least one number i selected from the group of integers from 2 to 12; and/or
ii) a value ≥12 for the sum total of all APC i×10 sec sec values for all numbers i from the group of integers from 2 to 12;
wherein APC i×10 sec value is defined as follows:
APC i×10 sec value=(QI i×10 sec value) 2 ×PI i×10 sec value, where
the QI i×10 sec sec value is the value of the swell index determined i×10 seconds after adding a 0.9% by weight NaCl solution, and
the PI i×10 sec value is the value of the permeability index determined i×10 seconds after adding the 0.9% by weight NaCl solution; and
B) incorporating the particulate absorbent material in an absorbent core.
2. The method according to claim 1 , wherein the particulate absorbent polymer material has the following property: i) a maximum APC i×10 sec value ≥1.6 for at least one number i from the group of integers from 2 to 12.
3. The method according to claim 2 , wherein the particulate absorbent polymer material has the following property:
i) a maximum APC i×10 sec value ≥2.0 for at least one number i from the group of integers from 2 to 12.
4. The method according to claim 3 , wherein the particulate absorbent polymer material has the following property: i) a maximum APC i×10 sec value ≥2.4 for at least one number i from the group of integers from 2 to 12.
5. The method according to claim 1 , wherein the particulate absorbent polymer material has the following property:
ii) a value ≥12 for the sum total of all APC i×10 sec values for all numbers i from the group of integers from 2 to 12.
6. The method according to claim 5 , wherein the particulate absorbent polymer material has the following property: ii) a value ≥18 for the sum total of all APC i×10 sec values for all numbers i from the group of integers from 2 to 12.
7. The method according to claim 6 , wherein the particulate absorbent polymer material has the following property: ii) a value ≥24 for the sum total of all APC i×10 sec values for all numbers i from the group of integers from 2 to 12.
8. The method according to claim 1 , wherein the absorbent core is essentially free of cellulose fibers.
9. The method according to claim 1 , wherein the absorbent core contains a thermoplastic material and a multiplicity of compartments containing the particulate absorbent polymer material.
10. The method according to claim 9 , wherein the absorbent core contains layers of a thermoplastic material and a multiplicity of compartments containing the particulate absorbent polymer material, wherein the compartments are each bounded by the upper or lower substrate layer and also by a layer of the thermoplastic material.
11. The method according to claim 10 , wherein the absorbent core contains a first sub-layer and a second sub-layer adjoining the first sub-layer, wherein the first sub-layer contains the upper substrate layer and also compartments containing the particulate absorbent polymer material which are bounded by the upper substrate layer and a first layer of a thermoplastic material, and the second sub-layer contains the lower substrate layer and also compartments containing the particulate absorbent polymer material which are bounded by the lower substrate layer and a second layer of a thermoplastic material, wherein the first layer of thermoplastic material adjoins the second layer of thermoplastic material.
12. The method according to claim 10 , wherein at least one layer of a thermoplastic material is obtainable by melting a fibrous thermoplastic material.