IP Library Granted Patent US 9,683,170
Granted Patent B2
US 9,683,170 · App. 14/353,445 · Granted Jun 20, 2017

Liquid crystal composition and liquid crystal display device using the same

Inventors: Yoshinori Iwashita (Kita-adachi-gun, JP); Makoto Negishi (Kita-adachi-gun, JP)
Assignee: DIC CORPORATION
C09K19/3003C09K19/44C09K2019/0448C09K2019/123C09K2019/301C09K2019/3004C09K2019/3009C09K2019/3016C09K2019/3027
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Quick Facts
Patent No.
US 9,683,170
App. No.
14/353,445
Granted
Jun 20, 2017
Kind
B2
Abstract

There is provided a liquid crystal composition which is suitably used in a liquid crystal display device without impairment of properties inherent in liquid crystal display devices. There is provided a liquid crystal display device in which such a liquid crystal composition is used. There is provided a liquid crystal composition having a negative dielectric anisotropy and containing a compound represented by Formula (I-1) and at least one compound represented by General Formula (II) and also provided a liquid crystal display device in which such a liquid crystal composition is used.

Claims (24)

1. A liquid crystal composition having a negative dielectric anisotropy, the liquid crystal composition comprising:

a compound represented by Formula (I-1);

at least one compound represented by General Formula (II);

a compound represented by Formula (IVb-1);

a compound represented by Formula (IIIb-1), and

a compound represented by Formula (V-5-1),

wherein in the General Formula (II), R 1 represents an alkyl group having 2 to 5 carbon atoms or an alkoxy group having 1 to 4 carbon atoms.

2. The liquid crystal composition according to claim 1 , wherein R 1 in General Formula (II) is an ethyl group.

3. The liquid crystal composition according to claim 1 , further comprising one or two compounds selected from the group consisting of compounds represented by Formulae (I-2) and (I-3)

4. The liquid crystal composition according to claim 1 , wherein the amount of the compound represented by Formula (I-1) is in the range of 10 to 23 mass %.

5. The liquid crystal composition according to claim 1 , further comprising a compound represented by General Formula (III)

where R 3 and R 4 each independently represent an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms; at least one hydrogen atom of the alkyl group, alkenyl group, alkoxy group, and/or alkenyloxy group is optionally substituted with a fluorine atom; the methylene group of the alkyl group, alkenyl group, alkoxy group, and/or alkenyloxy group is optionally substituted with an oxygen atom provided that the oxygen atom is not bonded to another oxygen atom in series or substituted with a carbonyl group provided that the carbonyl group is not bonded to another carbonyl group in series; A′ represents a 1,4-cyclohexylene group, or a tetrahydropyran-2,5-diyl group.

6. The liquid crystal composition according to claim 1 , further comprising a compound represented by General Formula (IV)

where R 5 and R 6 each independently represent an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms; at least one hydrogen atom of the alkyl group, alkenyl group, alkoxy group, and/or alkenyloxy group is optionally substituted with a fluorine atom; the methylene group of the alkyl group, alkenyl group, alkoxy group, and/or alkenyloxy group is optionally substituted with an oxygen atom provided that the oxygen atom is not bonded to another oxygen atom in series or substituted with a carbonyl group provided that the carbonyl group is not bonded to another carbonyl group in series; A 2 represents a 1,4-cyclohexylene group, a 1,4-phenylene group, or a tetrahydropyran-2,5-diyl group; in the case where A 2 represents a 1,4-phenylene group, at least one hydrogen atom of the 1,4-phenylene group is optionally substituted with a fluorine atom; and the compound represented by General Formula (IV) excludes the compound represented by Formula (IVb-1).

7. The liquid crystal composition according to claim 1 , further comprising a compound represented by General Formula (V)

where R 7 and R 8 each independently represent an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alkoxy group having 1 to 8 carbon atoms, or an alkenyloxy group having 2 to 8 carbon atoms; at least one hydrogen atom of the alkyl group, alkenyl group, alkoxy group, and/or alkenyloxy group is optionally substituted with a fluorine atom; the methylene group of the alkyl group, alkenyl group, alkoxy group, and/or alkenyloxy group is optionally substituted with an oxygen atom provided that the oxygen atom is not bonded to another oxygen atom in series or substituted with a carbonyl group provided that the carbonyl group is not bonded to another carbonyl group in series;

A 3 represents a 1,4-cyclohexylene group, a 1,4-phenylene group, or a tetrahydropyran-2,5-diyl group; in the case where A 3 represents a 1,4-phenylene group, at least one hydrogen atom of the 1,4-phenylene group is optionally substituted with a fluorine atom;

Z 1 represents a single bond, —CH 2 CH 2 —, —OCH 2 —, —OCF 2 —, —CH 2 O—, or —CF 2 O—;

n represents 0 or 1; and

X 1 to X 6 each independently represents a hydrogen atom or fluorine atom, and at least one of X 1 to X 6 represents a fluorine atom.

8. The liquid crystal composition according to claim 1 , further comprising a reactive monomer.

9. A liquid crystal display device comprising the liquid crystal composition according to claim 1 .

10. A liquid crystal display comprising the liquid crystal display device according to claim 9 .

11. The liquid crystal composition according to claim 1 , further comprising a compound represented by a compound represented by formula (IIIa-1),

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2024
From: DIC CORPORATION
To: SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.
Reel/Frame 067528/0688 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 13, 2014
From: IWASHITA, YOSHINORI; NEGISHI, MAKOTO
To: DIC CORPORATION
Reel/Frame 033096/0620 →
Continuity (1)
Related Publication 20160060521A1 · Mar 3, 2016