Soluble branched polymers
View Patent ↗Branched polymers are prepared from at least (A) at least one monomer having an electron donor moiety, (B) at least one monomer having an electron acceptor moiety, and (C) at least one multifunctional branching agent comprising a urea moiety and at least two N-vinyl groups. The branched polymers are least 20% (by weight) soluble in a solvent for which the corresponding polymer of equal molecular weight made without said multifunctional branching agent is at least 20% (by weight) soluble. Due in part to the wide range of chemistries and solubility and rheological properties, the branched polymers find application in personal care, pharmaceutical/nutritional, and performance chemicals compositions.
1. A branched polymer resulting from the polymerization of: (A) at least one monomer having an electron donor moiety, (B) at least one monomer having an electron acceptor moiety, and (C) at least one multifunctional branching agent comprising a urea moiety and at least two N-vinyl groups; wherein said monomer having an electron donor moiety is selected from the group consisting of: methyl vinyl ether, N-vinyl-2-pyrrolidone, isobutylene, and combinations thereof, and wherein said monomer having an electron acceptor moiety is maleic anhydride, and wherein said multifunctional branching agent is 1,3-divinyl imidazolidone; and wherein said polymer is methyl vinyl ether/maleic anhydride/1,3-divinyl imidazolidone polymer, isobutylene/maleic anhydride/1,3-divinyl imidazolidone polymer, methyl vinyl ether/N-vinyl-2-pyrrolidone/maleic anhydride/1,3-divinyl imidazolidone polymer, or isobutylene/maleic anhydride/N-vinyl-2-pyrrolidone/1,3-divinyl imidazolidone polymer.
2. The branched polymer according to claim 1 that is at least 20% (by weight) soluble in a solvent for which the corresponding polymer of equal molecular weight made without said multifunctional branching agent is at least 20% (by weight) soluble.
3. The branched polymer according to claim 1 having a frequency-dependent storage modulus (G′), a frequency-dependent loss modulus (G″), or frequency-dependent G′ and G″ over the range from about 1 rad/s to about 100 rad/s.
4. The branched polymer according to claim 1 for which G′ divided by G″ (i.e., tan δ) equal to or greater than 1.
5. The branched polymer according to claim 1 that is polymerized using up to about 14,000 ppm 1,3-divinyl imidazolidone.