Treated inorganic core particles having improved dispersability
View Patent ↗This disclosure relates to a process for preparing a treated inorganic core particle having improved dispersability comprising: (a) heating a slurry comprising porous silica treated inorganic core particle and water at a temperature of at least about 90° C.; and (b) adding a soluble alumina source to the slurry from step (a) while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated inorganic core particle; wherein the treated inorganic core particle does not comprise dense silica or alumina treatments, and has silica present in the amount of at least about 7% up to about 14% and alumina present in the amount of about 4.0% to about 8.0%; and wherein the particle to particle surface treatments are substantially homogeneous.
1. A process for preparing a treated TiO 2 core particle having improved dispersibility comprising:
(a) preparing a slurry comprising porous silica treated TiO 2 particle by a condensed phase aqueous oxide precipitation process comprising:
(a1) providing a slurry of TiO 2 core particle in water;
(a2) heating the slurry to about 30 to about 40° C. and adjusting the pH to about 3.5 to about 7.5;
(a3) adding a soluble silicate solution to the slurry while maintaining the pH between about 3.5 and about 7.5; and
(a4) stirring for at least about 5 mins;
(b) heating the slurry comprising porous silica treated TiO 2 particle at a temperature of at least about 90° C.; and
(c) adding a soluble alumina source to the slurry from step (b) while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated TiO 2 particle; wherein the treated TiO 2 particle does not comprise dense silica or alumina treatments, and has silica present in the amount of at least about 7% up to about 14% and alumina present in the amount of about 4.0% to about 8.0% all percentages based on the total weight of the TiO 2 particle; and wherein the particle to particle surface treatments are substantially homogeneous.
2. The process of claim 1 wherein the slurry in step (b) is heated to a temperature of about 93 to about 97° C.
3. The process of claim 2 wherein the slurry in step (b) is heated to a temperature of about 95 to about 97° C.
4. The process of claim 1 wherein the soluble alumina source is an alkali metal salt of an aluminate anion.
5. The process of claim 4 wherein the soluble alumina source is sodium aluminate or potassium aluminate.
6. The process of claim 1 wherein the the silica in the porous silica treated inorganic core particle is applied by deposition of pyrogenic silica onto pyrogenic inorganic core particle or by co-oxygenation of silicon tetrachloride with titanium tetrachloride.
7. The process of claim 1 wherein the soluble silicate is sodium silicate or potassium silicate.
8. The process of claim 1 wherein the TiO 2 is present in the amount of at least about 30% by weight, based on the total weight of the slurry.
9. The process of claim 1 wherein the slurry in step (a2) is heated to a temperature of about 33 to about 37° C.
10. The process of claim 9 wherein the soluble silicate is sodium silicate or potassium silicate.