Laminate paper treated with inorganic pigments having improved dispersability
View Patent ↗The disclosure provides a laminate paper comprising a treated inorganic core particle, in particular treated titanium dioxide (TiO 2 ) particle, having improved dispersability, prepared by a process comprising: (a) heating a slurry comprising porous silica treated inorganic core particle and water at a temperature of at least about 90° C.; and (b) adding a soluble alumina source to the slurry from step (a) while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated inorganic core particle; wherein the treated inorganic core particle does not comprise dense silica or alumina treatments, and has silica present in the amount of about 7% to about 14% and alumina present in the amount of about 4.0% to about 8.0%; and wherein the particle to particle surface treatments are substantially homogeneous.
1. A laminate paper comprising a treated inorganic core particle having improved dispersability, prepared by a process comprising:
(a) heating a slurry comprising porous silica treated inorganic core particle and water at a temperature of at least about 90° C.; and
(b) adding a soluble alumina source to the slurry from step (a) while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated inorganic core particle; wherein the treated inorganic core particle does not comprise dense silica or alumina treatments, and has silica present in the amount of at about 7% to about 14% and alumina present in the amount of about 4.0% to about 8.0% based on the total weight of the inorganic core particle; and wherein the particle to particle surface treatments are substantially homogeneous.
2. The laminate paper of claim 1 further comprising an opaque, cellulose pulp-based sheet.
3. The laminate paper of claim 1 further comprising an impregnating resin.
4. The laminate paper of claim 3 wherein the impregnating resin is a phenolic resin or a melamine resin.
5. The laminate paper of claim 1 wherein the inorganic core particle is an oxide of titanium, aluminum, zinc, copper or iron; a sulfate of calcium, strontium or barium; zinc sulfide; copper sulfide, zeolite; mica; talc; kaolin, mullite, calcium carbonate, or silica.
6. The laminate paper of claim 5 wherein the inorganic core particle is titanium dioxide, TiO 2 or barium sulfate.
7. The laminate paper of claim 6 wherein the inorganic core particle is titanium dioxide, TiO 2 .
8. The laminate paper of claim 1 wherein the slurry in step (a) is heated to a temperature of about 93 to about 97° C.
9. The laminate paper of claim 1 wherein the soluble alumina source is an alkali metal salt of an aluminate anion.
10. The laminate paper of claim 9 wherein the soluble alumina source is sodium aluminate or potassium aluminate.
11. The laminate paper of claim 1 wherein the treated inorganic core particle is completely dispersed in water to form a slurry in less than 10 minutes.
12. The laminate paper of claim 1 wherein the silica in the porous silica treated inorganic core particle is applied by deposition of pyrogenic silica onto pyrogenic inorganic core particle, by co-oxygenation of silicon tetrachloride with titanium tetrachloride, or by deposition via condensed phase aqueous oxide precipitation onto the inorganic core particle.
13. The laminate paper of claim 12 wherein the slurry comprising porous silica treated inorganic core particle and water is prepared by a process comprising:
(a1) providing a slurry of inorganic core particle in water;
(a2) heating the slurry to about 30 to about 40° C. and adjusting the pH to about 3.5 to about 7.5;
(a3) adding a soluble silicate solution to the slurry while maintaining the pH between about 3.5 and about 7.5; and
(a4) stirring for at least about 5 mins.
14. The laminate paper of claim 13 wherein the slurry is heated to a temperature of about 33 to about 37° C.
15. The laminate paper of claim 14 wherein the soluble silicate is sodium silicate or potassium silicate.
16. A paper laminate comprising a laminate paper, wherein the laminate paper comprises a treated inorganic core particle having improved dispersability, prepared by a process comprising:
(a) heating a slurry comprising porous silica treated inorganic core particle and water at a temperature of at least about 90° C.; and
(b) adding a soluble alumina source to the slurry from step (a) while maintaining the pH at about 8.0 to 9.5 to form an alumina treatment on the porous silica treated inorganic core particle; wherein the treated inorganic core particle does not comprise dense silica or alumina treatments, and has silica present in the amount of about 7% to about 14% and alumina present in the amount of about 4.0% to about 8.0%; and wherein the particle to particle surface treatments are substantially homogeneous.
17. The paper laminate of claim 16 further comprising Kraft paper.