Liquid crystal display
The liquid crystal display of the present invention includes: a liquid crystal panel including vertical alignment liquid crystals encapsulated between a first substrate and a second substrate; a first compensation layer stacked on one side of the first layer; a first polarizing layer stacked on one side of the first compensation layer; a second compensation layer stacked on one side of the second substrate; and a second polarizing layer stacked on one side of the second compensation layer, wherein the first compensation layer includes a polyimide copolymer, and the polyimide copolymer is a copolymer of a monomer mixture including maleimide compounds and aromatic vinyl compounds. The liquid crystal display provides significantly improved lateral viewing angle.
1. A liquid crystal display, comprising:
a liquid crystal panel including vertical alignment liquid crystals encapsulated between a first substrate and a second substrate;
a first compensation layer stacked on one side of the first substrate;
a first polarizing layer stacked on one side of the first compensation layer;
a second compensation layer stacked on one side of the second substrate; and
a second polarizing layer stacked on one side of the second compensation layer,
wherein the first compensation layer includes a polyimide copolymer, the polyimide copolymer being a copolymer of:
a first copolymer including repeating units of a maleimide compound and an aromatic vinyl compound, and
a second copolymer including repeating units of an aromatic vinyl compound and a vinyl cyanide compound.
2. The liquid crystal display according to claim 1 , wherein the first copolymer further includes repeating units of maleic anhydride.
3. The liquid crystal display according to claim 2 , wherein the polyimide copolymer includes a unit represented by Formula 1-1, a unit represented by Formula 1-2, a unit represented by Formula 1-3, and a unit represented by Formula 1-4:
in the Formula 1-1, each R is independently hydrogen, a substituted or unsubstituted C 1 -C 6 alkyl group, or a substituted or unsubstituted C 6 -C 12 aryl group; and
in the Formula 1-2, each Ar is independently a substituted or unsubstituted C 6 -C 12 aryl group.
4. The liquid crystal display according to claim 2 , wherein the polyimide copolymer is represented by Formula 1:
in the Formula 1, each R is independently, a substituted or unsubstituted C 1 -C 6 alkyl group, or a substituted or unsubstituted C 6 -C 12 aryl group; each Ar is independently a substituted or unsubstituted C 6 -C 12 aryl group; and M and N are each independently an integer from 2 to 8.
5. The liquid crystal display according to claim 1 , wherein the first compensation layer has reversed wavelength dispersion characteristics.
6. The liquid crystal display according to claim 1 , wherein the first compensation layer has C s of about −0.7 to about −0.2.
7. The liquid crystal display according to claim 1 , wherein R e of the first compensation layer ranges from about 40 nm to about 100 nm at 550 nm.
8. The liquid crystal display according to claim 1 , wherein R th of the first compensation layer ranges from about 100 nm to about 150 nm at 550 nm.
9. The liquid crystal display according to claim 1 , wherein the second compensation layer is a biaxial film or a C-plate.
10. The liquid crystal display according to claim 9 , wherein the biaxial film has indexes of refraction (n x , n y ) in x and y directions on a plane and an index of refraction (n z ) in a thickness direction satisfying a relationship: n x >n y >n z , R e of greater than 0 (R e >0), and R th of less than 0 (R th <0).
11. The liquid crystal display according to claim 9 , wherein the biaxial film is a cycloolefin polymer (COP), triacetylcellulose (TAC), or polyether sulfone (PES) compensation film.
12. The liquid crystal display according to claim 9 , wherein the C-plate is a cycloolefin polymer (COP) or acrylic compensation film having indexes of refraction (n x , n y ) in x and y directions on a plane and an index of refraction (n z ) in a thickness direction satisfying a relationship: n x =n y <n z , and R th of greater than 0 (R th >0).
13. The liquid crystal display according to claim 1 , wherein the first compensation layer has a slow axis perpendicular to a slow axis of the second compensation layer, the slow axis of the first compensation layer being perpendicular to an absorption axis of the first polarizing layer, the slow axis of the second compensation layer being perpendicular to the absorption axis of the second polarizing layer.
14. A compensation film comprising a copolymer of:
a first copolymer of a maleimide compound, an aromatic vinyl compound, and maleic anhydride, and
a second copolymer of a vinyl cyanide compound and an aromatic vinyl compound.
15. The compensation film according to claim 14 , wherein the compensation film has C s of −0.7 to −0.2, R e of about 40 nm to about 100 nm at 550 nm, and R th of about 100 nm to about 150 nm at 550 nm.
16. A liquid crystal display, comprising:
a liquid crystal panel that includes vertical alignment liquid crystals encapsulated between a first substrate and a second substrate;
a first compensation layer stacked on one side of the first substrate;
a first polarizing layer stacked on one side of the first compensation layer;
a second compensation layer stacked on one side of the second substrate; and
a second polarizing layer stacked on one side of the second compensation layer,
wherein the first compensation layer includes a polyimide copolymer represented by Formula 1:
wherein, in Formula 1,
each R is independently a substituted or unsubstituted C 1 -C 6 alkyl group or a substituted or unsubstituted C 6 -C 12 aryl group;
each Ar is independently a substituted or unsubstituted C 6 -C 12 aryl group; and
M and N are each independently an integer from 2 to 8.