IP Library Granted Patent US 9,324,894
Granted Patent B2
US 9,324,894 · App. 14/358,237 · Granted Apr 26, 2016

Glass sheet with high energy transmission

Inventors: Audrey Dogimont (Gosselies, BE); Sebastien Hennecker (Gosselies, BE); Thomas Lambricht (Gosselies, BE)
Assignee: AGC Glass Europe
H01L31/0481C03C3/087C03C3/095C03C4/0092G02B1/105G02B1/11G02B5/08H01L31/0392H01L31/048H01L31/0525C03C2201/20C03C2201/32C03C2201/3423C03C2201/40C03C2201/42C03C2201/54C03C2204/00
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Quick Facts
Patent No.
US 9,324,894
App. No.
14/358,237
Granted
Apr 26, 2016
Kind
B2
Abstract

The invention relates to an extra-clear glass sheet, i.e. a glass sheet with high energy transmission, which can be used in particular in the field of solar energy. Specifically, the invention relates to a glass sheet having a composition that includes, in an amount expressed in wt % for the total weight of the glass: 60-78% of SiO2; 0-10% of Al2O3; 0-5% of B2O3; 0-15% of CaO; 0-10% of MgO; 5-20% of Na2O; 0-10% of K2O; 0-5% of BaO, wherein the total amount of iron (in the form of Fe2O3) is 0.002-0.03%, and the composition includes a ratio of manganese/(total iron) of 1 to 8.5, the manganese content being expressed in the form of MnO in wt % relative to the total weight of the glass.

Claims (44)

1. A glass sheet having a composition comprising, in a content expressed as percentages by total weight of glass:

60 to 78% SiO 2 ;

0 to 10% Al 2 O 3 ;

0 to 5% B 2 O 3 ;

0 to 15% CaO;

0 to 10% MgO;

5 to 20% Na 2 O;

0 to 10% K 2 O;

0 to 5% BaO;

0.002 to 0.03% total iron expressed in the form of Fe 2 O 3 ; and

manganese

wherein the composition comprises a manganese/(total iron) ratio of 1 to 8.5, a manganese content being expressed in the form of MnO as percentage by weight, with respect to the total weight of the glass, and

wherein the composition comprises a manganese expressed in the form of MnO content of 0.005% to 0.2% by weight, with respect to the total weight of the glass.

2. The glass sheet of claim 1 , wherein the composition comprises a manganese/(total iron) ratio of 2.5 to 6.5.

3. The glass sheet of claim 1 , wherein the composition comprises a total iron expressed in the form of Fe 2 O 3 content of 0.002% to 0.02% by weight, with respect to the total weight of the glass.

4. The glass sheet of claim 1 , wherein the composition comprises a manganese expressed in the form of MnO content of 0.01% to 0.2% by weight, with respect to the total weight of the glass.

5. The glass sheet of claim 1 , further comprising cerium, wherein a cerium content expressed in the form of CeO 2 is ≦0.02% by weight, with respect to the total weight of the glass.

6. The glass sheet of claim 5 , further comprising vanadium, wherein the vanadium content expressed in the form of V 2 O 5 is ≦0.005% by weight, with respect to the total weight of the glass, and the cerium content expressed in the form of CeO 2 is ≦0.01% by weight, with respect to the total weight of the glass.

7. The glass sheet of claim 1 , further comprising vanadium, wherein a vanadium content expressed in the form of V 2 O 5 is ≦0.01% by weight, with respect to the total weight of the glass.

8. The glass sheet of claim 1 , further comprising antimony, wherein an antimony content expressed in the form of Sb 2 O 3 is <0.2% by weight, with respect to the total weight of the glass.

9. The glass sheet of claim 1 , wherein the glass sheet has an energy transmission, measured for a thickness of 3.85 mm, of at least 90%.

10. The glass sheet of claim 1 , wherein the glass sheet is coated with at least one transparent and electrically conducting thin layer.

11. The glass sheet of claim 1 , wherein the glass sheet is coated with at least one dirt-repellent layer.

12. The glass sheet of claim 1 , wherein the glass sheet is coated with at least one antireflection layer.

13. The glass sheet of claim 1 , wherein the glass sheet is coated with at least one mirror layer.

14. The glass sheet of claim 1 , wherein the composition comprises a total iron expressed in the form of Fe 2 O 3 content of 0.005% to 0.03% by weight, with respect to the total weight of the glass.

15. A solar photovoltaic module or mirror for concentrating solar energy, comprising at least one glass sheet of claim 1 .

16. A glass sheet having a composition consisting essentially of, in a content expressed as percentages by total weight of glass:

60 to 78% SiO 2 ;

0 to 10% Al 2 O 3 ;

0 to 5% B 2 O 3 ;

0 to 15% CaO;

0 to 10% MgO;

5 to 20% Na 2 O;

0 to 10% K 2 O;

0 to 5% BaO;

0.002 to 0.03% total iron expressed in the form of Fe 2 O 3 ; and

manganese

wherein the composition comprises a manganese/(total iron) ratio of 1 to 8.5, a manganese content being expressed in the form of MnO as percentage by weight, with respect to the total weight of the glass, and

wherein the composition comprises a manganese expressed in the form of MnO content of 0.005% to 0.2% by weight, with respect to the total weight of the glass.

17. The glass sheet of claim 16 , wherein the composition comprises a manganese/(total iron) ratio of 2.5 to 6.5.

18. The glass sheet of claim 16 , wherein the composition comprises a total iron expressed in the form of Fe 2 O 3 content of 0.005% to 0.03% by weight, with respect to the total weight of the glass.

19. The glass sheet of claim 16 , wherein the composition comprises a manganese expressed in the form of MnO content of 0.01% to 0.2% by weight, with respect to the total weight of the glass.

20. The glass sheet of claim 16 , further comprising cerium, wherein a cerium content expressed in the form of CeO 2 is ≦0.02% by weight, with respect to the total weight of the glass.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 15, 2014
From: DOGIMONT, AUDREY; HENNECKER, SEBASTIEN; LAMBRICHT, THOMAS
To: AGC GLASS EUROPE
Reel/Frame 032893/0413 →
Priority Claims (1)
BE 2011/0664 · Nov 15, 2011 · national
Continuity (1)
Related Publication 20140326314A1 · Nov 6, 2014