Electrode assembly, method for fabricating same, and battery charging and discharging method
The present invention relates to an electrode assembly, to a method for manufacturing same, and to a battery charging and discharging method. The electrode assembly according to one embodiment of the present invention includes: an electrode collector, wherein a first electrical active material layer is stacked on the electrode collector; and a first porous conductive network layer of which at least one portion is recessed into the first electrical active material layer, wherein the first porous conductive network layer is stacked on the circumferential surface opposite to that of the first electrical active material layer contacting the electrode collector.
1. An electrode assembly comprising:
a current collector;
a first electric active material layer stacked on the current collector; and
a first porous conductive network layer comprising a plurality of metal long fibers stacked as an exposed uppermost layer on a first main surface of the first electric active material layer opposite to a second main surface of the first electric active material layer contacting the current collector,
wherein only a portion of the plurality of metal long fibers is depressed into the first main surface of the electric active material layer so as to obtain a mechanical coupling between the porous conductive network layer and the electric active material layer, thereby ensuring a 3-dimensional deformation of the electrode assembly via at least one of stacking, bending and winding of the electrode assembly,
wherein the porous conductive network layer is rendered to be electrical conductive by bending, tangling and bridging the plurality of metal long fibers to each other and includes a nonwoven fabric structure consisting of a plurality of segmented metal long fibers, thereby locally forming an electric field inside the electric active material layer to improve speed and efficiency for charging and discharging the electrode assembly,
wherein thickness of the plurality of metal long fibers is over 1 μm and below 10 μm,
wherein the plurality of metal long fibers have an average length between 10 μm and 100 mm,
wherein the nonwoven fabric structure includes a high-density porous conductive network layer formed on the first main surface of the first electric active material layer and a low-density porous conductive network layer depressed into the first electric active material layer.
2. The electrode assembly of claim 1 , wherein the current collector comprises a metal foil, a metal mesh, or a combination thereof.
3. The electrode assembly of claim 1 , wherein the metal long fiber layer has a felt-like structure.
4. The electrode assembly of claim 1 , further comprising a base porous conductive network layer stacked between the current collector and the first electric active material layer, and at least partially depressed into the first electric active material layer.
5. The electrode assembly of claim 1 , further comprising a second electric active material layer stacked on a main surface of the first porous conductive network layer opposite to a main surface of the first porous conductive network layer contacting the first electric active material layer.
6. The electrode assembly of claim 5 , further comprising a second porous conductive network layer stacked on a main surface of the second electric active material layer opposite to a main surface of the second electric active material layer contacting the first porous conductive network layer.
7. The electrode assembly of claim 6 , wherein the second porous conductive network layer comprises a metal foam, carbon fibers, a metal long fiber layer, and a combination thereof.
8. The electrode assembly of claim 7 , wherein the metal long fiber layer has a felt-like structure.
9. The electrode assembly of claim 1 , wherein thickness of the first porous conductive network layer is from about 0.5 μm to about 100 μm.
10. The electrode assembly of claim 1 , wherein the metal long fiber layer comprises a plurality of segmented metal long fibers, and the plurality of metal long fibers have an average length from about 10 μm to about 100 mm.