Method for producing polyisocyanates and use thereof

1. A method for preparing polyisocyanates comprising iminooxadiazinedione groups by oligomerization of monomeric di- and/or triisocyanates comprising utilizing a catalyst, wherein the catalyst is a quaternary phosphonium polyfluoride of the formula R 4 P + F − .n(HF), where R are the same or different, optionally branched, aliphatic, aromatic and/or araliphatic C 1 -C 20 residues and optionally two or more substituents R may also form saturated or unsaturated rings with one another and with the phosphorus atom and n can have any values between 0.1 and 20, and wherein the water content of the catalyst added to the isocyanates to be oligomerized does not exceed 1000 ppm.

2. A method for preparing polyisocyanates containing iminooxadiazinedione groups which comprises reacting

a) at least one organic di- and/or triisocyanate,

b) one or more catalyst, comprising at least one quaternary phosphonium polyfluoride wherein the water contents of the catalyst does not exceed 1000 ppm in total,

c) optionally a solvent and

d) optionally an additive.

3. The method as claimed in claim 2 , wherein the method is carried out in the temperature range between 0° C. and 250° C.

4. The method as claimed in claim 2 , wherein the method is interrupted after 5 to 80% of the monomeric diisocyanate used have reacted.

5. The method as claimed in claim 2 , wherein the catalyst is used in a proportion between 1 mol ppm and 1 mol %, based on the amount of monomer.

6. The method as claimed in claim 2 , wherein unreacted monomer is removed from the reaction mixture.

7. The method as claimed in claim 2 , wherein at least one isocyanate used in the method is selected from the group consisting of hexamethylene diisocyanate (HDI), 2-methylpentane-1,5-diisocyanate, 2,4,4-trimethyl-1,6-hexanediisocyanate, 2,2,4-trimethyl-1,6-hexanediisocyanate, 4-isocyanatomethyl-1,8-octanediisocyanate, 3(4)-isocyanatomethyl-1-methylcyclohexyl isocyanate (IMCI), isophorone diisocyanate (IPDI), 1,3- and 1,4-bis(isocyanatomethyl)benzene (XDI), 1,3- and 1,4-bis(isocyanatomethyl)cyclohexane (H6XDI), 2,4- and 2,6-toluylene diisocyanate (TDI), bis(4-isocyanatophenyl)methane (4,4′MDI), 4-isocyanatophenyl-2-isocyanatophenylmethane (2,4′MDI), and polycyclic products which are accessible by formaldehyde-aniline polycondensation and subsequent conversion of the resulting (poly)amines to the corresponding (poly)isocyanates (polymer-MDI).