Holographic medium having a protective layer
View Patent ↗This invention relates to a holographic medium comprising a protective layer and a photopolymer film which is bonded to the protective layer and contains polyurethane matrix polymers, acrylate writing monomers and photoinitiators, wherein the protective layer is impermeable to the constituents of the photopolymer film, is optically clear and is transparent to electromagnetic radiation having a wavelength in the range of from 350 to 800 nm. The invention further provides the use of a holographic medium according to the invention in the production of holograms, and a process for the production of a holographic medium according to the invention.
1. A holographic medium comprising a protective layer and a photopolymer film which is bonded to the protective layer and contains polyurethane matrix polymers, acrylate writing monomers and photoinitiators, wherein the protective layer is impermeable to the constituents of the photopolymer film, is optically clear and is transparent to electromagnetic radiation having a wavelength in the range of from 350 to 800 nm, wherein the protective layer comprises high molecular weight, uncrosslinked polymers or three-dimensional network structures of high network density, wherein the high molecular weight, uncrosslinked polymers have a mean molar mass of >7500 g/mol, and wherein the three-dimensional network structures of high network density are obtained by reacting components that have number-average equivalent molar masses of <1500 g/mol.
2. The holographic medium according to claim 1 , wherein the protective layer covers at least one surface of the photopolymer film completely.
3. The holographic medium according to claim 1 , wherein the protective layer has a thickness of from 1 to 40 μm.
4. The holographic medium according to claim 1 , wherein the protective layer comprises polyurethane, polychloroprene and/or acrylate polymers.
5. The holographic medium according to claim 1 , wherein the protective layer is obtained by applying an aqueous or low-solvent polymer formulation to the photopolymer film.
6. The holographic medium according to claim 1 , wherein the photoinitiators comprise an anionic, cationic or neutral dye and a coinitiator.
7. The holographic medium according to claim 1 , wherein a hologram is exposed into the photopolymer film.
8. A method for the production of a hologram comprising exposing interferometrically the holographic medium according to claim 1 wherein in the hologram is selected from the groups consisting of in-line hologram, off-axis hologram, full-aperture transfer hologram, white light transmission hologram, Denisyuk hologram, off-axis reflection holograms, edge-lit hologram, and holographic stereogram.
9. A process for the production of a holographic medium according to claim 1 comprising preparing a photopolymer film from a formulation comprising polyisocyanates, polyols, acrylate writing monomers and photoinitiators and applying a protective layer to the photopolymer film, wherein the protective layer is impermeable to the constituents of the photopolymer film, is optically clear and is transparent to electromagnetic radiation having a wavelength in the range of from 350 to 800 nm.
10. The holographic medium according to claim 1 , wherein the protective layer is the outermost layer of the holographic medium.