Substrate with a functional layer comprising a sulphurous compound
View Patent ↗The invention relates to a substrate ( 1 ) comprising a medium ( 10 ), said medium ( 10 ) comprising, on at least one of its main faces, a functional layer ( 11 ) that has low-E or antisolar properties or is electrically conductive, characterized in that said functional layer ( 11 ) comprises, on its extreme surface opposite the medium ( 10 ), at least one sulphurous compound, in particular a sulphate, a sulphonate and/or a thiosulphate.
1. A substrate, comprising a carrier comprising, on at least one of its main faces, a functional film providing electrical conduction properties,
wherein:
the functional film comprises at least one metallic film and, on its extreme surface opposite the carrier, at least one thiosulfate, and
the functional film comprises a uniformity-promoting film which promotes uniform surface electrical properties and, within the functional film, is furthest from the carrier.
2. The substrate of claim 1 , wherein the functional film comprises at least one metallic silver-based film.
3. The substrate of claim 1 , wherein the functional film comprises at least one barrier film.
4. The substrate of claim 2 , wherein the metallic silver-based film comprises, on at least one of its faces, at least one sacrificial film.
5. The substrate of claim 2 , wherein the functional film comprises at least one optical optimization film situated between the metallic silver-based film and the carrier.
6. The substrate of claim 2 , wherein the functional film comprises at least one crystallization film situated between the carrier and the metallic silver-based film.
7. The substrate of claim 2 , wherein the functional film comprises at least one insertion film situated between the metallic silver-based film and a thin uniformity-promoting film.
8. The substrate of claim 1 , wherein the functional film is a discontinuous film in the form of separate adjacent zones.
9. A process for increasing uniformity of a surface of a substrate comprising a carrier comprising, on at least one of the carrier's main faces, a functional film providing electrical conduction properties, wherein the film comprises at least one metallic film, the process comprising in succession:
depositing the functional film;
etching the functional film by laser etching; and
applying an aqueous solution comprising thiosulfate anions.
10. The process of claim 9 , wherein the applying of the aqueous solution occurs with stirring.
11. The process of claim 9 , wherein a thiosulfate anion concentration of the aqueous solution is 0.1 M or higher.
12. The process of claim 9 , wherein a duration of the applying (t in mins) with respect to a concentration of the thiosulfate anions in the aqueous solution (c in M) is at least equal to t=4e −0.139c −0.25 and at most equal to t=4e −0.139c +0.25.
13. An optoelectronic device, comprising the substrate of claim 1 .
14. The substrate of claim 1 , wherein the functional film is a discontinuous film in the form of parallel strips.
15. The process of claim 9 , further comprising after the applying, rinsing in a water-based solvent to increase the uniformity of the substrate surface.
16. The process of claim 9 , wherein the functional film comprises at least one metallic silver-based film.
17. The process of claim 9 , wherein the functional film comprises at least one barrier film.
18. The process of claim 9 , wherein the metallic silver-based film comprises, on at least one of its faces, at least one sacrificial film.
19. The process of claim 9 , wherein the functional film comprises a uniformity-promoting film which promotes uniform surface electrical properties and, within the functional film, is furthest from the carrier.
20. The process of claim 9 , wherein the functional film comprises at least one optical optimization film situated between the metallic silver-based film and the carrier.
21. The process of claim 9 , wherein the functional film comprises at least one crystallization film situated between the carrier and the metallic silver-based film.
22. The process of claim 9 , wherein the functional film comprises at least one insertion film situated between the metallic silver-based film and a thin uniformity-promoting film.
23. The process of claim 9 , wherein the functional film is a discontinuous film in the form of separate adjacent zones.
24. The process of claim 9 , wherein the functional film is a discontinuous film in the form of separate adjacent zones in the form of parallel strips.
25. A process for increasing uniformity of a surface of a substrate comprising a carrier comprising, on at least one of its main faces, a functional film providing electrical conduction properties, wherein the film comprises at least one metallic film, the process comprising in succession:
depositing the functional film;
etching the functional film; and
applying an aqueous solution comprising thiosulfate anions,
wherein a duration of the applying (t in mins) with respect to a concentration of the thiosulfate anions in the aqueous solution (c in M) is at least equal to t=4e-0.139c−0.25 and at most equal to t=4e-0.139c+0.25.