Polylactide fibers
View Patent ↗Polylactide fibers are made from a blend of polylactides. One of the polylactides has a ratio of R-lactic and S-lactic units from 8:92 to 92:8. The second polylactide has a ratio of the R-lactic and S-lactic units of >97:3 or <3:97. The ratio of the R-lactic units to S-lactic units in the blend is from 7:93 to 25:75 or from 75:25 to 93:7. The polylactide fiber contains at least 5 Joules of polylactide crystallites per gram of polylactide resin in the fiber.
1. A method for treating a subterranean formation, comprising
a) introducing a treatment fluid into the subterranean formation, wherein
(i) the treatment fluid contains a liquid phase and multiple polylactide fibers dispersed in the liquid phase, and (ii) the polylactide fibers have a denier of 0.5 to 20 per filament and contain a polylactide resin, wherein the polylactide resin is a blend of (1) 20 to 90% by weight of a first polylactide in which the ratio of the R-lactic and S-lactic units is from 8:92 to 92:8 and (2) from 10 to 80% by weight of a second polylactide in which the ratio of the R-lactic and S-lactic units is ≧97:3 or ≦3:97, wherein the R-lactic units and S-lactic units combined constitute at least 90% of the weight of the second polylactide and further wherein the ratio of the R-lactic units to S-lactic units in the blend is from 7:93 to 25:75 or from 75:25 to 93:7; and the polylactide fiber contains at least 5 Joules of polylactide crystallites per gram of polylactide resin in the fiber, and then
b) degrading the polylactide fibers in the subterranean formation.
2. The method of claim 1 , wherein the blend of polylactide resins contains about 15 to 50 milliequivalents of carboxyl end groups per kilogram of polylactide resins.
3. The method of claim 2 , wherein the first polylactide resin has a weight average molecular weight from 40,000 to 125,000.
4. The method of claim 3 , wherein the fibers contain at least 10 Joules of polylactide crystallites per gram of polylactide resin in the fiber.
5. The method of claim 4 , wherein the fibers contain 12 to 22 Joules of polylactide crystallites per gram of polylactide resin in the fiber.
6. The method of claim 1 , wherein the fibers lose 7 to 20% of their mass upon immersing 0.48 g of the fibers in 100 mL of a 0.1 M phosphate buffer solution for 6 days at 65° C.
7. The method of claim 1 , wherein the fibers exhibit 5 to 25% shrinkage when heated in air at 80° C. for 10 minutes.
8. The method of claim 1 , wherein the fibers contains an agent that increases the hydrophilicity of the polylactide resin, or a catalyst for the hydrolysis of the polylactide resin, or both.