Grease composition
View Patent ↗A calcium complex grease composition is disclosed. The grease composition has a high dropping point and a suitable thickness and is stable to heat.
1. A grease composition comprising:
a base oil and
a thickening agent comprising a calcium complex soap, wherein the calcium complex soap comprises:
(1) a calcium soap of a higher fatty acid present in an amount of 2 to 15 parts by mass, wherein the higher fatty acid is a substituted or unsubstituted straight chain higher mono-fatty acid having 18 to 22 carbon atoms,
(2) a calcium soap of an aromatic fatty acid present in an amount of 0.5 to 3 parts by mass, wherein the aromatic fatty acid is an aromatic mono-fatty acid having a substituted or unsubstituted benzene ring and
(3) a calcium soap of a lower fatty acid present in an amount of 1 to 5 parts by mass, relative to 100 parts by mass of the overall grease composition, wherein the lower fatty acid is a straight chain saturated lower mono-fatty acid having 2 to 4 carbon atoms
wherein the amount of the higher fatty acid, relative to 100 parts by mass of the total fatty acid content, is greater than the amount of the lower fatty acid.
2. The grease composition according to claim 1 , wherein the dropping point is at least 180° C. or higher, as measured by JIS K 2220 8.
3. The grease composition according to claim 1 , wherein:
the higher fatty acid is selected from the group consisting of: stearic acid, oleic acid, 12-hydroxystearic acid, behenic acid, and a combination thereof,
the aromatic fatty acid is selected from the group consisting of: benzoic acid, para-toluic acid, and a combination thereof, and
the lower fatty acid is acetic acid.
4. The grease composition of claim 1 , wherein the dropping point is at least 250° C. or higher, as measured by JIS K 2220 8.
5. The grease composition according to claim 1 , wherein the higher fatty acid is selected from the group consisting of: stearic acid, oleic acid, 12-hydroxystearic acid, behenic acid, and a combination thereof.
6. The grease composition according to claim 1 , wherein the aromatic fatty acid is selected from the group consisting of: benzoic acid, para-toluic acid, and a combination thereof.
7. The grease composition according to claim 1 , wherein the lower fatty acid is acetic acid.
8. The grease composition according to claim 1 , wherein the base oil is present in an amount of 60 to 99 parts by mass, relative to 100 parts by mass of the overall grease composition.
9. The grease composition according to claim 1 , wherein the calcium complex soap is present in an amount of 1 to 40 parts by mass, relative to 100 parts by mass of the overall grease composition.
10. A method for preparing a grease composition comprising:
combining a base oil, calcium hydroxide, a higher fatty acid, an aromatic fatty acid, and a lower fatty acid to form the grease composition wherein:
(1) the higher fatty acid is a substituted or unsubstituted straight chain higher mono-fatty acid having 18 to 22 carbon atoms present in an amount of 2 to 15 parts by mass,
(2) the aromatic fatty acid is an aromatic mono-fatty acid having a substituted or unsubstituted benzene ring present in an amount of 0.5 to 3 parts by mass, and
(3) the lower fatty is a straight chain saturated lower mono-fatty acid having 2 to 4 carbon atoms present in an amount of 1 to 5 parts by mass, relative to 100 parts by mass of the overall grease composition,
wherein the amount of the higher fatty acid, relative to 100 parts by mass of the total fatty acid content, is greater than the amount of the lower fatty acid.
11. The method according to claim 10 , wherein the dropping point is at least 180° C. or higher, as measured by JIS K 2220 8.
12. The method according to claim 10 , wherein the dropping point is at least 250° C. or higher, as measured by JIS K 2220 8.
13. The method according to claim 10 , wherein:
the higher fatty acid is selected from the group consisting of: stearic acid, oleic acid, 12-hydroxystearic acid, behenic acid, and a combination thereof,
the aromatic fatty acid is selected from the group consisting of: benzoic acid, para-toluic acid, and a combination thereof, and
the lower fatty acid is acetic acid.
14. The method according to claim 10 , wherein the base oil is present in an amount of 60 to 99 parts by mass, relative to 100 parts by mass of the overall grease composition.
15. The method according to claim 10 , wherein the calcium complex soap is present in an amount of 1 to 40 parts by mass, relative to 100 parts by mass of the overall grease composition.
16. The grease composition according to claim 1 , wherein the higher fatty acid is present in an amount of 62 to 70 parts by mass, relative to 100 parts by mass of the total fatty acid content.
17. The grease composition according to claim 1 , wherein the aromatic fatty acid is present in an amount of 2 to 17 parts by mass, relative to 100 parts by mass of the total fatty acid content.
18. The grease composition according to claim 1 , wherein the lower fatty acid is present in an amount of 10 to 24 parts by mass, relative to 100 parts by mass of the total fatty acid content.
19. The method according to claim 10 , wherein the higher fatty acid is present in an amount of 62 to 70 parts by mass, relative to 100 parts by mass of the total fatty acid content.
20. The method according to claim 10 , wherein the aromatic fatty acid is present in an amount of 2 to 17 parts by mass, relative to 100 parts by mass of the total fatty acid content.
21. The method according to claim 10 , wherein the lower fatty acid is present in an amount of 10 to 24 parts by mass, relative to 100 parts by mass of the total fatty acid content.