Method of manufacturing double-sided polarizing plate and double-sided polarizing plate manufactured using the same
A method of manufacturing a double-sided polarizing plate and a double-sided polarizing plate manufactured using the same are provided. The method of manufacturing a double-sided polarizing plate includes attaching transparent films to both surfaces of a polarizer by means of adhesive layers, irradiating the adhesive layers with active energy rays emitted by an energy source disposed in a single direction with respect to the polarizer, and thermally treating a surface of the transparent film disposed opposite to the energy source at a temperature of 25° C. to 65° C.
1. A method of manufacturing a double-sided polarizing plate, comprising:
attaching transparent films to both surfaces of a polarizer by means of adhesive layers;
irradiating the adhesive layers with active energy rays emitted by an energy source disposed in a single direction with respect to the polarizer; and
thermally treating a surface of the transparent film disposed opposite to the energy source at a temperature of 30° C. to 50° C.,
wherein the thermal treatment is performed in a drum,
wherein the irradiation with the active energy rays is performed simultaneously with the thermal treatment,
wherein the adhesive layers are formed using a cationic adhesive,
wherein the cationic adhesive includes (1) 5 to 90 parts by weight of an epoxy compound having at least two epoxy groups in a molecule; (2) 5 to 90 parts by weight of an oxetane compound having at least one oxetanyl group in the molecule; and (3) 0.5 to 20 parts by weight of an optical cationic photopolymerization initiator, based on a total of 100 parts by weight of an adhesive composition,
wherein the epoxy compound is a combination of a first epoxy compound containing one or more epoxidized alicyclic groups and a second epoxy compound containing one or more glycidyl ether groups, and
wherein the first epoxy compound and the second epoxy compound are mixed at a weight ratio of 1:1 to 3:1.
2. The method of claim 1 , further comprising simultaneously curing the adhesive layers formed on both surfaces of the polarizer by once irradiation with the active energy rays.
3. The method of claim 1 , wherein the adhesive layer formed on the transparent film having the energy source disposed therein has a thickness of 0.1 μm to 10 μm.
4. The method of claim 1 , wherein the adhesive layer formed on the transparent film disposed opposite to the energy source has a thickness of 0.1 μm to 3 μm.
5. The method of claim 1 , wherein the cationic adhesive further comprises at least one selected from the group consisting of a silane coupling agent, a vinyl-based compound, and a radical polymerizable monomer.
6. The method of claim 1 , wherein at least one of the transparent films formed on both surfaces of the polarizer is an acrylic film.
7. The method of claim 1 , further comprising forming a primer layer between at least one surface of the adhesive layer and at least one surface of the transparent film.
8. The method of claim 7 , wherein the primer layer has a thickness of 100 nm to 1 μm.
9. The method of claim 7 , wherein the primer layer is formed of a primer composition comprising 1 to 50 parts by weight of a urethane polymer; 0.1 to 10 parts by weight of water-dispersible fine particles; and the balance of water, based on a total of 100 parts by weight of the primer composition.
10. The method of claim 9 , wherein the primer composition further comprises a cross-linking agent.