IP Library Granted Patent US 10,005,717
Granted Patent B2
US 10,005,717 · App. 14/361,425 · Granted Jun 26, 2018

Photo-reactive binder

Inventors: Paul Gevaert (Geraardsbergen, BE); Steven Cappelle (Ninove, BE); Hugues Van Den Bergen (Drogenbos, BE); Ram Gupta (Stamford, CT)
Assignee: ALLNEX BELGIUM S.A.
C07C229/38C07C69/76C07C227/16C07C229/12C09D11/02C09D11/101C09D133/14Y10T428/24802
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Quick Facts
Patent No.
US 10,005,717
App. No.
14/361,425
Granted
Jun 26, 2018
Kind
B2
Abstract

A compound obtained by reaction of one or more amines of general formula NHR 6 R 7 with a benzophenone derivative of the following general formula (IX) wherein M is a group comprising a number z of (meth)acrylate groups equal to at least one, L is a linker, G is linker comprising a number p′ of unreacted hydroxyl groups, and R, R″ and R′″ are optional substituents as well as inks, coating compositions and adhesives comprising the same.

Claims (25)

1. A process for the synthesis of a compound having the following formula (I),

comprising reacting:

a) a benzophenone derivative of the following general formula

b) a linker comprising from 4 to 300 hydroxyl groups, and

c1) a (meth)acrylating compound comprising at least one (meth)acrylate group and at least one reactive group capable to react with an hydroxyl group, or

c2) a linker comprising at least two reactive groups capable to react with a hydroxyl, then a (meth)acrylating compound comprising at least one (meth)acrylate group and at least one hydroxyl,

wherein in the formulas:

L is a linker,

R 5 is a reactive group capable to react with a hydroxyl group to form an ester,

R, R″ and R′″ are independently selected from the group consisting of H, C 1-8 alkyl, C 1-10 alkoxy and halogen,

m is from 1 to 100,

n is from 1 to 100,

G is a linker comprising a number p of unreacted hydroxyl groups comprised between 0 and 100, and is a residue of a polyhydroxy compound having at least 4 hydroxyl groups, and

M is a group comprising a number z of (meth)acrylate groups equal to at least one.

2. The process according to claim 1 , wherein the compound has the following formula (II),

3. The process according to claim 2 , wherein the compound has the following formula (IV),

4. The process according to claim 3 , wherein the compound has the following formula (VI),

5. The process according to claim 1 , wherein

the linker b) comprises from 4 to 92 hydroxyl groups,

n and m are independently from 1 to 31, and

p is from 0 to 30.

6. The process according to claim 5 , wherein the linker b) comprises from 4 to 40 hydroxyl groups and n and m are independently from 1 to 5.

7. The process according to claim 5 , wherein the linker b) comprises from 4 to 66 hydroxyl groups and p is from 0 to 4.

8. The process according to claim 1 , wherein n is from 2 to 100.

9. The process according to claim 8 , wherein the linker b) comprises from 4 to 205 hydroxyl groups and n is from 2 to 5.

Assignments (2)
CHANGE OF ADDRESS OF ASSIGNEE Recorded Sep 21, 2017
From: ALLNEX BELGIUM S.A.
To: ALLNEX BELGIUM S.A.
Reel/Frame 044168/0952 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2014
From: GEVAERT, PAUL; CAPELLE, STEVEN; VAN DEN BERGEN, HUGUES; GUPTA, RAM
To: ALLNEX BELGIUM S.A.
Reel/Frame 032988/0262 →
Priority Claims (1)
EP 12151911 · Jan 20, 2012 · regional
Continuity (1)
Related Publication 20140335326A1 · Nov 13, 2014
Cited By (2)
US 12,187,907 US 12,240,932