Hot-dip galvanized steel sheet having excellent adhesiveness at ultra-low temperatures
Provided is a hot-dip galvanized steel sheet having excellent adhesiveness at ultra-low temperatures as well as fine spangles, and a method of manufacturing the same. According to the present invention, a hot-dip galvanized steel sheet having excellent adhesiveness at ultra-low temperatures includes a base steel sheet, a composite layer formed on the base steel sheet and including transition metal, an inhibition layer formed on the composite layer and including a iron-aluminum (Fe—Al) based intermetallic compound, and a zinc (Zn)-plated layer formed on the inhibition layer, in which an average diameter of spangles in the zinc-plated layer is 150 μm or less, and a method of manufacturing the hot-dip galvanized steel sheet is provided.
1. A hot-dip galvanized steel sheet having excellent adhesiveness at ultra-low temperatures comprising:
a base steel sheet;
a composite layer having a shape of a band formed on the base steel sheet and including transition metal;
an inhibition layer formed on the composite layer and including an iron-aluminum (Fe—Al) based intermetallic compound; and
a zinc (Zn)-plated layer formed on the inhibition layer,
wherein an average diameter of spangles in the zinc-plated layer is 150 μm or less, excluding 0; and
wherein the composite layer comprises 50 wt. % to 90 wt. % of the transition metal, 10 wt. % to 30 wt. % of Al, and other unavoidable impurities as a remainder.
2. The hot-dip galvanized steel sheet having excellent adhesiveness at ultra-low temperatures of claim 1 , wherein the composite layer is in conformal relationship with the inhibition layer and the base steel sheet.
3. The hot-dip galvanized steel sheet having excellent adhesiveness at ultra-low temperatures of claim 1 , wherein the composite layer has a cubic structure.
4. The hot-dip galvanized steel sheet having excellent adhesiveness at ultra-low temperatures of claim 1 , wherein a thickness of the composite layer is 80 nm or more.